Perovskite substrates boost the thermopower of cobaltate thin films at high temperatures Available to Purchase

Transition metal oxides are promising candidates for thermoelectric applications, because they are stable at high temperature and because strong electronic correlations can generate large Seebeck coefficients, but their thermoelectric power factors are limited by the low electrical conductivity. We report transport measurements on Ca₃Co₄O₉ films on various perovskite substrates and show that reversible incorporation of oxygen into SrTiO₃ and LaAlO₃ substrates activates a parallel conduction channel for p-type carriers, greatly enhancing the thermoelectric performance of the film-substrate system at temperatures above 450 °C. Thin-film structures that take advantage of both electronic correlations and the high oxygen mobility of transition metal oxides thus open up new perspectives for thermopower generation at high temperature.