We report a cost-effective approach to the fabrication of GaN based nanoporous structure for applications in renewable hydrogen production. Photoelectrochemical etching in a KOH solution has been employed to fabricate both GaN and InGaN/GaN nanoporous structures with pore sizes ranging from 25 to 60 nm, obtained by controlling both etchant concentration and applied voltage. Compared to as-grown planar devices the nanoporous structures have exhibited a significant increase of photocurrent with a factor of up to four times. An incident photon conversion efficiency of up to 46% around the band edge of GaN has been achieved.

1.
K.
Maeda
and
K.
Domen
,
J. Phys. Chem. Lett.
1
,
2655
(
2010
).
2.
Y.
Wu
,
M. K. Y.
Chan
, and
G.
Ceder
,
Phys. Rev. B
83
,
235301
(
2011
).
3.
Y.
Ling
,
G.
Wang
,
D.
Wheeler
,
J. Z.
Zhang
, and
Y.
Li
,
Nano Lett.
11
,
2119
(
2011
).
4.
K.
Sayama
,
A.
Nomura
,
T.
Arai
,
T.
Sugita
,
R.
Abe
,
M.
Yanagida
,
T.
Oi
,
Y.
Iwasaki
,
Y.
Abe
, and
H.
Sugihara
,
J. Phys. Chem. B
110
,
11352
(
2006
).
5.
E. J. W.
Crossland
,
N.
Noel
,
V.
Sivaram
,
T.
Leijtens
,
J. A.
Alexander-Webber
, and
H. J.
Smith
,
Nature
495
,
215
(
2013
).
6.
T. W.
Kim
and
K.
Choi
,
Science
343
,
990
(
2014
).
8.
X.
Li
,
Y.-W.
Kim
,
P. W.
Bohn
, and
I.
Adesida
,
Appl. Phys. Lett.
80
,
980
(
2002
).
9.
K.
Al-Heuseen
,
M. R.
Hashim
, and
N. K.
Ali
,
Appl. Surf. Sci.
257
,
6197
(
2011
).
10.
S. Y.
Bae
,
H. W.
Seo
,
J.
Park
,
H.
Yang
, and
B.
Kim
,
Chem. Phys. Lett.
376
,
445
(
2003
).
11.
K.
Al-heuseen
,
M. R.
Hashim
, and
N. K.
Ali
,
Physica B
405
,
3176
(
2010
).
12.
M.
Mynbaeva
,
N.
Bazhenov
,
K.
Mynbaev
,
V.
Evstropov
,
S. E.
Saddow
,
Y.
Koshka
, and
Y.
Melnik
,
Phys. Status Solidi B
228
,
589
(
2001
).
13.
M.
Mynbaeva
,
A.
Titkov
,
A.
Kryganovskii
,
V.
Ratnikov
,
K.
Mynbaev
,
H.
Huhtinen
,
R.
Laiho
, and
V.
Dmitriev
,
Appl. Phys. Lett.
76
,
1113
(
2000
).
14.
T.
Hisatomi
,
J.
Kubota
, and
K.
Domen
,
Chem. Soc. Rev.
43
,
7520
(
2014
).
15.
M. G.
Walter
,
E. L.
Warren
,
J. R.
McKone
,
S. W.
Boettcher
,
Q.
Mi
,
E. A.
Santori
, and
N. S.
Lewis
,
Chem. Rev.
110
,
6446
(
2010
).
16.
P. G.
Moses
and
C. G.
Van de Walle
,
Appl. Phys. Lett.
96
,
021908
(
2010
).
17.
Y. J.
Hwang
,
C. H.
Wu
,
C.
Hahn
,
H. E.
Jeong
, and
P.
Yang
,
Nano Lett.
12
,
1678
(
2012
).
18.
D.
Zhuang
and
J. H.
Edgar
,
Mater. Sci. Eng., R
48
,
1
(
2005
).
19.
K.
Ohkawa
,
W.
Ohara
,
D.
Uchida
, and
M.
Deura
,
Jpn. J. Appl. Phys., Part 1
52
,
08JH04
(
2013
).
20.
S.-Y.
Liu
,
J. K.
Sheu
,
C.-K.
Tseng
,
J.-C.
Ye
,
K. H.
Chang
,
M. L.
Lee
, and
W. C.
Lai
,
J. Electrochem. Soc.
157
,
B266
(
2010
).
21.
I.
Waki
,
D.
Cohen
,
R.
Lal
,
U.
Mishra
,
S. P.
DenBaars
, and
S.
Nakamura
,
Appl. Phys. Lett.
91
,
093519
(
2007
).
22.
L.
Wang
,
W.
Zhao
,
Z.-B.
Hao
, and
Y.
Luo
,
Chin. Phys. Lett.
28
,
057301
(
2011
).
23.
S.-W.
Ryu
,
Y.
Zhang
,
B.
Leung
,
C.
Yerino
, and
J.
Han
,
Semicond. Sci. Technol.
27
,
015014
(
2012
).
24.
J.
Benton
,
J.
Bai
, and
T.
Wang
,
Appl. Phys. Lett.
102
,
173905
(
2013
).
25.
W.-H.
Tu
,
Y.-K.
Hsu
,
C.-H.
Yen
,
C.-I.
Wu
,
J.-S.
Hwang
,
L.-C.
Chen
, and
K.-H.
Chen
,
Electrochem. Commun.
13
,
530
(
2011
).
26.
J.
Benton
,
J.
Bai
, and
T.
Wang
,
Appl. Phys. Lett.
103
,
133904
(
2013
).
27.
T.
Wang
,
J.
Bai
,
P. J.
Parbrook
, and
A. G.
Cullis
,
Appl. Phys. Lett.
87
,
151906
(
2005
).
28.
A. P.
Vajpeyi
,
S.
Tripathy
,
S. J.
Chua
, and
E. A.
Fitzgerald
,
Physica E
28
,
141
(
2005
).
29.
F. K.
Yam
,
Z.
Hassan
,
L. S.
Chuah
, and
Y. P.
Ali
,
Appl. Surf. Sci.
253
,
7429
(
2007
).
30.
K.
Fujii
and
K.
Ohkawa
,
Phys. Status Solidi C
3
,
2270
(
2006
).
31.
B.
Alotaibi
,
H. P. T.
Nguyen
,
S.
Zhao
,
M. G.
Kibria
,
S.
Fan
, and
Z.
Mi
,
Nano Lett.
13
,
4356
(
2013
).
You do not currently have access to this content.