We report thermal conductivity measurements of individual single crystalline Bi2Se3 nano-ribbon (NR) synthesized via the gold nanoparticle catalyzed vapor-liquid-solid mechanism. By using the four-probe third harmonic method, thermal conductivity of Bi2Se3 NRs was obtained in the temperature range of 10 K to 300 K. It is found that the measured thermal conductivities are nearly two orders of magnitude smaller than the bulk value and have a maximum thermal conductivity at temperature (around 200 K) greater than the bulk. The significant reduced thermal conductivity of NRs is attributed to enhanced phonon boundary scattering in nanostructured material.

1.
H.
Zhang
,
C.-X.
Liu
,
X.-L.
Qi
,
X.
Dai
,
Z.
Fang
, and
S.-C.
Zhang
,
Nature Phys.
5
(
6
),
438
442
(
2009
).
2.
Y.
Xia
,
D.
Qian
,
D.
Hsieh
,
L.
Wray
,
A.
Pal
,
H.
Lin
,
A.
Bansil
,
D.
Grauer
,
Y.
Hor
, and
R.
Cava
,
Nature Phys.
5
(
6
),
398
402
(
2009
).
3.
H.
Peng
,
K.
Lai
,
D.
Kong
,
S.
Meister
,
Y.
Chen
,
X. L.
Qi
,
S. C.
Zhang
,
Z. X.
Shen
, and
Y.
Cui
,
Nature Mater.
9
(
3
),
225
229
(
2009
).
4.
J.
Chen
,
H.
Qin
,
F.
Yang
,
J.
Liu
,
T.
Guan
,
F.
Qu
,
G.
Zhang
,
J.
Shi
,
X.
Xie
, and
C.
Yang
,
Phys. Rev. Lett.
105
(
17
),
176602
(
2010
).
5.
J.
Checkelsky
,
Y.
Hor
,
R.
Cava
, and
N.
Ong
,
Phys. Rev. Lett.
106
(
19
),
196801
(
2011
).
6.
H.
Tang
,
D.
Liang
,
R. L. J.
Qiu
and
X. P. A.
Gao
,
ACS Nano
5
(
9
),
7510
7516
(
2011
).
7.
S.
Mishra
,
S.
Satpathy
, and
O.
Jepsen
,
J. Phys.: Condens. Matter
9
,
461
(
1997
).
8.
R.
Venkatasubramanian
,
E.
Siivola
,
T.
Colpitts
, and
B.
O'quinn
,
Nature
413
,
597
(
2001
).
9.
10.
A.
Al Bayaz
,
A.
Giani
,
A.
Foucaran
,
F.
Pascal-Delannoy
, and
A.
Boyer
,
Thin Solid Films
441
(
1
),
1
5
(
2003
).
11.
F. J.
DiSalvo
,
Science
285
(
5428
),
703
706
(
1999
).
12.
J. R.
Szczech
,
J. M.
Higgins
, and
S.
Jin
,
J. Mater. Chem.
21
,
4037
4055
(
2011
).
13.
A.
Saramat
,
G.
Svensson
,
A.
Palmqvist
,
C.
Stiewe
,
E.
Mueller
,
D.
Platzek
,
S.
Williams
,
D.
Rowe
,
J.
Bryan
, and
G.
Stucky
,
J. Appl. Phys.
99
,
023708
(
2006
).
14.
M.
Dresselhaus
,
G.
Chen
,
Z.
Ren
,
G.
Dresselhaus
,
A.
Henry
and
J. P.
Fleurial
,
JOM
61
(
4
),
86
90
(
2009
).
15.
L. D.
Hicks
and
M. S.
Dresselhaus
,
Phys. Rev. B
47
(
19
),
12727
12731
(
1993
).
16.
J.
Zhou
,
C.
Jin
,
J. H.
Seol
,
X.
Li
, and
L.
Shi
,
Appl. Phys. Lett.
87
,
133109
(
2005
).
17.
D.
Li
,
Y.
Wu
,
P.
Kim
,
L.
Shi
,
P.
Yang
, and
A.
Majumdar
,
Appl. Phys. Lett.
83
,
2934
(
2003
).
18.
L.
Shi
,
Q.
Hao
,
C.
Yu
,
N.
Mingo
,
X.
Kong
, and
Z. L.
Wang
,
Appl. Phys. Lett.
84
,
2638
(
2004
).
19.
Y. F.
Lin
,
H. W.
Chang
,
S. Y.
Lu
, and
C.
Liu
,
J. Phys. Chem. C
111
(
50
),
18538
18544
(
2007
).
20.
K.
Kadel
,
L.
Kumari
,
W.
Li
,
J. Y.
Huang
, and
P. P.
Provencio
,
Nanoscale Res. Lett.
6
,
57
(
2011
).
21.
L.
Lu
,
W.
Yi
, and
D. L.
Zhang
,
Rev. Sci. Instrum.
72
(
7
),
2996
(
2001
).
22.
M.
Sakr
and
X.
Gao
,
Appl. Phys. Lett.
93
(
20
),
203503
(
2008
).
23.
D.
Liang
,
M. R.
Sakr
, and
X. P. A.
Gao
,
Nano Lett.
9
(
4
),
1709
1712
(
2009
).
24.
P. A.
Lin
,
D.
Liang
,
S.
Reeves
,
X. P. A.
Gao
, and
R. M.
Sankaran
,
Nano Lett.
12
(
1
),
315
320
(
2012
).
25.
See supplementary material at http://dx.doi.org/10.1063/1.4789530 for S1: additional SEM image of HF etched Bi2Se3 NR device. S2: error estimate of heat loss due to radiation. S3: control experiment on the thermal conductivity of silver nanowire.
26.
T. Y.
Choi
,
D.
Poulikakos
,
J.
Tharian
, and
U.
Sennhauser
,
Appl. Phys. Lett.
87
(
1
),
013108
(
2005
).
27.
T. Y.
Choi
,
D.
Poulikakos
,
J.
Tharian
, and
U.
Sennhauser
,
Nano Lett.
6
(
8
),
1589
1593
(
2006
).
28.
S.
Dhara
,
H. S.
Solanki
,
R. A.
Pawan
,
V.
Singh
,
S.
Sengupta
,
B. A.
Chalke
,
A.
Dhar
,
M.
Gokhale
,
A.
Bhattacharya
, and
M. M.
Deshmukh
,
Phys. Rev. B
84
(
12
),
121307
R
(
2011
).
29.
J.
Callaway
,
Phys. Rev.
113
(
4
),
1046
1051
(
1959
).
30.
J.
Navratil
,
J.
Horák
,
T.
Plecháček
,
S.
Kamba
,
P.
Lošt’ák
,
J.
Dyck
,
W.
Chen
, and
C.
Uher
,
J. Solid State Chem.
177
(
4
),
1704
1712
(
2004
).

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