Solar cells based on organometal halide perovskites have recently become very promising among other materials because of their cost-effective character and improvements in efficiency. Such performance is primarily associated with effective light absorption and large diffusion length of charge carriers. Our paper is devoted to the explanation of large diffusion lengths in these systems. The transport mean free path of charged carriers in a perovskite/TiO2 heterojunction that is an important constituent of the solar cells have been analyzed. Large transport length is explained by the planar diffusion of indirect excitons. Diffusion length of the coupled system increases by several orders compared to single carrier length due to the correlated character of the effective field acting on the exciton.
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1 February 2016
Research Article|
February 04 2016
Large diffusion lengths of excitons in perovskite and TiO2 heterojunction
Zhyrair Gevorkian;
Zhyrair Gevorkian
1
Yerevan Physics Institute
, 0036 Yerevan, Armenia
2
Institute of Radiophysics and Electronics
, 0203 Ashtarak, Armenia
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Vladimir Gasparian;
Vladimir Gasparian
3
California State University
, Bakersfield, California 93311-1022, USA
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Yurii Lozovik
Yurii Lozovik
4Institute of Spectroscopy,
Academy of Sciences of Russia
, 142092 Troitsk, Moscow Region, Russian Federation
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Appl. Phys. Lett. 108, 051109 (2016)
Article history
Received:
November 10 2015
Accepted:
January 21 2016
Citation
Zhyrair Gevorkian, Vladimir Gasparian, Yurii Lozovik; Large diffusion lengths of excitons in perovskite and TiO2 heterojunction. Appl. Phys. Lett. 1 February 2016; 108 (5): 051109. https://doi.org/10.1063/1.4941242
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