In this paper, we employ a new approximate analytical method called the optimal homotopy asymptotic method (OHAM) to solve steady state heat transfer problem in slabs. The heat transfer problem is modeled using nonlinear two-point boundary value problem. Using OHAM, we obtained the approximate analytical solution for dimensionless temperature with different values of a parameter ε. Further, the OHAM results for dimensionless temperature have been presented graphically and in tabular form. Comparison has been provided with existing results from the use of homotopy perturbation method, perturbation method and numerical method. For numerical results, we used Runge-Kutta Fehlberg fourth-fifth order method. It was found that OHAM produces better approximate analytical solutions than those which are obtained by homotopy perturbation and perturbation methods, in the sense of closer agreement with results obtained from the use of Runge-Kutta Fehlberg fourth-fifth order method.

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