Substantial enhancement (36.7%) of the intrinsic electro-optic coefficient (r33) has been observed in lithium niobate channel waveguides, which are made to overlap with a pole-inhibited ferroelectric domain. The waveguide and the overlapping ferroelectric domain are both produced by a single UV irradiation process and are thus self-aligning. The enhancement of the electro-optic coefficient effect is attributed to strain, which is associated with the ferroelectric domain boundaries that contain the channel waveguide.

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