The light-induced deformation of a micro-textured photo-sensitive polymeric material is exploited for modifying the surface hydrophobicity along deterministic directions. Arrays of azopolymeric micro-pillars are fabricated over large area and irradiated with a green laser. Upon laser irradiation, the micro-pillars deform reversibly along a direction parallel to the laser polarization, resulting in elongated shapes with controllable eccentricity. Such a locally anisotropic topography induces a directional yet reversible change of hydrophobicity, as measured by contact angles varying within a range of 30°.

1.
M. A. C.
Stuart
,
W. T. S.
Huck
,
J.
Genzer
,
M.
Müller
,
C.
Ober
,
M.
Stamm
,
G. B.
Sukhorukov
,
I.
Szleifer
,
V. V.
Tsukruk
,
M.
Urban
,
F.
Winnik
,
S.
Zauscher
,
I.
Luzinov
, and
S.
Minko
,
Nat. Mater.
9
,
101
(
2010
).
2.
B.
Liu
,
Y.
He
,
Y.
Fan
, and
X.
Wang
,
Macromol. Rapid Commun.
27
,
1859
(
2006
).
3.
G.
Caputo
,
B.
Cortese
,
C.
Nobile
,
M.
Salerno
,
R.
Cingolani
,
G.
Gigli
,
P. D.
Cozzoli
, and
A.
Athanassiou
,
Adv. Funct. Mater.
19
,
1149
(
2009
).
4.
S.
Lee
,
H. S.
Kang
,
A.
Ambrosio
,
J. K.
Park
, and
L.
Marrucci
,
ACS Appl. Mater. Interfaces
7
,
8209
(
2015
).
5.
A.
Athanassiou
,
M.
Varda
,
E.
Mele
,
M. I.
Lygeraki
,
D.
Pisignano
,
M.
Farsari
,
C.
Fotakis
,
R.
Cingolani
, and
S. H.
Anastasiadis
,
Appl. Phys. A: Mater. Sci. Process.
83
,
351
(
2006
).
6.
C. J.
Barrett
,
J.
Mamiya
,
K. G.
Yager
, and
T.
Ikeda
,
Soft Matter
3
,
1249
(
2007
).
7.
A.
Priimagi
and
A.
Shevchenko
,
J. Polym. Sci., Part B: Polym. Phys.
52
,
163
(
2014
).
8.
G. S.
Kumar
and
D. C.
Neckers
,
Chem. Rev.
89
,
1915
(
1989
).
9.
A.
Natansohn
and
P.
Rochon
,
Chem. Rev.
102
,
4139
(
2002
).
10.
M. M.
Russew
and
S.
Hecht
,
Adv. Mater.
22
,
3348
(
2010
).
11.
J.
Groten
,
C.
Bunte
, and
J.
Rühe
,
Langmuir
28
,
15038
(
2012
).
12.
B.
Xin
and
J.
Hao
,
Chem. Soc. Rev.
39
,
769
(
2010
).
13.
K.
Ichimura
,
S.-K.
Oh
, and
M.
Nakagawa
,
Science
288
,
1624
(
2000
).
14.
C.
Radüge
,
G.
Papastavrou
,
D. G.
Kurth
, and
H.
Motschmann
,
Eur. Phys. J. E
10
,
103
(
2003
).
15.
C. L.
Feng
,
Y. J.
Zhang
,
J.
Jin
,
Y. L.
Song
,
L. Y.
Xie
,
G. R.
Qu
,
L.
Jiang
, and
D. B.
Zhu
,
Langmuir
17
,
4593
(
2001
).
16.
W.
Jiang
,
G.
Wang
,
Y.
He
,
X.
Wang
,
Y.
An
,
Y.
Song
, and
L.
Jiang
,
Chem. Commun.
3550
(
2005
).
17.
N.
Delorme
,
J.-F.
Bardeau
,
A.
Bulou
, and
F.
Poncin-Epaillard
,
Langmuir
21
,
12278
(
2005
).
18.
M. Y.
Paik
,
S.
Krishnan
,
F.
You
,
X.
Li
,
A.
Hexemer
,
Y.
Ando
,
S. H.
Kang
,
D. A.
Fischer
,
E. J.
Kramer
, and
C. K.
Ober
,
Langmuir
23
,
5110
(
2007
).
19.
T.
Sun
,
G.
Wang
,
L.
Feng
,
B.
Liu
,
Y.
Ma
,
L.
Jiang
, and
D.
Zhu
,
Angew. Chem., Int. Ed.
43
,
357
(
2004
).
20.
F.
Pirani
,
A.
Angelini
,
F.
Frascella
,
R.
Rizzo
,
S.
Ricciardi
, and
E.
Descrovi
,
Sci. Rep.
6
,
31702
(
2016
).
21.
J. T.
Yang
,
Z. H.
Yang
,
C. Y.
Chen
, and
D. J.
Yao
,
Langmuir
24
,
9889
(
2008
).
22.
S.
Piotto
,
S.
Concilio
,
L.
Sessa
,
P.
Iannelli
,
A.
Porta
,
E. C.
Calabrese
,
M. R.
Galdi
, and
L.
Incarnato
,
Polym. Compos.
34
,
1489
(
2013
).
23.
S.
Piotto
,
S.
Concilio
,
L.
Sessa
,
P.
Iannelli
,
A.
Porta
,
E. C.
Calabrese
,
A.
Zanfardino
,
M.
Varcamonti
, and
P.
Iannelli
,
Eur. J. Med. Chem.
68
,
178
(
2013
).
You do not currently have access to this content.