We have developed thermal impulse sensors to measure and record temperature and heating duration in explosive fireballs. The functionality of these sensors is similar to that of our temperature-only sensors – rare-earth ions are used to monitor temperature-induced phase changes. However, in this case two sensor materials, p-Dy:Y2O3 and p-Eu:ZrO2, with different phase change kinetics are mixed. In addition, a fluorescence standard, Ho:ZrO2, is included. Also, using laser heating, we have now reduced the shortest heating duration for our calibration measurements from the previously reported 2 s to 100 ms, and we have evaluated these sensors for temperatures between 400 °C and 900 °C, and heating times between 100 ms and 1000 ms. Using spectral matching, we determine the temperature and heating duration.

1.
C.
Milby
,
D.
Stamatis
,
J.
Carney
,
J.
Horn
,
J.
Lightstone
,
Efficacy of Energetic Formulations in the Defeat of Bio Agents
, in
Central States Section of the Combustion Institute Spring Technical Meeting 2012 - Combustion Fundamentals and Applications
,
Dayton, Ohio, USA
,
2012
, pp.
861
868
.
2.
A. K.
Mishra
and
L.
Huang
,
Small
11
,
361
366
(
2015
).
3.
H.
Sun
,
M.
Liu
,
X.
Sun
,
G.
Wang
, and
J.
Lian
,
The Journal of Physical Chmistry C
117
,
3366
3373
(
2013
).
4.
E. G.
Yukihara
,
A. C.
Coleman
,
S.
Bastani
,
T.
Gustafson
,
J. J.
Talghader
,
A.
Daniels
,
D.
Stamatis
,
J. M.
Lightstone
,
C.
Milby
, and
F. R.
Svingala
,
Journal of Luminescence
165
,
145
152
(
2015
).
5.
H.
Eilers
,
R.
Gunawidjaja
,
T.
Myint
,
J.
Lightstone
, and
J.
Carney
,
AIP Conference Proceedings
1426
,
1577
1580
(
2012
).
6.
C.
Görller-Walrand
and
K.
Binnemans
, “Rationalization of Crystal-Field Parametrization”, in
Handbook on the Physics and Chemistry of Rare-Earths
, edited by
K. A.
Gschneidner
, Jr.
and
L.
Eyring
(
Elsevier Science Publishers B.V
.;
1996
).
7.
T.
Myint
,
R.
Gunawidjaja
, and
H.
Eilers
,
Journal of Physical Chemistry C
116
,
1687
1693
(
2012
)
8.
T.
Myint
,
R.
Gunawidjaja
, and
H.
Eilers
,
Journal of Physical Chemistry C
116
,
21629
21634
(
2012
).
9.
R.
Gunawidjaja
,
T.
Myint
, and
H.
Eilers
,
Chemical Physics Letters
515
,
122
126
(
2011
).
10.
R.
Gunawidjaja
,
H.
Diez-y-Riega
, and
H.
Eilers
,
“Advanced Luminescent Core/Shell Temperature Sensors for Use in Explosions
” in
International Detonation Symposium-2014, Conference Proceedings
.
11.
R.
Gunawidjaja
,
H.
Diez-y-Riega
, and
H.
Eilers
,
Journal of Solid State Chemistry
229
,
350
357
(
2015
).
12.
D.
Patel
,
N.
King
, and
C.
Mingo
,
“Synthesis, Spectroscopic Studies and AFM Analysis of Ho3+ Doped Zirconium Oxide Nanoparticles
”, in
Optical Components and Materials VI-2009, SPIE Conference Proceedings
Vol.
7212
, 72121E, edited by
S.
Jiang
,
Michel J. F.
Digonnet
,
J. W.
Glesener
,
J. C.
Dries
.
13.
F.
Vetrone
,
J.-C.
Boyer
,
J. A.
Capobianco
,
A.
Speghini
and
M.
Bettinelli
,
Nanotechnology
15
,
75
81
(
2004
).
14.
W.-N.
Wang
,
W.
Widiyastuti
,
T.
Ogi
,
I. W.
Lenggoro
, and
K.
Okuyama
,
Chemistry of Materials
19
,
1723
1730
(
2007
).
15.
V.K.
Pecharsky
and
P.Y.
Zavalij
in
Fundamentals of Powder Diffraction and Structural Characterization of Materials
(
Kluwer Academic Publishers
,
Boston/Dordrecht/London
,
2003
).
This content is only available via PDF.