Electrospinning (ES) enables simple production of fibers for broad applications (e.g., biomedical engineering, energy storage, and electronics). However, resulting structures are predominantly random; displaying significant disordered fiber entanglement, which inevitably gives rise to structural variations and reproducibility on the micron scale. Surface and structural features on this scale are critical for biomaterials, tissue engineering, and pharmaceutical sciences. In this letter, a modified ES technique using a rotating multi-nozzle emitter is developed and utilized to fabricate continuous micron-scaled polycaprolactone (PCL) ropes, providing control on fiber intercalation (twist) and structural order. Micron-scaled ropes comprising 312 twists per millimeter are generated, and rope diameter and pitch length are regulated using polymer concentration and process parameters. Electric field simulations confirm vector and distribution mechanisms, which influence fiber orientation and deposition during the process. The modified fabrication system provides much needed control on reproducibility and fiber entanglement which is crucial for electrospun biomedical materials.
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10 October 2016
Research Article|
October 10 2016
Continuous micron-scaled rope engineering using a rotating multi-nozzle electrospinning emitter
Chunchen Zhang;
Chunchen Zhang
1
Key Laboratory for Biomedical Engineering of Education Ministry of China
, Hangzhou 310027, People's Republic of China
2
Zhejiang Provincial Key Laboratory of Cardio-Cerebral Vascular Detection Technology and Medicinal Effectiveness Appraisal
, Hangzhou 310027, People's Republic of China
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Chengcheng Gao;
Chengcheng Gao
1
Key Laboratory for Biomedical Engineering of Education Ministry of China
, Hangzhou 310027, People's Republic of China
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Ming-Wei Chang;
Ming-Wei Chang
a)
1
Key Laboratory for Biomedical Engineering of Education Ministry of China
, Hangzhou 310027, People's Republic of China
2
Zhejiang Provincial Key Laboratory of Cardio-Cerebral Vascular Detection Technology and Medicinal Effectiveness Appraisal
, Hangzhou 310027, People's Republic of China
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Zeeshan Ahmad;
Zeeshan Ahmad
3Leicester School of Pharmacy,
De Montfort, University
, The Gateway, Leicester LE1 9BH, United Kingdom
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Jing-Song Li
Jing-Song Li
1
Key Laboratory for Biomedical Engineering of Education Ministry of China
, Hangzhou 310027, People's Republic of China
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a)
Author to whom correspondence should be addressed. Electronic mail: mwchang@zju.edu.cn.
Appl. Phys. Lett. 109, 151903 (2016)
Article history
Received:
August 08 2016
Accepted:
September 28 2016
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Citation
Chunchen Zhang, Chengcheng Gao, Ming-Wei Chang, Zeeshan Ahmad, Jing-Song Li; Continuous micron-scaled rope engineering using a rotating multi-nozzle electrospinning emitter. Appl. Phys. Lett. 10 October 2016; 109 (15): 151903. https://doi.org/10.1063/1.4964645
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