Carbon microcoils (CMCs) have emerged as versatile material artifacts for a variety of applications due to their helical and spiral structures. Embedded in matrix, CMCs have already been demonstrated for their potential tactile/proximity sensor application. In this study, CMCs were prepared using a conventional chemical vapor deposition method, and then were functionalized with octadecylamine. Upon photoexcitation, the functionalized CMCs exhibited photoluminescence in the visible region, which has never been found before. Similar to carbon based nanoparticles, the photoluminescence of CMCs was attributed to electron-hole radiative recombination after surface passivation. The results suggested that this kind of fluorescent functionalized CMCs might be used as a promising class of optical agents for biological applications.

1.
K.
Kaneto
,
M.
Tsuruta
, and
S.
Motojima
,
Synth. Met.
103
(
1
),
2578
2579
(
1999
).
2.
Z.
Tianliang
,
W.
Yuehong
,
Z.
Kuangyu
,
L.
Qian
, and
T.
Ye
,
Chin. J. Aeronaut.
20
(
6
),
559
563
(
2007
).
3.
N.-K.
Chang
and
S.-H.
Chang
,
IEEE Trans. Nanotechnol.
7
(
2
),
197
201
(
2008
).
4.
X.
Chen
,
S.
Yang
, and
S.
Motojima
,
Mater. Lett.
57
(
1
),
48
54
(
2002
).
5.
Y.
Kato
,
N.
Adachi
,
T.
Okuda
,
T.
Yoshida
,
S.
Motojima
, and
T.
Tsuda
,
Jpn. J. Appl. Phys., Part 1
42
,
5035
5037
(
2003
).
6.
S.
Motojima
,
X.
Chen
,
S.
Yang
, and
M.
Hasegawa
,
Diamond Relat. Mater.
13
(
11
),
1989
1992
(
2004
).
7.
T.
Katsuno
,
X.
Chen
,
S.
Yang
, and
S.
Motojima
,
Diamond Relat. Mater.
16
(
4
),
1000
1003
(
2007
).
8.
K.
Yoshimura
,
K.
Nakano
,
T.
Miyake
,
Y.
Hishikawa
,
C.
Kuzuya
,
T.
Katsuno
, and
S.
Motojima
,
Carbon
45
(
10
),
1997
2003
(
2007
).
9.
K.
Yamauchi
,
T.
Imada
, and
T.
Asakura
,
J. Phys. Chem. B
109
(
37
),
17689
17692
(
2005
).
10.
C.
Kuzuya
,
M.
Kohda
,
Y.
Hishikawa
, and
S.
Motojima
,
Carbon
40
(
11
),
1991
2001
(
2002
).
11.
S.
Yang
,
X.
Chen
,
H.
Aoki
, and
S.
Motojima
,
Smart Mater. Struct.
15
(
3
),
687
694
(
2006
).
12.
L.
Cao
,
M. J.
Meziani
,
S.
Sahu
, and
Y.-P.
Sun
,
Acc. Chem. Res.
46
(
1
),
171
180
(
2013
).
13.
L.
Cao
,
S.
Sahu
,
P.
Anilkumar
,
C. Y.
Kong
, and
Y.-P.
Sun
,
MRS Bull.
37
(
12
),
1283
1289
(
2012
).
14.
V. N.
Mochalin
and
Y.
Gogotsi
,
J. Am. Chem. Soc.
131
(
13
),
4594
4595
(
2009
).
15.
C.
Liu
,
P.
Zhang
,
F.
Tian
,
W.
Li
,
F.
Li
, and
W.
Liu
,
J. Mater. Chem.
21
(
35
),
13163
13167
(
2011
).
16.
X.
Wang
,
L.
Cao
,
C. E.
Bunker
,
M. J.
Meziani
,
F.
Lu
,
E. A.
Guliants
, and
Y.-P.
Sun
,
J. Phys. Chem. C
114
(
49
),
20941
20946
(
2010
).
17.
H.
Bi
,
K.
Kou
,
A.
Rider
,
K.
Ostrikov
,
H.
Wu
, and
Z.
Wang
,
Appl. Surf. Sci.
255
(
15
),
6888
6893
(
2009
).
18.
Y.
Furuya
,
T.
Hashishin
,
H.
Iwanaga
,
S.
Motojima
, and
Y.
Hishikawa
,
Carbon
42
(
2
),
331
335
(
2004
).
19.
S.
Motojima
,
Y.
Itoh
,
S.
Asakura
, and
H.
Iwanaga
,
J. Mater. Sci.
30
(
20
),
5049
5055
(
1995
).
20.
X.
Chen
and
S.
Motojima
,
J. Mater. Sci.
34
(
22
),
5519
5524
(
1999
).
21.
A.
Cuesta
,
P.
Dhamelincourt
,
J.
Laureyns
,
A.
Martinez-Alonso
, and
J. M.
Tascón
,
J. Mater. Chem.
8
(
12
),
2875
2879
(
1998
).
22.
A.
Dandekar
,
R.
Baker
, and
M.
Vannice
,
Carbon
36
(
12
),
1821
1831
(
1998
).
23.
A.
Sharma
,
T.
Kyotani
, and
A.
Tomita
,
Carbon
38
(
14
),
1977
1984
(
2000
).
24.
A. K.
Kercher
and
D. C.
Nagle
,
Carbon
41
(
1
),
15
27
(
2003
).
25.
D.
Pan
,
L.
Guo
,
J.
Zhang
,
C.
Xi
,
Q.
Xue
,
H.
Huang
,
J.
Li
,
Z.
Zhang
,
W.
Yu
, and
Z.
Chen
,
J. Mater. Chem.
22
(
8
),
3314
3318
(
2012
).
26.
V.
Datsyuk
,
M.
Kalyva
,
K.
Papagelis
,
J.
Parthenios
,
D.
Tasis
,
A.
Siokou
,
I.
Kallitsis
, and
C.
Galiotis
,
Carbon
46
(
6
),
833
840
(
2008
).
27.
A.
Ferrari
and
J.
Robertson
,
Phys. Rev. B
61
(
20
),
14095
14107
(
2000
).
28.
A.
Cuesta
,
P.
Dhamelincourt
,
J.
Laureyns
,
A.
Martinez-Alonso
, and
J. D.
Tascón
,
Carbon
32
(
8
),
1523
1532
(
1994
).
29.
F.-H.
Ko
,
C.-Y.
Lee
,
C.-J.
Ko
, and
T.-C.
Chu
,
Carbon
43
(
4
),
727
733
(
2005
).
30.
A.
Rodríguez-Fortea
,
M.
Iannuzzi
, and
M.
Parrinello
,
J. Phys. Chem. C
111
(
5
),
2251
2258
(
2007
).
31.
F.
Tuinstra
and
J. L.
Koenig
,
J. Chem. Phys.
53
,
1126
1130
(
1970
).
32.
F.
Tuinstra
and
J. L.
Koenig
,
J. Compos. Mater.
4
,
492
499
(
1970
).
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