Solid particles have been shown to be able to operate at temperatures higher than 1000 °C in concentrated solar power (CSP) systems with thermal energy storage (TES). Thermochemical energy storage (TCES) using metal oxides have also found to be advantageous over sensible and latent heat storage concepts. This paper investigates the compatibility of the inner lining material of a TES tank with the reduced metal oxide. Two candidate metal oxides are investigated against six candidate lining materials. XRD results for both the materials are investigated and compared before and after the reduction of metal oxide at 1000°C in the presence of lining material. It is found that the lining material rich in zirconia is suitable for such application. Silicon Carbide is also found non-reacting with one of the metal oxides so it needs to be further investigated with other candidate metal oxides.

1.
A. J.
Schrader
,
A. P.
Muroyama
,
P. G.
Loutzenhiser
, “
Solar electricity via an Air Brayton cycle with an integrated two-step thermochemical cycle for heat storage based on Co3O4/CoO redox reactions: Thermodynamic analysis
”,
Solar Energy
118
,
485
495
(
2015
).
2.
C.
Pagkoura
,
G.
Karagiannakis
,
A.
Zygogianni
,
S.
Lorentzou
,
M.
Kostoglou
,
A. G.
Konstandopoulos
,
M.
Rattenburry
,
J. W.
Woodhead
, “
Cobalt oxide based structured bodies as redox thermochemical heat storage medium for future CSP plants
”,
Solar Energy
108
,
146
163
(
2014
).
3.
M.
Linder
, “14-Using thermochemical reactions in thermal energy storage systems”, in
Advances in Thermal Energy Storage Systems: Methods and Applications
, edited by
L. F.
Cabeza
(
Woodhead Publishing Series in Energy: Number 66
,
2015
), pp.
357
374
.
4.
W. D.
Steinmann
, “21 - Thermal energy storage systems for concentrating solar power (CSP) technology”, in
Advances in Thermal Energy Storage Systems: Methods and Applications
, edited by
L. F.
Cabeza
(
Woodhead Publishing Series in Energy: Number 66
,
2015
), pp.
511
531
.
5.
E.
Alonso
,
C. P.
Rábago
,
J.
Licurgo
,
E.
Fuentealba
,
C. A.
Estrada
, “
First experimental studies of solar redox reactions of copper oxides for thermochemical energy storage
”,
Solar Energy
115
,
297
305
(
2015
).
6.
P.
Pardo
,
A.
Deydier
,
Z.
Anxionnaz-Minvielle
,
S.
Rouge
,
M.
Cabassud
and
P.
Cognet
, “
A review on high temperature thermochemical heat energy storage
”,
Renewable and Sustainable Energy Reviews
32
,
591
610
(
2014
).
8.
B.
Ehrhart
,
E.
Coker
,
N.
Siegel
, and
A.
Weimer
. “
Thermochemical Cycle of a Mixed Metal Oxide for Augmentation of Thermal Energy Storage in Solid Particles
.”
Energy Procedia
49
,
762
771
(
2014
).
9.
A.
Carrillo
,
J.
Moya
,
A.
Bayón
,
P.
Jana
,
A.
Víctor
,
M.
Romero
,
J.
Gonzalez-Aguilar
,
D.
Serrano
,
P.
Pizarro
, and
J.
Coronado
. “
Thermochemical energy storage at high temperature via redox cycles of Mn and Co oxides: Pure oxides versus mixed ones
”,
Solar Energy Materials and Solar Cells
123
,
47
57
(
2014
).
This content is only available via PDF.