This work investigates non-rare-earth phosphor (Sr4Al14O25:Mn4+, 0.5%Mg) with intensively red luminescence as a luminescent down-shifting layer for perovskite solar cells. The power conversion efficiency of the fabricated device with a structure of NiO/CH3NH3PbI3/[6,6]-phenyl C61-butyric acid methyl ester/Au coated with phosphor layer shows a 10% increase as compared with that of the control devices. Importantly, the phosphor layer coating can realize UV-protection as well as waterproof capability, achieving a reduced moisture-degradation of CH3NH3PbI3 perovskite upon applying an UV irradiation. Therefore, perovskite devices using this luminescent coating show a combined enhancement in both UV down-shifting conversion and long term stability. This can be expanded as a promising encapsulation technique in the perovskite solar cell community.
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24 October 2016
Research Article|
October 26 2016
Phosphor coated NiO-based planar inverted organometallic halide perovskite solar cells with enhanced efficiency and stability Available to Purchase
Jin Cui;
Jin Cui
a)
1Wuhan National Laboratory for Optoelectronics, School of Optical and Electronic Information,
Huazhong University of Science and Technology
, Wuhan, Hubei 430074, People's Republic of China
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Pengfei Li;
Pengfei Li
a)
2The China-Germany Research Center for Photonic Materials and Device, The State Key Laboratory of Luminescent Materials and Devices, School of Materials Science and Engineering,
South China University of Technology
, Guangzhou 510640, People's Republic of China
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Zhifan Chen;
Zhifan Chen
a)
1Wuhan National Laboratory for Optoelectronics, School of Optical and Electronic Information,
Huazhong University of Science and Technology
, Wuhan, Hubei 430074, People's Republic of China
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Kun Cao;
Kun Cao
1Wuhan National Laboratory for Optoelectronics, School of Optical and Electronic Information,
Huazhong University of Science and Technology
, Wuhan, Hubei 430074, People's Republic of China
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Dan Li;
Dan Li
1Wuhan National Laboratory for Optoelectronics, School of Optical and Electronic Information,
Huazhong University of Science and Technology
, Wuhan, Hubei 430074, People's Republic of China
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Junbo Han;
Junbo Han
3Wuhan National High Magnetic Field Center,
Huazhong University of Science and Technology
, 1037 Luoyu Road, Wuhan, Hubei 430074, People's Republic of China
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Yan Shen;
Yan Shen
1Wuhan National Laboratory for Optoelectronics, School of Optical and Electronic Information,
Huazhong University of Science and Technology
, Wuhan, Hubei 430074, People's Republic of China
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Mingying Peng;
Mingying Peng
b)
2The China-Germany Research Center for Photonic Materials and Device, The State Key Laboratory of Luminescent Materials and Devices, School of Materials Science and Engineering,
South China University of Technology
, Guangzhou 510640, People's Republic of China
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Yong Qing Fu;
Yong Qing Fu
4Department of Physics and Electrical Engineering, Faculty of Engineering and Environment,
Northumbria University
, Newcastle Upon Tyne NE1 8ST, United Kingdom
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Mingkui Wang
Mingkui Wang
b)
1Wuhan National Laboratory for Optoelectronics, School of Optical and Electronic Information,
Huazhong University of Science and Technology
, Wuhan, Hubei 430074, People's Republic of China
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Jin Cui
1,a)
Pengfei Li
2,a)
Zhifan Chen
1,a)
Kun Cao
1
Dan Li
1
Junbo Han
3
Yan Shen
1
Mingying Peng
2,b)
Yong Qing Fu
4
Mingkui Wang
1,b)
1Wuhan National Laboratory for Optoelectronics, School of Optical and Electronic Information,
Huazhong University of Science and Technology
, Wuhan, Hubei 430074, People's Republic of China
2The China-Germany Research Center for Photonic Materials and Device, The State Key Laboratory of Luminescent Materials and Devices, School of Materials Science and Engineering,
South China University of Technology
, Guangzhou 510640, People's Republic of China
3Wuhan National High Magnetic Field Center,
Huazhong University of Science and Technology
, 1037 Luoyu Road, Wuhan, Hubei 430074, People's Republic of China
4Department of Physics and Electrical Engineering, Faculty of Engineering and Environment,
Northumbria University
, Newcastle Upon Tyne NE1 8ST, United Kingdom
a)
J. Cui, P. Li, and Z. Chen contributed equally to this work.
b)
Authors to whom correspondence should be addressed. Electronic addresses: [email protected] and [email protected]
Appl. Phys. Lett. 109, 171103 (2016)
Article history
Received:
April 28 2016
Accepted:
September 15 2016
Citation
Jin Cui, Pengfei Li, Zhifan Chen, Kun Cao, Dan Li, Junbo Han, Yan Shen, Mingying Peng, Yong Qing Fu, Mingkui Wang; Phosphor coated NiO-based planar inverted organometallic halide perovskite solar cells with enhanced efficiency and stability. Appl. Phys. Lett. 24 October 2016; 109 (17): 171103. https://doi.org/10.1063/1.4965838
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