Environmental monitoring has been one of the key to provide better safety measure in various sectors of life. The most famously featured technology in this area is the gas detecting system. It serves not only in an early-warning application, but also a continuous mean to provide background check of the atmospheric status of a specific area ranges. According to their principals, gas sensors can be separated into two categories; the conductive metal-oxides and the electrochemical-type, with the latter gaining more recognition over the last decade as the future standard component in any gas sensing apparatus. Within this article, the whole concept of an electrochemical gas sensor will be presented, including the basic science and the basic electronical engineering that runs the device. The main concern will be fallen onto a specific amperometric-type sensor as the most common electrochemical sensor in the market. Ultimately, since there are multiple parts that comprise a single electrochemical sensor, a special section will be written within this article to show the array of materials that are responsible to the sensing capabilities of the sensor, particularly in the area of sensitivity and selectivity of gases.

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