While the Internet-of-Things has already fueled a plethora of different possibilities, we are still in need of means to mitigate the inefficiencies of the cold chain generating every year massive food and drug waste, even causing serious illnesses. This is caused by the lack of remote sensing technologies suitable for a widespread deployment able to timely mark any cooled items exposed to inadequate temperatures. This work introduces a class of printable, battery-less, and chip-less passive tags, namely, the Parametric Alarm Sensor Tags (PASTs), allowing detection of any violations in the storage temperature of refrigerated items with extraordinary reading ranges. In order to do so, PASTs leverage a three-way sensing scheme and nonlinear dynamics never explored in any tag technologies to trigger the passive generation of a radio frequency signal only when the temperature exceeds a remotely configurable threshold (Tth). Furthermore, PASTs exhibit a dynamically enabled temperature-controlled hysteresis loop. As a result, the signal generated at the occurrence of a temperature violation remains active even if the temperature returns within a tolerable range. This allows us to flag any items previously or currently exposed to inadequate temperatures, allowing their prompt identification. We report a 870 MHz PAST and show that, thanks to its unique characteristics, it is finally possible to identify any items along the cold chain whose temperature has exceeded a remotely configurable Tth value as low as −47 °C, even if operating in uncontrolled electromagnetic environments and up to 46 m away from the corresponding PAST outside a line-of-sight.

1.
T. K.
Kim
,
X.
Li
, and
C.
Wang
, “
Temperature dependent capacity contribution of thermally treated anode current collectors in lithium ion batteries
,”
Appl. Surf. Sci.
264
,
419
423
(
2013
).
2.
L. M.
Ni
,
Y.
Liu
,
Y. C.
Lau
, and
A. P.
Patil
, “
LANDMARC: Indoor location sensing using active RFID
,” in
Proceedings of the First IEEE International Conference on Pervasive Computing and Communications, 2003 (PerCom 2003)
(
IEEE
,
2003
), pp.
407
415
.
3.
K. V. S.
Rao
,
P. V.
Nikitin
, and
S. F.
Lam
, “
Antenna design for UHF RFID tags: A review and a practical application
,”
IEEE Trans. Antennas Propag.
53
,
3870
3876
(
2005
).
4.
R. H.
Murofushi
and
J.
Tavares
, “
Towards fourth industrial revolution impact: Smart product based on RFID technology
,”
IEEE Instrum. Meas. Mag.
20
,
51
56
(
2017
).
5.
E.
Elbasani
,
P.
Siriporn
, and
J. S.
Choi
, “
A survey on RFID in industry 4.0
,” in
Internet of Things for Industry 4.0
(
Springer
,
2020
), pp.
1
16
.
6.
A. Y.-L.
Chong
and
F. T.
Chan
, “
Structural equation modeling for multi-stage analysis on radio frequency identification (RFID) diffusion in the health care industry
,”
Expert Syst. Appl.
39
,
8645
8654
(
2012
).
7.
A.
Björk
,
M.
Erlandsson
,
J.
Häkli
,
K.
Jaakkola
,
Å.
Nilsson
,
K.
Nummila
,
V.
Puntanen
, and
A.
Sirkka
, “
Monitoring environmental performance of the forestry supply chain using RFID
,”
Comput. Ind.
62
,
830
841
(
2011
).
8.
L.
Ruiz-Garcia
and
L.
Lunadei
, “
The role of RFID in agriculture: Applications, limitations and challenges
,”
Comput. Electron. Agric.
79
,
42
50
(
2011
).
9.
S.
Mercier
,
S.
Villeneuve
,
M.
Mondor
, and
I.
Uysal
, “
Time-temperature management along the food cold chain: A review of recent developments
,”
Compr. Rev. Food Sci. Food Saf.
16
,
647
667
(
2017
).
10.
E.
Scallan
,
R. M.
Hoekstra
,
F. J.
Angulo
,
R. V.
Tauxe
,
M.-A.
Widdowson
,
S. L.
Roy
,
J. L.
Jones
, and
P. M.
Griffin
, “
Foodborne illness acquired in the United States–major pathogens
,”
Emerging Infect. Dis.
17
,
7
15
(
2011
).
11.
R. L.
Scharff
, “
Economic burden from health losses due to foodborne illness in the United States
,”
J. Food Prot.
75
,
123
131
(
2012
).
12.
Centers for Disease Control and Prevention
,
Burden of Foodborne Illness: Findings
(
Centers for Disease Control and Prevention
,
2016
).
13.
L.
Young
, “
Our biggest problem? Were wasting food
,” (published online, 2012); available at https://canadiangrocer.com/our-biggest-problem-were-wasting-food
14.
G.
Bruckner
,
J.
Bardong
,
C.
Gruber
, and
V.
Plessky
, “
A wireless, passive id tag and temperature sensor for a wide range of operation
,” in
26th European Conference on Solid-State Transducers, EUROSENSOR, 2012
G.
Bruckner
,
J.
Bardong
,
C.
Gruber
, and
V.
Plessky
[
Procedia Eng.
47
,
132
135
(
2012
)].
15.
F.
Vivaldi
,
B.
Melai
,
A.
Bonini
,
N.
Poma
,
P.
Salvo
,
A.
Kirchhain
,
S.
Tintori
,
A.
Bigongiari
,
F.
Bertuccelli
,
G.
Isola
, and
F. D.
Francesco
, “
A temperature-sensitive RFID tag for the identification of cold chain failures
,”
Sens. Actuators, A
313
,
112182
(
2020
).
16.
R.
Badia-Melis
,
J.
Garcia-Hierro
,
L.
Ruiz-Garcia
,
T.
Jiménez-Ariza
,
J. I. R.
Villalba
, and
P.
Barreiro
, “
Assessing the dynamic behavior of WSN motes and RFID semi-passive tags for temperature monitoring
,”
Comput. Electron. Agric.
103
,
11
16
(
2014
).
17.
Z.
Qi
,
Y.
Zhuang
,
X.
Li
,
W.
Liu
,
Y.
Du
, and
B.
Wang
, “
Full passive UHF RFID tag with an ultra-low power, small area, high resolution temperature sensor suitable for environment monitoring
,”
Microelectron. J.
45
,
126
131
(
2014
).
18.
A.
Stelzer
,
S.
Scheiblhofer
,
S.
Schuster
, and
R.
Teichmann
, “
Wireless sensor marking and temperature measurement with saw-identification tags
,”
Measurement
41
,
579
588
(
2008
).
19.
A.
Dehghani-Sanij
,
E.
Tharumalingam
,
M.
Dusseault
, and
R.
Fraser
, “
Study of energy storage systems and environmental challenges of batteries
,”
Renewable Sustainable Energy Rev.
104
,
192
208
(
2019
).
20.
T.
Kimura
,
M.
Omura
,
Y.
Kishimoto
, and
K.
Hashimoto
, “
Applicability investigation of SAW devices in the 3 to 5 GHz range
,” in
Proceedings of IEEE/MTT-S International Microwave Symposium-IMS
(
IEEE
,
2018
), pp.
846
848
.
21.
V. P.
Plessky
, “
Surface acoustic wave RFID tags
,” in
Development and Implementation of RFID Technology
(
InTechOpen
,
2009
).
22.
V. P.
Plessky
and
L. M.
Reindl
, “
Review on SAW RFID tags
,”
IEEE Trans. Ultrason., Ferroelectr., Freq. Control
57
,
654
668
(
2010
).
23.
R. M.
Ferdous
,
A. W.
Reza
, and
M. F.
Siddiqui
, “
Renewable energy harvesting for wireless sensors using passive RFID tag technology: A review
,”
Renewable Sustainable Energy Rev.
58
,
1114
1128
(
2016
).
24.
Z.
Popović
,
S.
Korhummel
,
S.
Dunbar
,
R.
Scheeler
,
A.
Dolgov
,
R.
Zane
,
E.
Falkenstein
, and
J.
Hagerty
, “
Scalable RF energy harvesting
,”
IEEE Trans. Microwave Theory Tech.
62
,
1046
1056
(
2014
).
25.
H.
Dagan
,
A.
Teman
,
A.
Fish
,
E.
Pikhay
,
V.
Dayan
, and
Y.
Roizin
, “
A low-cost low-power non-volatile memory for RFID applications
,” in
Proceedings IEEE International Symposium on Circuits and Systems (ISCAS)
(
IEEE
,
2012
), pp.
1827
1830
.
26.
J.
Yeo
,
J.
Preishuber-Pfluegl
,
A.
Janek
,
A.
Schuhal
,
H.-W.
Son
,
J.-Y.
Jung
,
H.-S.
Mo
,
J.-H.
Bae
,
G.-Y.
Choi
,
C.-S.
Pyo
 et al., “
Passive tag including volatile memory
,”
U.S. patent 8,102,263
(January 24,
2012
).
27.
V.
Gutnik
,
J. D.
Hyde
,
D. D.
Dressler
,
A.
Pesavento
,
R. A.
Oliver
,
S. A.
Cooper
, and
K. E.
Sundstrom
, “
RFID tags with electronic fuses for storing component configuration data
,” U.S. patent 7,307,529 (December 11,
2007
).
28.
L.
Dong-Sheng
,
Z.
Xue-Cheng
,
Z.
Fan
, and
D.
Min
, “
Embedded EEPROM memory achieving lower power-new design of EEPROM memory for RFID tag IC
,”
IEEE Circuits Devices Mag.
22
,
53
59
(
2006
).
29.
M.
Zgaren
,
S.
Mohamad
,
A.
Amira
, and
M.
Sawan
, “
EPC Gen-2 UHF RFID tags with low-power CMOS temperature sensor suitable for gas applications
,” in
2016 14th IEEE International New Circuits and Systems Conference (NEWCAS)
(
IEEE
,
2016
), pp.
1
4
.
30.
Z.
Jiang
and
F.
Yang
, “
Reconfigurable sensing antennas integrated with thermal switches for wireless temperature monitoring
,”
IEEE Antennas Wireless Propag. Lett.
12
,
914
917
(
2013
).
31.
Z.
Jiang
and
F.
Yang
, “
Reconfigurable RFID tag antenna for wireless temperature monitoring
,” in
Proceedings of the IEEE International Symposium on Antennas and Propagation
(
IEEE
,
2012
), pp.
1
2
.
32.
R.
Bhattacharyya
,
C. D.
Leo
,
C.
Floerkemeier
,
S.
Sarma
, and
L.
Anand
, “
RFID tag antenna based temperature sensing using shape memory polymer actuation
,” in
Proceedings IEEE SENSORS
(
IEEE
,
2010
), pp.
2363
2368
.
33.
W.
Wang
,
R.
Owyeung
,
A.
Sadeqi
, and
S.
Sonkusale
, “
Single event recording of temperature and tilt using liquid metal with RFID tags
,”
IEEE Sens. J.
20
,
3249
3256
(
2020
).
34.
Y.
Shafiq
,
J.
Henricks
,
C. P.
Ambulo
,
T. H.
Ware
, and
S. V.
Georgakopoulos
, “
A passive RFID temperature sensing antenna with liquid crystal elastomer switching
,”
IEEE Access
8
,
24443
24456
(
2020
).
35.
P.
Fathi
,
N. C.
Karmakar
,
M.
Bhattacharya
, and
S.
Bhattacharya
, “
Potential chipless RFID sensors for food packaging applications: A review
,”
IEEE Sens. J.
20
,
9618
9636
(
2020
).
36.
H. M. E.
Hussein
,
M.
Rinaldi
,
M.
Onabajo
, and
C.
Cassella
, “
A chip-less and battery-less subharmonic tag for wireless sensing with parametrically enhanced sensitivity and dynamic range
,”
Sci. Rep.
11
,
3782
(
2021
).
37.
H. M. E.
Hussein
,
M. A. A.
Ibrahim
,
G.
Michetti
,
M.
Rinaldi
,
M.
Onabajo
, and
C.
Cassella
, “
Systematic synthesis and design of ultralow threshold 2:1 parametric frequency dividers
,”
IEEE Trans. Microwave Theory Tech.
68
,
3497
3509
(
2020
).
38.
A.
Suárez
,
Analysis and Design of Autonomous Microwave Circuits
(
John Wiley & Sons
,
2009
), Vol.
190
.
39.
C.
Cassella
,
N.
Miller
,
J.
Segovia-Fernandez
, and
G.
Piazza
, “
Parametric filtering surpasses resonator noise in ALN contour-mode oscillators
,” in
Proceedings of IEEE 27th International Conference on Micro Electro Mechanical Systems (MEMS)
(
IEEE
,
2014
), pp.
1269
1272
.
40.
C.
Cassella
,
S.
Strachan
,
S. W.
Shaw
, and
G.
Piazza
, “
Phase noise suppression through parametric filtering
,”
Appl. Phys. Lett.
110
,
063503
(
2017
).
41.
J. M. T.
Thompson
and
H. B.
Stewart
,
Nonlinear Dynamics and Chaos
(
John Wiley & Sons
,
2002
).
42.
Y.
Gu
and
T.
He
, “
Data forwarding in extremely low duty-cycle sensor networks with unreliable communication links
,” in
Proceedings of the 5th International Conference on Embedded Networked Sensor Systems
(
IEEE
,
2007
), pp.
321
334
.

Supplementary Material

You do not currently have access to this content.