We have measured the reflectance of rhenium in the visible region to pressures up to 100 GPa in a diamond anvil cell (DAC). By photographing the reflecting surface, we visually show that there are challenges to obtaining accurate values in a DAC for several reasons, including cupping of the diamonds and roughening of the surface with the increase in pressure. We propose some useful procedures, such as careful alignment of the incident light and using thin gaskets to minimize cupping of the diamonds as well as measurement in the central region of the diamond culet. We also show that knowledge of the reflectance of rhenium can overcome the problem of absorption of light by diamonds when studying the reflectance of materials at high pressure in a DAC.

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