Structure and magnetotransport properties of epitaxial nanocomposite La_0.67Ca_0.33MnO₃:SrTiO₃ thin films grown by a chemical solution approach Available to Purchase

Epitaxial La_0.67Ca_0.33MnO₃:SrTiO₃ (LCMO:STO) composite thin films have been grown on single crystal LaAlO₃(001) substrates by a cost effective polymer-assisted deposition method. Both x-ray diffraction and high-resolution transmission electron microscopy confirm the growth of epitaxial films with an epitaxial relationship between the films and the substrates as (002)_film||(002)_sub and [202]_film||[202]_sub. The transport property measurement shows that the STO phase significantly increases the resistivity and enhances the magnetoresistance (MR) effect of LCMO and moves the metal-insulator transition to lower temperatures. For example, the MR values measured at magnetic fields of 0 and 3 T are −44.6% at 255 K for LCMO, −94.2% at 125 K for LCMO:3% STO, and −99.4% at 100 K for LCMO:5% STO, respectively.