High indium composition InGaN is a promising material for thermoelectric harvesting application, which can work at high temperature and extreme environments. Due to the strong composition segregation, high indium composition InGaN material usually forms localized quantum dots, which advantageously enhances the thermoelectric (TE) properties. In this research, the two-dimensional InGaN/GaN superlattices (SLs) structured TE material with high In composition of 35% quantum dots is first grown and characterized. Using open-circuit voltage measurement, the Seebeck coefficient (S) exhibits a high value of −571 μV/K. Analysis indicates this relatively high S value is related to the increased density of electron states near the Fermi level induced by the reduced dimensionality, resulting in a power factor of 11.83 × 10−4W/m·K2. The dense boundary between InGaN quantum dots also increases the interface phonon scattering, thereby suppressing the heat transportation and leading to a low thermal conductivity (k) value of 19.9 W/m·K. As a result, a TE figure of merit (ZT) value of 0.025 is demonstrated in the sample. This work first clarifies the impact of embedded quantum dots in InGaN/GaN SLs structure on TE properties. It is very conductive for the design and fabrication of low-dimensional GaN based TE device.
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30 September 2024
Research Article|
September 30 2024
Thermoelectric properties of InGaN/GaN superlattices structure with high indium composition quantum dots
Junjie Kang
;
Junjie Kang
(Investigation, Writing – original draft)
1
Research and Development Center for Wide Bandgap Semiconductors, Institute of Semiconductors, Chinese Academy of Sciences
, Beijing 100083, China
2
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences
, Beijing 100049, China
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Qun Ma;
Qun Ma
(Investigation, Writing – review & editing)
1
Research and Development Center for Wide Bandgap Semiconductors, Institute of Semiconductors, Chinese Academy of Sciences
, Beijing 100083, China
2
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences
, Beijing 100049, China
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Yang Li;
Yang Li
(Writing – review & editing)
1
Research and Development Center for Wide Bandgap Semiconductors, Institute of Semiconductors, Chinese Academy of Sciences
, Beijing 100083, China
2
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences
, Beijing 100049, China
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Song Fu
;
Song Fu
(Investigation, Methodology, Writing – review & editing)
1
Research and Development Center for Wide Bandgap Semiconductors, Institute of Semiconductors, Chinese Academy of Sciences
, Beijing 100083, China
2
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences
, Beijing 100049, China
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Xiaoyan Yi;
Xiaoyan Yi
(Resources, Supervision, Writing – review & editing)
1
Research and Development Center for Wide Bandgap Semiconductors, Institute of Semiconductors, Chinese Academy of Sciences
, Beijing 100083, China
2
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences
, Beijing 100049, China
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Junxi Wang;
Junxi Wang
(Investigation, Methodology, Project administration, Visualization)
1
Research and Development Center for Wide Bandgap Semiconductors, Institute of Semiconductors, Chinese Academy of Sciences
, Beijing 100083, China
2
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences
, Beijing 100049, China
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Jinmin Li;
Jinmin Li
(Project administration, Resources, Supervision)
1
Research and Development Center for Wide Bandgap Semiconductors, Institute of Semiconductors, Chinese Academy of Sciences
, Beijing 100083, China
2
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences
, Beijing 100049, China
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Meng Liang
;
Meng Liang
a)
(Conceptualization, Data curation, Project administration, Visualization, Writing – review & editing)
1
Research and Development Center for Wide Bandgap Semiconductors, Institute of Semiconductors, Chinese Academy of Sciences
, Beijing 100083, China
2
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences
, Beijing 100049, China
a)Authors to whom correspondence should be addressed: liangmeng@semi.ac.cn; wanglai@tsinghua.edu.cn; and lzq@semi.ac.cn
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Lai Wang
;
Lai Wang
a)
(Conceptualization, Project administration, Writing – review & editing)
3
Department of Electronic Engineering, Tsinghua University
, Beijing 100084, China
a)Authors to whom correspondence should be addressed: liangmeng@semi.ac.cn; wanglai@tsinghua.edu.cn; and lzq@semi.ac.cn
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Zhiqiang Liu
Zhiqiang Liu
a)
(Conceptualization, Data curation, Funding acquisition, Project administration, Supervision, Writing – review & editing)
1
Research and Development Center for Wide Bandgap Semiconductors, Institute of Semiconductors, Chinese Academy of Sciences
, Beijing 100083, China
2
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences
, Beijing 100049, China
a)Authors to whom correspondence should be addressed: liangmeng@semi.ac.cn; wanglai@tsinghua.edu.cn; and lzq@semi.ac.cn
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a)Authors to whom correspondence should be addressed: liangmeng@semi.ac.cn; wanglai@tsinghua.edu.cn; and lzq@semi.ac.cn
Appl. Phys. Lett. 125, 142204 (2024)
Article history
Received:
June 28 2024
Accepted:
September 09 2024
Citation
Junjie Kang, Qun Ma, Yang Li, Song Fu, Xiaoyan Yi, Junxi Wang, Jinmin Li, Meng Liang, Lai Wang, Zhiqiang Liu; Thermoelectric properties of InGaN/GaN superlattices structure with high indium composition quantum dots. Appl. Phys. Lett. 30 September 2024; 125 (14): 142204. https://doi.org/10.1063/5.0226027
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