We report on the fabrication of graphene contact to GaN nanowire ensemble and on the demonstration of photodetectors using chemical vapor deposition-grown few-layered graphene as a transparent electrode. The optimization of the transfer method allowed to form a continuous contact to the nanowires over a large area. The adhesion energy of the graphene sheet to the nanowire ensemble is estimated to be 0.3–0.7 J/m2. Ultraviolet photodetectors with a room-temperature responsivity of ∼25 A/W at 357 nm were fabricated. The photocurrent spectrum shows that the device has a strong response up to 4.15 eV confirming a good transparency of the top graphene contact.
REFERENCES
1.
Y. J.
Hong
, W. H.
Lee
, Y.
Wu
, R. S.
Ruoff
, and T.
Fukui
, “van der Waals epitaxy of InAs nanowires vertically aligned on single-layer graphene
,” Nano Lett.
12
(3
), 1431
–1436
(2012
).2.
A. M.
Munshi
, D. L.
Dheeraj
, V. T.
Fauske
, D. C.
Kim
, A. T.
van Helvoort
, B. O.
Fimland
, and H.
Weman
, “Vertically aligned GaAs nanowires on graphite and few-layer graphene: Generic model and epitaxial growth
,” Nano Lett.
12
(9
), 4570
–4576
(2012
).3.
C.
Xie
, P.
Lv
, B.
Nie
, J.
Jie
, X.
Zhang
, Z.
Wang
, P.
Jiang
, Z.
Hu
, L.
Luo
, Z.
Zhu
, L.
Wang
, and C.
Wu
, “Monolayer graphene film/silicon nanowire array Schottky junction solar cells
,” Appl. Phys. Lett.
99
(13
), 133113
(2011
).4.
H.
Park
, S.
Chang
, J.
Jean
, J. J.
Cheng
, P. T.
Araujo
, M.
Wang
, M. G.
Bawendi
, M. S.
Dresselhaus
, V.
Bulovic
, and J.
Kong
, “Graphene cathode-based ZnO nanowire hybrid solar cells
,” Nano Lett.
13
(1
), 233
–239
(2013
).5.
D.
Choi
, M. Y.
Choi
, W. M.
Choi
, H. J.
Shin
, H. K.
Park
, J. S.
Seo
, J.
Park
, S. M.
Yoon
, S. J.
Chae
, Y. H.
Lee
, S. W.
Kim
, J. Y.
Choi
, S. Y.
Lee
, and J. M.
Kim
, “Fully rollable transparent nanogenerators based on graphene electrodes
,” Adv. Mater.
22
(19
), 2187
–2192
(2010
).6.
S. E.
Lee
, H. J.
Kim
, H.
Kim
, J. H.
Park
, and D. G.
Choi
, “Highly robust silicon nanowire/graphene core-shell electrodes without polymeric binders
,” Nanoscale
5
, 8986
(2013
).7.
S.
Kim
, H.
Choi
, M.
Jung
, S. Y.
Choi
, and S.
Ju
, “Hybrid nanowire–multilayer graphene film light-emitting sources
,” Nanotechnology
21
(42
), 425203
(2010
).8.
Y.
Ye
, L.
Gan
, L.
Dai
, H.
Meng
, F.
Wei
, Y.
Dai
, Z.
Shi
, B.
Yu
, X.
Guo
, and G.
Qin
, “Multicolor graphene nanoribbon/semiconductor nanowire heterojunction light-emitting diodes
,” J. Mater. Chem.
21
(32
), 11760
–11763
(2011
).9.
J.
Yi
, J. M.
Lee
, and W. I.
Park
, “Vertically aligned ZnO nanorods and graphene hybrid architectures for high-sensitive flexible gas sensors
,” Sens. Actuators B
155
(1
), 264
–269
(2011
).10.
H.
Lee
, K.
Heo
, J.
Park
, Y.
Park
, S.
Noh
, K. S.
Kim
, C.
Lee
, B. H.
Hong
, J.
Jian
, and S.
Hong
, “Graphene–nanowire hybrid structures for high-performance photoconductive devices
,” J. Mater. Chem.
22
(17
), 8372
–8376
(2012
).11.
X. W.
Fu
, Z. M.
Liao
, Y. B.
Zhou
, H. C.
Wu
, Y. Q.
Bie
, J.
Xu
, and D. P.
Yu
, “Graphene/ZnO nanowire/graphene vertical structure based fast-response ultraviolet photodetector
,” Appl. Phys. Lett.
100
(22
), 223114
(2012
).12.
H. X.
Chang
, Z. H.
Sun
, K. Y. F.
Ho
, X. M.
Tao
, F.
Yan
, W. M.
Kwok
, and Z. J.
Zheng
, “A highly sensitive ultraviolet sensor based on a facile in situ solution-grown ZnO nanorod/graphene heterostructure
,” Nanoscale
3
(1
), 258
(2011
).13.
F.
González-Posada
, R.
Songmuang
, M. D.
Hertog
, and E.
Monroy
, “Room-temperature photodetection dynamics of single GaN nanowires
,” Nano Lett.
12
(1
), 172
–176
(2012
).14.
A.
de Luna Bugallo
, M.
Tchernycheva
, G.
Jacopin
, L.
Rigutti
, F. H.
Julien
, S. T.
Chou
, Y. T.
Lin
, P. H.
Tseng
, and L. W.
Tu
, “Visible-blind photodetector based on p–i–n junction GaN nanowire ensembles
,” Nanotechnology
21
(31
), 315201
(2010
).15.
A. V.
Babichev
, V. E.
Gasumyants
, and V. Y.
Butko
, “Resistivity and thermopower of graphene made by chemical vapor deposition technique
,” J. Appl. Phys.
113
(7
), 076101
(2013
).16.
C.
Lee
, B. J.
Kim
, F.
Ren
, S. J.
Pearton
, and J.
Kim
, “Large-area suspended graphene on GaN nanopillars
,” J. Vac. Sci. Technol. B
29
(6
), 060601
(2011
).17.
Z.
Zong
, C. L.
Chen
, M. R.
Dokmeci
, and K. T.
Wan
, “Direct measurement of graphene adhesion on silicon surface by intercalation of nanoparticles
,” J. Appl. Phys.
107
(2
), 026104
(2010
).18.
J. S.
Bunch
and M. L.
Dunn
, “Adhesion mechanics of graphene membranes
,” Solid State Commun.
152
(15
), 1359
–1364
(2012
).19.
S.
Tongay
, M.
Lemaitre
, T.
Schumann
, K.
Berke
, B. R.
Appleton
, B.
Gila
, and A. F.
Hebard
, “Graphene/GaN Schottky diodes: Stability at elevated temperatures
,” Appl. Phys. Lett.
99
(10
), 102102
(2011
).20.
L.
Wang
, Y.
Zhang
, X.
Li
, Z.
Liu
, E.
Guo
, X.
Yi
, and G.
Wang
, “Interface and transport properties of GaN/graphene junction in GaN-based LEDs
,” J. Phys. D: Appl. Phys.
45
(50
), 505102
(2012
).21.
R.
Calarco
, M.
Marso
, T.
Richter
, A. I.
Aykanat
, R.
Meijers
, A.
v. d. Hart
, T.
Stoica
, and H.
Lüth
, “Size-dependent photoconductivity in MBE-grown GaN-nanowires
,” Nano Lett.
5
(5
), 981
–984
(2005
).22.
Q.
Bao
and K. P.
Loh
, “Graphene photonics, plasmonics, and broadband optoelectronic devices
,” ACS Nano
6
(5
), 3677
–3694
(2012
).23.
A.
Pospischil
, M.
Humer
, M. M.
Furchi
, D.
Bachmann
, R.
Guider
, T.
Fromherz
, and T.
Mueller
, “CMOS-compatible graphene photodetector covering all optical communication bands
,” Nature Photon.
7
, 892
(2013
);M.
Freitag
, T.
Low
, and P.
Avouris
, “Increased responsivity of suspended graphene photodetectors
,” Nano Lett.
13
(4
), 1644
–1648
(2013
).
[PubMed]
24.
L.
Polenta
, M.
Rossi
, A.
Cavallini
, R.
Calarco
, M.
Marso
, R.
Meijers
, T.
Richter
, T.
Stoica
, and H.
Lüth
, “Investigation on localized states in GaN nanowires
,” ACS Nano
2
, 287
–292
(2008
).25.
N. A.
Sanford
, P. T.
Blanchard
, K. A.
Bertness
, L.
Mansfield
, J. B.
Schlager
, A. W.
Sanders
, A.
Roshko
, B. B.
Burton
, and S. M.
George
, “Steady-state and transient photoconductivity in c-axis GaN nanowires grown by nitrogen-plasma-assisted molecular beam epitaxy
,” J. Appl. Phys.
107
(3
), 034318
(2010
).© 2013 AIP Publishing LLC.
2013
AIP Publishing LLC
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