This paper aims to synthesize nanocomposites based in nitrate hydroxide salts intercalated with organic ultraviolet (UV) absorbent molecule to use in lining of cables based in polyethylene that could be apply in the electrical center. The synthesis procedure was performed using urea hydrolysis of Ni (II)nitrate melts at 160 °C and its modification carryout in an oven at 70 and 120 °C in a simple process. The modified structure and thermal stability of the hydroxide salt with formula Ni(PABA)0,16(OH)1,84called NiHAB were characterized by XRD, FTIR, TGA, DRUV-Vis. Its studies suggest that NiHAB may have potential application as a UV absorber, because it improves this property when mixing with polyethylene, when the UV spectra shows a big band that covered the region between 400-200 nm

Topics
Thermodynamic states and processes, Ultraviolet light, Ultraviolet spectra, Nanocomposites, Supramolecular chemistry, Transition metals, Polymers, Chemical compounds
1.
Biswick
,
T.
,
Jones
,
W.
,
Pacula
,
A.
 &
Serwicka
 
E.
 
Synthesis, characterisation and anion exchange properties of copper, magnesium, zinc and nickel hydroxy nitrates
.
Journal of Solid State Chemistry
,
179
,
49
–
55
(
2006
).
https://doi.org/10.1016/j.jssc.2005.09.040
Google Scholar
Crossref
Search ADS
 
2.
Coutinho
,
F.
,
Mello
,
I.
, &
Maria
,
L
 
Polietileno: principais tipos, propriedades e aplicacoes
.
Polimeros: Ciência e tecnologia
,
3
,
1
–
13
(
2003
).
Google Scholar
 
3.
Crepaldi
,
E. L.
, &
Barros Valim
,
J.
 
Hidroxidos duplos lamelares: Síntese, estrutura, propriedades e aplicacoes
.
Quimica Nova
,
3
(
21
) (
1998
).
Google Scholar
 
4.
Guadalupe Carbaljal
,
G.
,
Gundapa
,
S.
, &
Wypych
,
F.
 
Layered hydroxide salts: Synthesis, properties and potential applications
.
Solid state Ionics
(
178
),
1143
–
1162
(
2007
).
https://doi.org/10.1016/j.ssi.2007.04.016
Google Scholar
Crossref
Search ADS
 
5.
Li
,
Y.
,
Tang
,
L.-p.
,
Zhou
,
W.
, &
Wang
,
X.-R.
 
Fabrication of intercalated p-aminobenzoic acid into ZnTi layered double hydroxide and its application as UV absorbent
.
Chinsese Chemical Letters
(
2016
).
Google Scholar
 
6.
Munaro
,
M.
,
Souza
,
G.
, &
Akcelrud
,
L.
 
Estudo da degradacao do polietileno usado em revestimento de cabos elétricos
.
Belo Horizonte: 7CBPol.
 
2003
, pp.
65
–
67
.
Google Scholar
 
7.
Nakamoto
,
K
 (
2009
).
Infrared and raman spectra of inorganic and coordination compounds part A.
 
New York
:
J. Wiley
.
Google Scholar
 
8.
Rajamthi
,
M.
, &
Vishnu Lamath
,
P.
 (
2001
).
Urea hydrolysis (II) nitrate melts: Synthesis of novel hydroxides and hydroxynitrates
.
International Journal of inorganic materials
,
2
,
901
–
906
(1968).
https://doi.org/10.1016/S1466-6049(01)00090-3
Google Scholar
Crossref
Search ADS
 
9.
Trindade Cursino
,
A.
,
Ferreira da Costa Gardolinski
,
J.
, &
Wypych
,
F.
 
Intercalation of anionic organic ultravioletec ray absorbers into layered zinc hydroxude nitrate
.
Journal of Colloid and Interface science
(
347
),
49
–
55
(
2010
).
https://doi.org/10.1016/j.jcis.2010.03.007
Google Scholar
 
10.
Yousi
,
E.
, &
Haddad
,
R
 
Phodegradacao and photosbtabilization of polyxmer: especially polyestyrene
.
Springer plus
,
2
(
398
) (
2013
).
Google Scholar
 
11.
Zimmermann
,
A.
,
Jaerger
,
S.
,
Faria Zawadzki
,
S.
, &
Wypych
,
F.
 
Synthetic zinc layered hydroxide salts intercalated with anionic azo dyes as fillers into high-density polyethyelene composites: first insights
.
J. Polym Res
(
20
),
224
(
2013
).
https://doi.org/10.1007/s10965-013-0224-3
Google Scholar
 
© 2019 Author(s).
2019
Author(s)