Rapid room-temperature synthesis of hierarchical porous metal organic framework (H-MOFs) with high space-time yield (STY) is highly valuable for their widespread applications. Here we developed a simple and facile strategy to rapidly synthesize hierarchical porous Cu-BTC at room temperature by using a cooperative template strategy. The synthesis time was shortened dramatically to within 1 minute, and the resulting material contains micro-, meso-, and macropore structure together with excellent thermal stability. The space-time yield (STY) was as high as 1.0 × 104 kg·m-3·d-1, at least four times higher than any previously reports. This work offers a new direction for the facile and effective synthesis of H-MOFs with high STY.
REFERENCES
1.
G.
Maurin
, C.
Serre
, A.
Cooper
, G.
Ferey
, The new age of MOFs and of their porous-related solids
, Chem. Soc. Rev.
46
(2017
) 3104
–3107
.2.
J.R.
Long
, O.M.
Yaghi
, The pervasive chemistry of metal-organic frameworks
, Chem. Soc. Rev.
38
(2009
) 1213
–1214
.3.
M.
Rubio-Martinez
, C.
Avci-Camur
, A.W.
Thornton
, I.
Imaz
, D.
Maspoch
, M.R.
Hill
, New synthetic routes towards MOF production at scale
, Chem. Soc. Rev.
46
(2017
) 3453
–3480
.4.
B.
Liu
, Q.
Duan
, C.
Li
, Z.
Zhu
, H.
Xi
, Y.
Qian
, Template synthesis of the hierarchically structured MFI zeolite with nanosheet frameworks and tailored structure
, New J. Chem.
38
(2014
) 4380
–4387
.5.
Q.
Sun
, Z.
Dai
, X.
Meng
, F.-S.
Xiao
, Porous polymer catalysts with hierarchical structures
, Chem. Soc. Rev.
44
(2015
) 6018
–6034
.6.
L.-B.
Sun
, J.-R.
Li
, J.
Park
, H.-C.
Zhou
, Cooperative template-directed assembly of mesoporous metal–organic frameworks
, J. Am. Chem. Soc.
134
(2011
) 126
–129
.7.
Y.-B.
Huang
, M.
Shen
, X.
Wang
, P.-C.
Shi
, H.
Li
, R.
Cao
, Hierarchically micro-and mesoporous metal– organic framework-supported alloy nanocrystals as bifunctional catalysts: Toward cooperative catalysis
, J. Catal.
330
(2015
) 452
–457
.8.
C.
Duan
, F.
Li
, H.
Zhang
, J.
Li
, X.
Wang
, H.
Xi
, Template synthesis of hierarchical porous metal-organic frameworks with tunable porosity
, RSC Adv.
7
(2017
) 52245
–52251
.9.
D.
Bradshaw
, S.
El-Hankari
, L.
Lupica-Spagnolo
, Supramolecular templating of hierarchically porous metal– organic frameworks
, Chem. Soc. Rev.
43
(2014
) 5431
–5443
.10.
J.
Zhao
, W.T.
Nunn
, P.C.
Lemaire
, Y.
Lin
, M.D.
Dickey
, C.J.
Oldham
, H.J.
Walls
, G.W.
Peterson
, M.D.
Losego
, G.N.
Parsons
, Facile Conversion of Hydroxy Double Salts to Metal-Organic Frameworks Using Metal Oxide Particles and Atomic Layer Deposition Thin-Film Templates
, J. Am. Chem. Soc.
137
(2015
) 13756
–13759
.11.
K.S.
Sing
, Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984
), Pure. Appl. Chem.
57
(1985
) 603
–619
.12.
J.
Huo
, M.
Brightwell
, S.
El Hankari
, A.
Garai
, D.
Bradshaw
, A versatile, industrially relevant, aqueous room temperature synthesis of HKUST-1 with high space-time yield
, J. Mater. Chem. A
1
(2013
) 15220
–15223
.
This content is only available via PDF.
© 2018 Author(s).
2018
Author(s)
