In this work, metallic tools are surface modified with different perfluoroalkylsilanes from the liquid phase. In particular, these molecular coatings are investigated with respect to their anti-adhesive properties, durability and long-term stability. Steel surfaces are treated with acid (dilute HNO3) to increase the density of surface hydroxyl group. The modification of the metal surface is achieved by subsequent reaction of the surface hydroxyl groups with organo-silanes. The characterization of the modified surfaces is performed by X-ray photoelectron spectroscopy (XPS), and contact angle measurements. The work aims at strategies to reduce demolding forces in injection molding processes.

1.
D.M.
Mattox
,
Handbook of Physical Vapor Deposition (PVD) Processing: Film Formation, Adhesion, Surface Preparation and Contamination Control
,
Westwood, N.J.
:
Noyes Publications
(
1998
).
2.
C.
Donnet
,
A.
Erdemir
,
Tribological Letters
17
,
389
397
(
2004
).
3.
J.
Vetter
,
J. of Adv. Mater.
31
,
41
47
(
1999
).
4.
S.
PalDey
,
S.C.
Deevi
,
Mat. Sci. Eng. A
342
,
58
79
(
2003
).
5.
K.
Bobzin
,
N.
Bagcivan
, and
P.
Immich
 et al.,
J. Materials Processing Soc.
209
, pp.
65
170
(
2009
).
6.
G.-Y.
Jung
,
Z.
Li
,
W.
Wu
,
Y.
Chen
,
D.L.
Olynick
,
S.Y.
Wang
,
W. M.
Tong
, and
R.S.
Williams
,
Langmuir
21
,
1158
1161
(
2005
).
7.
G.
Pritchard
, Coupling agents, in:
G.
Pritchard
(Ed.),
Chapman & Hall
,
London
,
189
196
(
1998
).
8.
E.
Plueddemann
,
Silane Coupling Agents
,
Plenum Press
,
New York
(
1982
).
9.
T.
Van Schaftinghen
,
C.
Le Pen
,
H.
Terryn
and
F.
Horzenberger
,
Electrochim. Acta
49
,
2997
3004
(
2004
).
10.
E.
Petrie
,
Primers and adhesion promoters
,
McGraw-Hill
,
New York
,
277
305
(
2007
).
This content is only available via PDF.