It is well known that, in the high-speed melt spinning of bicomponent fibers, structure development behaviors of individual components are different from those in the single-component spinning of respective components because of the kinematic mutual interaction of the two components in the spinning process. With the aim of obtaining the fibers of unique characteristics, sheath/core bicomponent fibers consisting of the low and high molecular weight poly(L-lactide)s (LowMw-PLLA and HighMw-PLLA) as the sheath and core components were prepared through the high-speed melt spinning process. Both PLLAs have the high optical purity with the D-lactide content of less than 0.5 %. The sheath/core ratio was set to 50/50. The attainable maximum take-up velocities, which are the measure of the spinnability, were 8, 9 and 10 km/min for the HighMw-PLLA, Sheath/core and LowMw-PLLA, respectively. Thinning and solidification behavior of the spin-line analysed through the on-line measurement of the spin-line diameter indicated that the neck-like deformation started to occur from lower take-up velocity in the order of HighMw-PLLA, Sheath/core and LowMw-PLLA. Position of the neck-like deformation at the same take-up velocity was closer to the spinneret with the same order. Different fiber formation behaviors in terms of the starting of the orientation-induced crystallization between the three types of spinning wert also confirmed from the Wide-angle X-ray Diffraction analysis of the as-spun fibers. After the starting of the orientation-induced crystallization of the sheath/core bicomponent fibers, the birefringence of the HighMw-PLLA component was higher than that of the single-component HighMw-PLLA fibers, whereas the birefringence of the LowMw-PLLA component was lower than that of the single component Low-Mw-PLLA. It is interesting to note that the birefringence of the LowMw-PLLA component decreased significantly with the increase of take-up velocity and reached close to zero at the highest take-up velocity of 9 km/min.
High-speed melt spinning of sheath/core bicomponent fibers of poly(L-lactide)s with different molecular weight
N. Roungpaisan, W. Takarada, T. Kikutani; High-speed melt spinning of sheath/core bicomponent fibers of poly(L-lactide)s with different molecular weight. AIP Conf. Proc. 5 February 2019; 2065 (1): 030030. https://doi.org/10.1063/1.5088288
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