Fabrication and characterization of perovskite-based solar cell using TiO2 as an electron transporting layer and 2,2’,7,7’-tetrakis-(N,N-di-4-methoxyphenylamino) -9,9’-spirobifluorene as a hole transporting layer (HTL) have been performed for improving the photovoltaic performance. The purpose of the present study is to investigate a role of halogen doping using iodine, bromine and chlorine compounds on the photovoltaic performance such as short-circuit current density, open−circuit voltage, conversion efficiency and microstructures of HC(NH2)2PbI3-x-yBrxCly perovskite solar cells. The photovoltaic properties were investigated by current-voltage curves under light irradiation, incident photon to current conversion efficiency, X-ray diffraction and optical microscopy. The photovoltaic performance and optical properties were influenced by halogen addition into the perovskite crystal structure.

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