Photomodulation Raman spectroscopy (PM‐RS) has been employed to investigate the effect of the interfacial minority carrier traps in metal: n‐type GaAs interfaces; using the forbidden LO phonon scattering as a prob. Photomodulating‐pumping beam (PMB) will decrease the interfacial field and consequently the intensity of forbidden LO scattering. Two molecular beam epitaxy junctions of 80 A° Au on n‐type GaAs (001) substrate with two different doping densities were used. The change in the band bending has been obtained as a function of the photomodulating intensity for the low doping case. The minority carrier’s lifetime was also determined through dynamical measurements for the PM‐RS intensity.

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