We present here a short overview of the main classes of methods used to generate diamond nanostructures. The described methodologies, namely the CVD techniques, the explosive reactions, the laser-induced processes and the plasma treatments, offer the feasibility to produce nanosized diamonds in forms of powders or films, to modulate size, shape and structure of individual nanograins or of nanodiamond aggregates, to build complex architectures. A proper design and a subsequent controlled production of diamond structures at the nanoscale are strict requirements for the transition from fundamental material research to real-world applications.

1.
Mann
,
I.
,
Murad
,
E.
,
Czechowski
,
A.
(
2007
).
Nanoparticles in the inner solar system
.
Planetary and Space Science
,
55
(
9
),
1000
1009
2.
Huss
,
G.R.
,
Ott
,
U.
,
Koscheev
,
A.P.
(
2008
).
Noble gases in presolar diamonds III: Implications of ion implantation experiments with synthetic nanodiamonds
.
Meteoritics & Planetary Science
,
43
(
11
),
1811
1826
3.
Kinzie
,
C.R.
,
Hee
,
S.S.Q.
,
Stich
,
A.
, et al (
2014
).
Nanodiamond-rich layer across three continents consistent with major cosmic impact at 12,800 Cal BP
.
The Journal of Geology
, (
122
),
475
506
4.
Chen
,
H.G.
,
Chang
,
L.
(
2004
).
Characterization of diamond nanoplatelets
.
Diamond and related materials
,
13
(
4
),
590
594
5.
Spitsyn
,
B.V.
,
Deryaguin
,
B.V.
USSR Author’s Certificate No 339134
,
Appl. 964957/716358
6.
Spitsyn
,
B.V.
,
Bouilov
,
L.L.
,
Derjaguin
,
B.V.
(
1981
).
Vapor growth of diamond on diamond and other surfaces
.
Journal of Crystal Growth
,
52
,
219
226
.
7.
Molinari
,
E.
,
Polini
,
R.
,
Terranova
,
M.L.
,
Ascarelli
,
P.
,
Fontana
,
S.
(
1992
).
Uncoupling crystal growth and nucleation in the deposition of diamond from the gas phase
.
Journal of materials research
,
7
(
07
),
1778
1787
8.
Butler
,
J.E.
,
Sumant
,
A.V.
(
2008
).
The CVD of nanodiamond materials
.
Chemical Vapor Deposition
,
14
(
7-8
),
145
160
9.
Gruen
,
D.M.
(
1999
).
Nanocrystalline Diamond Films 1
.
Annual Review of Materials Science
,
29
(
1
),
211
259
10.
Corrigan
T.D.
,
Krauss
A.R.
,
Gruen
D.M.
,
.
Auciello
O.,
Chang
R.P.H.
(
2000
)
Low temperature growth of ultrananocrystalline diamond on glass substrates for field emission applications
.
Materials Research Society Symposium – Proceedings
593
,
233
236
11.
Gruen
,
D. M.
(
2001
).
Ultrananocrystalline diamond in the laboratory and the cosmos
.
MRS bulletin
,
26
(
10
),
771
776
12.
Arenal
,
R.
,
Bruno
,
P.
,
Miller
,
D.J.
,
Bleuel
,
M.
,
Lal
,
J.
,
Gruen
,
D.M.
(
2007
).
Diamond nanowires and the insulator-metal transition in ultrananocrystalline diamond films
.
Physical Review B
,
75
(
19
),
195431
13.
Orlanducci
,
S.
,
Fiori
,
A.
,
Sessa
,
V.
,
Tamburri
,
E.
,
Toschi
,
F.
,
Terranova
,
M.L.
(
2008
).
Nanocrystalline diamond films grown in nitrogen rich atmosphere: structural and field emission properties
.
Journal of Nanoscience and Nanotechnology
,
8
(
6
),
3228
3234
14.
Terranova
,
M.L.
,
Orlanducci
,
S.
,
Rossi
,
M.
,
Tamburri
,
E.
(
2015
)
Nanodiamonds for Field Emission: State of the Art
.
Nanoscale
,
7
,
5094
5114
15.
Cianchetta
,
I.
,
Orlanducci
,
S.
,
Tamburri
,
E.
,
Gugliemotti
,
V.
, &
Terranova
,
M. L.
(
2013
).
Diamond-based systems: innovative materials for photonics
.
7th European Conference on Antennas and Propagation-EUCAP 2013
,
6546316
,
498
499
16.
Cianchetta
,
I.
,
Tomellini
,
M.
,
Tamburri
,
E.
,
Gay
,
S.
,
Porchetta
,
D.
,
Terranova
,
M. L.
,
Orlanducci
,
S.
(
2014
).
Can a metal nanoparticle based catalyst drive the selective growth of bright SiV color centers in CVD diamonds?
.
Journal of Materials Chemistry C
,
2
(
45
),
9666
9673
17.
Toschi
,
F.
,
Orlanducci
,
S.
,
Sessa
,
V.
,
Tamburri
,
E.
,
Terranova
,
M.L.
,
Rossi
,
M.
(
2007
). Preparation routes by CVD and functional characterizations of conductive diamond films containing metal dispersion.
C.R.
Kleijn
(ed.).
EuroCVD-16 Book of Extended Abstracts
,
Delft University of Technology
,
The Netherlands
.
141
143
18.
Danilenko
,
V.V.
(
2004
).
On the history of the discovery of nanodiamond synthesis
.
Physics of the Solid State
,
46
(
4
),
595
599
19.
Dolmatov
,
V.Y.
,
Yur’ev
,
G.S.
,
Myllymäki
,
V.
,
Korolev
,
K.M.
(
2013
).
Why detonation nanodiamonds are small
.
Journal of Superhard Materials
,
35
(
2
),
77
82
20.
Greiner
,
N.R.
,
Phillips
,
D.S.
,
Johnson
,
J.D.
,
Volk
,
F.
(
1988
).
Diamonds in detonation soot
.
Nature
333
,
440
442
21.
Shenderova
,
O. A.
,
Gruen
,
D. M.
(
2012
).
Ultrananocrystalline diamond: synthesis, properties and applications
.
William
Andrew
Ed.
22.
Chang
,
L. Y.
,
Ōsawa
,
E.
,
Barnard
,
A. S.
(
2011
).
Confirmation of the electrostatic self-assembly of nanodiamonds
.
Nanoscale
,
3
(
3
),
958
962
23.
Terranova
,
M. L.
,
Orlanducci
,
S.
,
Tamburri
,
E.
,
Guglielmotti
,
V.
,
Toschi
,
F.
,
Hampai
,
D.
,
Rossi
,
M.
(
2008
).
Polycrystalline diamond on self-assembled detonation nanodiamond: a viable route for fabrication of all-diamond preformed microcomponents
.
Nanotechnology
,
19
(
41
),
415601
24.
Mochalin
,
V.N.
,
Shenderova
,
O.
,
Ho
,
D.
, &
Gogotsi
,
Y.
(
2012
).
The properties and applications of nanodiamonds
.
Nature nanotechnology
,
7
(
1
),
11
23
25.
Shalaginov
,
M. Y.
,
Ishii
,
S.
,
Liu
,
J.
,
Irudayaraj
,
J.
,
Lagutchev
,
A.
,
Kildishev
,
A. V.
,
Shalaev
,
V. M.
(
2013
).
Broadband enhancement of spontaneous emission from nitrogen-vacancy centers in nanodiamonds by hyperbolic metamaterials
.
Applied Physics Letters
,
102
(
17
),
173114
26.
Gerasin
,
V.A.
,
Antipov
,
E.M.
,
Karbushev
,
V.V.
,
Kulichikhin
,
V.G.
,
Karpacheva
,
G.P.
,
Talroze
,
E.V.
,
Kudryavtsev
,
Y.V.
(
2013
)
Russian Chemical Reviews
,
82
(
4
)
303
27.
Tamburri
,
E.
,
Guglielmotti
,
V.
,
Matassa
,
R.
, et al (
2014
).
Detonation nanodiamonds tailor the structural order of PEDOT chains in conductive coating layers of hybrid nanoparticles
.
Journal of Materials Chemistry C
,
2
(
19
),
3703
3716
28.
Tamburri
,
E.
,
Guglielmotti
,
V.
,
Orlanducci
,
S.
, et al (
2012
).
Nanodiamond-mediated crystallization in fibers of PANI nanocomposites produced by template-free polymerization: Conductive and thermal properties of the fibrillar networks
.
Polymer
,
53
(
19
),
4045
4053
29.
Tamburri
,
E.
,
Orlanducci
,
S.
,
Guglielmotti
,
V.
, et al (
2011
).
Engineering detonation nanodiamond–Polyaniline composites by electrochemical routes: Structural features and functional characterizations
.
Polymer
,
52
(
22
),
5001
5008
30.
Vaijayanthimala
,
V.
,
Chang
,
H.C.
(
2009
).
Functionalized fluorescent nanodiamonds for biomedical applications
.
Future Med.
4
,
47
55
31.
Purtov
,
K.V.
,
Petunin
,
A.I.
,
Burov
,
A.E.
,
Puzyr
,
A.P.
,
Bondar
,
V.S.
(
2010
)
Nanodiamonds as carriers for address delivery of biologically active substances
.
Nanoscale Res Let.
5
,
631
636
32.
Alhaddad
,
A.
,
Adam
,
M.P.
,
Botsoa
, et al (
2011
).
Nanodiamond as a vector for siRNA delivery to Ewing sarcoma cells
.
Small
,
7
,
3087
3095
33.
Zhu
,
Y.
,
Li
,
J.
,
Li
,
W.
, et al (
2012
).
The biocompatibility of nanodiamonds and their application in drug delivery systems
.
Theranostics
,
2
,
302
312
34.
Gismondi
,
A.
,
Reina
,
G.
,
Orlanducci
,
S.
, et al (
2015
).
Nanodiamonds coupled with plant bioactive metabolites: A nanotech approach for cancer therapy
.
Biomaterials
,
38
,
22
35
35.
Reina
,
G.
,
Orlanducci
,
S.
,
Cairone
,
C.
, et al (
2015
).
Rhodamine/Nanodiamond as a System Model for Drug Carrier
.
Journal of Nanoscience and Nanotechnology
,
15
(
2
),
1022
1029
36.
Zeng
,
H.
,
Du
,
X. W.
,
Singh
,
S. C.
,
Kulinich
,
S. A.
,
Yang
,
S.
,
He
,
J.
,
Cai
,
W.
(
2012
).
Nanomaterials via laser ablation/irradiation in liquid: a review
.
Advanced Functional Materials
,
22
(
7
),
1333
1353
37.
Yang
,
G.W.
,
Wang
,
J.B.
,
Liu
,
Q.X.
(
1998
).
Preparation of nano-crystalline diamonds using pulsed laser induced reactive quenching
.
Journal of Physics: Condensed Matter
,
10
(
35
),
7923
38.
Askarian
,
G.
,
Chanturiia
,
G.
,
Prokhorov
,
A.
,
Shipulo
,
G. P.
(
1963
).
The effects of a laser beam in a liquid (Effervescence, scattering and photohydraulic effects in transparent and absorbing liquids, due to intense ruby laser beam)
.
Soviet Physics-JETP
,
17
,
1463
1465
39.
Askaryan
G.
(
1966
).
Self-focusing of a light beam upon excitation of the atoms and molecule of the medium in the beam
.
JETP Lett.
4
,
270
272
40.
Chiao
,
R.Y.
,
Garmire
,
E.
,
Townes
,
C.H.
(
1964
).
Self-trapping of optical beams
.
Physical Review Letters
,
13
(
15
),
479
.
41.
Zousman
,
B.
,
Levinson
,
O.
(
2012
).
Monodispersed Nanodiamonds Produced by Laser Ablation
.
MRS Proceedings
1452
,
mrss12
1452
42.
Baidakova
,
M.V.
,
Kukushkina
,
Y.A.
, Sitnikova, et al (
2013
).
Structure of nanodiamonds prepared by laser synthesis
.
Physics of the Solid State
,
55
(
8
),
1747
1753
43.
Perevedentseva
,
E.
,
Peer
,
D.
,
Uvarov
,
V.
,
Zousman
,
B.
,
Levinson
,
O.
(
2015
).
Nanodiamonds of Laser Synthesis for Biomedical Applications
.
Journal of Nanoscience and Nanotechnology
,
15
(
2
),
1045
1052
.
44.
Panich
,
A.M.
,
Shames
,
A.I.
,
Zousman
,
B.
,
Levinson
,
O.
(
2012
).
Magnetic resonance study of nanodiamonds prepared by laser-assisted technique
.
Diamond and Related Materials
,
23
,
150
153
45.
Ostrikov
,
K.
(
2008
).
Plasma Nanoscience
.
John Wiley & Sons
.
46.
Plasma Processing of Nanomaterials
.
R.M.
Sankaran
Ed,
CRC Press
,
Boca Raton
,
2012
.
47.
Orlanducci
,
S.
,
Guglielmotti
,
V.
,
Cianchetta
,
I.
,
Sessa
,
V.
,
Tamburri
,
E.
,
Toschi
,
F.
,
Terranova
,
M.L.
,
Rossi
,
M.
(
2012
).
One-step growth and shaping by a dual-plasma reactor of diamond nanocones arrays for the assembling of stable cold cathodes
.
Nanoscience and Nanotechnology Letters
,
4
(
3
),
338
343
.
48.
Orlanducci
,
S.
,
Guglielmotti
,
V.
,
Sessa
,
V.
,
Tamburri
,
E.
,
Terranova
,
M.L.
,
Toschi
,
F.
,
Rossi
,
M.
2012
.
Materials Research Society Symposium – Proceedings
.
1395
,
93
98
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