Inspired by the gecko foot pad, we fabricated polystyrene-block-poly(N-isopropylacrylamide) (PS-b-PNIPAAm) copolymer pillar array to mimic climbing attitude of a gecko, alternately attach to and detach from a surface. The pillar array structure of the PS segment significantly enhances both of the hydrophilic and hydrophobic property of PNIPAAm segment tips at 25 and 50 °C, respectively, which could generate alternating adhesive forces of approximately 120 and 11 nN. The dramatic change in adhesive and friction force difference at 25 and 50 °C may guide the design of bio-inspired artificial analogues, which could approach gecko's climbing behavior.

1.
K.
Autumn
,
Y. A.
Liang
,
S. T.
Hsieh
,
W.
Zesch
,
W. P.
Chan
,
T. W.
Kenny
,
R.
Fearing
, and
R. J.
Full
,
Nature
405
,
681
685
(
2000
).
2.
A.
del Campo
,
C.
Greiner
,
I.
Alvarez
, and
E.
Arzt
,
Adv. Mater.
19
,
1973
1977
(
2007
).
3.
E.
Arzt
,
S.
Gorb
, and
R.
Spolenak
,
Proc. Natl. Acad. Sci. U.S.A.
100
,
10603
10606
(
2003
).
4.
H.
Zeng
,
N.
Pesika
,
Y.
Tian
,
B.
Zhao
,
Y.
Chen
,
M.
Tirrell
,
K. L.
Turner
, and
J. N.
Israelachvili
,
Langmuir
25
,
7486
7495
(
2009
).
5.
H.
Lee
,
B. P.
Lee
, and
P. B.
Messersmith
,
Nature
448
,
338
342
(
2007
).
6.
J.-K.
Chen
,
B.-J.
Bai
, and
F.-C.
Chang
,
Appl. Phys. Lett.
99
,
013701
(
2011
).
7.
J. K.
Chen
and
A. L.
Zhuang
,
Colloid Polym. Sci.
289
,
1283
1294
(
2011
).
8.
N. A.
Peppas
,
J. Z.
Hilt
,
A.
Khademhosseini
, and
R.
Langer
,
Adv. Mater.
18
,
1345
1360
(
2006
).
9.
C. H.
Chan
,
J. K.
Chen
, and
F. C.
Chang
,
Sens. Actuators, B
133
,
327
332
(
2008
).
10.
J.-K.
Chen
,
C.-Y.
Hsieh
,
C.-F.
Huang
, and
P.-M.
Li
,
J. Colloid Interface Sci.
338
,
428
434
(
2009
).
11.
T.-Y.
Chen
and
J.-K.
Chen
,
Colloid Polym. Sci.
289
,
433
445
(
2011
).
12.
J.-K.
Chen
and
J.-Y.
Li
,
Sens. Actuators, B
150
,
314
320
(
2010
).
13.
J.-K.
Chen
,
Z.-Y.
Chen
,
H.-C.
Lin
,
P.-D.
Hong
, and
F.-C.
Chang
,
ACS Appl. Mater. Interfaces
1
,
1525
1532
(
2009
).
14.
J. K.
Chen
and
T.-Y.
Chen
,
J. Colloid Interface Sci.
355
,
359
367
(
2011
).
15.
G.
Li
,
J.
Fan
,
R.
Jiang
, and
Y.
Gao
,
Chem. Mater.
16
,
1835
1837
(
2004
).
16.
R. N.
Wenzel
,
Ind. Eng. Chem.
28
,
988
(
1936
).
17.
A. B. D.
Cassie
, and
S.
Baxter
,
Trans. Faraday Soc.
40
,
546
(
1944
).
18.
J. K.
Chen
and
A.-L.
Zhuang
,
J. Phys. Chem. C
114
,
11801
11809
(
2010
).
19.
J. K.
Chen
,
C. Y.
Hsieh
,
C. F.
Huang
,
P. M.
Li
,
S. W.
Kuo
, and
F. C.
Chang
,
Macromolecules
41
,
8729
8736
(
2008
).
20.
W.
Zhao
,
L.
Wang
, and
Q.
Xue
,
ACS Appl. Mater. Interfaces
2
,
788
794
(
2010
).
21.
J.-K.
Chen
,
B.-J.
Bai
, and
F.-C.
Chang
,
J. Phys. Chem. C
115
,
21341
21350
(
2011
).
22.
H.
Tu
,
C. E.
Heitzman
, and
P. V.
Braun
,
Langmuir
20
,
8313
8320
(
2004
).
23.
J.-K.
Chen
,
J.-H.
Wang
,
S.-K.
Fan
, and
J.-Y.
Chang
,
J. Phys. Chem. C
116
,
6980
6992
(
2012
).
24.
L.
Li
,
Y.
Zhu
,
B.
Li
, and
C.
Gao
,
Langmuir
24
,
13632
13639
(
2008
).
25.
Y. F.
Mo
,
W. J.
Zhao
,
D. M.
Huang
,
F.
Zhao
, and
M. W.
Bai
,
Ultramicroscopy
109
,
247
252
(
2009
).
26.
S. Y.
Song
,
S. L.
Ren
,
J. Q.
Wang
,
S. R.
Yang
, and
J. Y.
Zhang
,
Langmuir
22
,
6010
6015
(
2006
).
27.
W. J.
Zhao
,
M.
Zhu
,
Y. F.
Mo
, and
M. W.
Bai
,
Colloids. Surf. A
332
,
78
82
(
2009
).
You do not currently have access to this content.