This research activity proposes to assess the influence of nanoparticle morphology on the specific heat capacity and melting entropies of nanomaterials using Differential Scanning Calorimetry (DSC). Several varieties of nanoparticles, including spherical, rod-shaped, and cuboidal particles, were created and examined, exhibiting their diverse thermal properties. In particular, rod-shaped nanoparticles had a somewhat lower specific heat capacity of 0.31 J/g°C, while spherical nanoparticles had an average specific heat capacity of 0.38 J/g°C. Cuboidal nanoparticles, on the other hand, had a substantially higher specific heat capacity, with an average of 0.45 J/g°C. Furthermore, the analysis of melting entropy data indicated significant discrepancies across types. Spherical nanoparticles, for example, had an entropy of 17.9 J/g°C on average, rod-shaped nanoparticles had an entropy of 17.2 J/g°C, and cuboidal nanoparticles had a substantially higher entropy of 23.6 J/g°C. The findings show that shape has a considerable effect on thermal features, in addition to the link between nanoparticle form, surface area-to-volume ratios, and distinct thermal behaviors. Understanding these interactions allows for the tweaking of designs in nanomaterial engineering for applications requiring precise thermal characteristics.

1.
Gao
,
Y.
;
Zhao
,
B.
;
Vlassak
,
J.J.
;
Schick
,
C.
Reprint of: Nanocalorimetry: Door Opened for in Situ Material Characterization under Extreme Non-Equilibrium Conditions
.
Prog Mater Sci
2021
,
120
, doi:.
2.
Desai
,
F.J.
;
Uddin
,
M.N.
;
Rahman
,
M.M.
;
Asmatulu
,
R.
A Critical Review on Improving Hydrogen Storage Properties of Metal Hydride via Nanostructuring and Integrating Carbonaceous Materials
.
Int J Hydrogen Energy
2023
,
48
,
29256
29294
, doi:.
3.
Panahi-Sarmad
,
M.
;
Goodarzi
,
V.
;
Amirkiai
,
A.
;
Noroozi
,
M.
;
Abrisham
,
M.
;
Dehghan
,
P.
;
Shakeri
,
Y.
;
Karimpour-Motlagh
,
N.
;
Poudineh Hajipoor
,
F.
;
Ali Khonakdar
,
H.
; et al
Programing Polyurethane with Systematic Presence of Graphene-Oxide (GO) and Reduced Graphene-Oxide (RGO) Platelets for Adjusting of Heat-Actuated Shape Memory Properties
.
Eur Polym J
2019
,
118
,
619
632
, doi:.
4.
Skrbek
,
K.
;
Bartůněk
,
V.
;
Sedmidubský
,
D.
Molten Salt-Based Nanocomposites for Thermal Energy Storage: Materials, Preparation Techniques and Properties
.
Renewable and Sustainable Energy Reviews
2022
,
164
, doi:.
5.
Mezzetta
,
A.
;
Łuczak
,
J.
;
Woch
,
J.
;
Chiappe
,
C.
;
Nowicki
,
J.
;
Guazzelli
,
L.
Surface Active Fatty Acid ILs: Influence of the Hydrophobic Tail and/or the Imidazolium Hydroxyl Functionalization on Aggregates Formation
.
J Mol Liq
2019
,
289
, doi:.
6.
Gupta
,
A.
;
Mekonnen
,
T.H.
Cellulose Nanocrystals Enabled Sustainable Polycaprolactone Based Shape Memory Polyurethane Bionanocomposites
.
J Colloid Interface Sci
2022
,
611
,
726
738
, doi:.
7.
Kumar
,
K.
;
Chowdhury
,
A.
Pushing the Limits of Analytical Characterization Tools: How Much Is Too Much?
Handbook on Miniaturization in Analytical Chemistry: Application of Nanotechnology
2020
,
239
275
, doi:.
8.
Dima
,
C.
;
Assadpour
,
E.
;
Dima
,
S.
;
Jafari
,
S.M.
Characterization and Analysis of Nanomaterials in Foods
.
Handbook of Food Nanotechnology: Applications and Approaches
2020
,
577
653
, doi:.
9.
Karchoubi
,
F.
;
Afshar Ghotli
,
R.
;
Pahlevani
,
H.
;
Baghban Salehi
,
M.
New Insights into Nanocomposite Hydrogels; a Review on Recent Advances in Characteristics and Applications
.
Advanced Industrial and Engineering Polymer Research
2023
, doi:.
10.
Liu
,
Y.
;
Yu
,
K.
;
Gao
,
X.
;
Ren
,
M.
;
Jia
,
M.
;
Yang
,
Y.
Enhanced Thermal Properties of Hydrate Salt/Poly (Acrylate Sodium) Copolymer Hydrogel as Form-Stable Phase Change Material via Incorporation of Hydroxyl Carbon Nanotubes
.
Solar Energy Materials and Solar Cells
2020
,
208
, doi:.
11.
Pielichowski
,
K.
;
Pielichowska
,
K.
Polymer Nanocomposites
.
Handbook of Thermal Analysis and Calorimetry
2018
,
6
,
431
485
, doi:.
12.
Mansfield
,
E.
;
Banash
,
M.
Thermal Analysis of Nanoparticles: Methods, Kinetics, and Recent Advances
.
Modeling, Characterization, and Production of Nanomaterials: Electronics, Photonics, and Energy Applications, Second Edition
2022
,
535
547
, doi:.
13.
Kalidasan
,
B.
;
Pandey
,
A.K.
;
Saidur
,
R.
;
Mishra
,
Y.N.
;
Ma
,
Z.
;
Tyagi
,
V. V.
Thermal Performance and Corrosion Resistance Analysis of Inorganic Eutectic Phase Change Material with One Dimensional Carbon Nanomaterial
.
J Mol Liq
2023
,
391
, doi:.
14.
Wong
,
T. Lo
;
Vallés
,
C.
;
Nasser
,
A.
;
Abeykoon
,
C.
A Critical Experimental Evaluation of Hexagonal Boron Nitride, Graphene Oxide and Graphite as Thermally Conductive Fillers in Organic PCMs
.
J Energy Storage
2023
,
72
, doi:.
15.
Wesolowski
,
M.
DSC of Low Molecular Mass Organic Materials and Pharmaceuticals
.
Handbook of Differential Scanning Calorimetry: Techniques, Instrumentation, Inorganic, Organic and Pharmaceutical Substances
2023
,
485
658
, doi:.
16.
Amirkiai
,
A.
;
Abrisham
,
M.
;
Panahi-Sarmad
,
M.
;
Xiao
,
X.
;
Alimardani
,
A.
;
Sadri
,
M.
Tracing Evolutions of Elastomeric Composites in Shape Memory Actuators: A Comprehensive Review
.
Mater Today Commun
2021
,
28
, doi:.
17.
Korczeniewski
,
E.
;
Bryk
,
P.
;
Koter
,
S.
;
Kowalczyk
,
P.
;
Zięba
,
M.
;
Łępicka
,
M.
;
Kurzydłowski
,
K.J.
;
Markiewicz
,
K.H.
;
Wilczewska
,
A.Z.
;
Kujawski
,
W.
; et al
Are Nanohedgehogs Thirsty? Toward New Superhydrophobic and Anti-Icing Carbon Nanohorn-Polymer Hybrid Surfaces
.
Chemical Engineering Journal
2022
,
446
, doi:.
18.
Parameshwaran
,
R.
;
Kalaiselvam
,
S.
Nanomaterial-Embedded Phase-Change Materials (PCMs) for Reducing Building Cooling Needs
.
Eco-efficient Materials for Mitigating Building Cooling Needs: Design, Properties and Applications
2015
,
402
439
, doi:.
19.
Amirkiai
,
A.
;
Panahi-Sarmad
,
M.
;
Sadeghi
,
G.M.M.
;
Arjmand
,
M.
;
Abrisham
,
M.
;
Dehghan
,
P.
;
Nazockdast
,
H.
Microstructural Design for Enhanced Mechanical and Shape Memory Performance of Polyurethane Nanocomposites: Role of Hybrid Nanofillers of Montmorillonite and Halloysite Nanotube
.
Appl Clay Sci
2020
,
198
, doi:.
20.
de Souza
,
J.F.
; da
Silva Pontes
,
K.
;
Alves
,
T.F.R.
;
Torqueti de Barros
,
C.
;
Amaral
,
V.A.
; de
Moura Crescencio
,
K.M.
;
Rios
,
A.C.
;
Batain
,
F.
;
Souto
,
E.B.
;
Severino
,
P.
; et al
Structural Comparison, Physicochemical Properties, and in Vitro Release Profile of Curcumin-Loaded Lyotropic Liquid Crystalline Nanoparticle: Influence of Hydrotrope as Interface Stabilizers
.
J Mol Liq
2020
,
306
, doi:.
21.
Zhu
,
L.
;
Li
,
C.
;
Yun
,
Q.
;
Han
,
S.
;
Lv
,
Y.
;
Lu
,
Q.
;
Chen
,
J.
Recent Advances of Rh-Based Intermetallic Nanomaterials for Catalytic Applications
.
Chinese Chemical Letters
2023
,
34
, doi:.
22.
Ali
,
H.M.
;
Rehman
,
T. ur
;
Arıcı
,
M.
;
Said
,
Z.
;
Duraković
,
B.
;
Mohammed
,
H.I.
;
Kumar
,
R.
;
Rathod
,
M.K.
;
Buyukdagli
,
O.
;
Teggar
,
M.
Advances in Thermal Energy Storage: Fundamentals and Applications
.
Prog Energy Combust Sci
2024
,
100
, doi:.
23.
Yang
,
J. hui
;
Zhang
,
Y. sheng
;
Xue
,
F.
;
Liu
,
D. feng
;
Zhang
,
N.
;
Huang
,
T.
;
Wang
,
Y.
Structural Relaxation and Dielectric Response of PVDF/PMMA Blend in the Presence of Graphene Oxide
.
Polymer (Guildf)
2021
,
229
, doi:.
24.
Abrisham
,
M.
;
Panahi-Sarmad
,
M.
;
Mir
Mohamad
Sadeghi
,
G.
;
Arjmand
,
M.
;
Dehghan
,
P.
;
Amirkiai
,
A.
Microstructural Design for Enhanced Mechanical Property and Shape Memory Behavior of Polyurethane Nanocomposites: Role of Carbon Nanotube, Montmorillonite, and Their Hybrid Fillers
.
Polym Test
2020
,
89
, doi:.
25.
Specific Heat and Melting Entropy of Nanomaterials: Investigating the Influence of Shape via Differential Scanning Calorimetry (DSC) - Search
| ScienceDirect.Com Available online: https://www.sciencedirect.com/search?qs=Specific%20Heat%20and%20Melting%20Entropy%20of%20Nanomaterials%3A%20Investigating%20the%20Influence%20of%20Shape%20via%20Differential%20Scanning%20Calorimetry%20%28DSC%29 (accessed on 26 November 2023).
26.
Dosawada
,
P.S.
;
Sharma
,
M.
;
Shukla
,
A.K.
;
Choudhary
,
T.
Review on Influence of Nanomaterials on Thermal Energy Storage Methods
.
Mater Today Proc
2023
,
78
,
580
593
, doi:.
27.
Saood
,
A.
;
Khan
,
A.H.
;
Equbal
,
M.I.
;
Saxena
,
K.K.
;
Prakash
,
C.
;
Vatin
,
N.I.
;
Dixit
,
S.
Influence of Fiber Angle on Steady-State Response of Laminated Composite Rectangular Plates
.
Materials
2022
,
15
, doi:.
28.
Miroshnikova
,
T.K.
;
Kirichenko
,
I.A.
;
Dixit
,
S.
Analytical Aspects of Anti-Crisis Measures of Public Administration
.
UPRAVLENIE / MANAGEMENT (Russia)
2023
,
10
,
5
13
, doi:.
29.
Gera
,
R.
;
Yadav
,
R.
;
Khera
,
G.S.
;
Saxena
,
A.
;
Chadha
,
P.
;
Dixit
,
S.
;
Yuliya Sergeevna
,
L.
A Systematic Literature Review of Supply Chain Management Practices and Performance
.
Mater Today Proc
2022
,
69
,
624
632
, doi:.
30.
Jaswal
,
A.
;
Kishore
,
K.
;
Singh
,
A.
;
Singh
,
J.
;
Dixit
,
S.
;
Kumar
,
K.
;
Sinha
,
M.K.
Synthesis and Characterization of Highly Transparent and Superhydrophobic Zinc Oxide (ZnO) Film
.
Lecture Notes in Mechanical Engineering
2023
,
119
127
, doi:.
31.
Singh
,
J.
;
Bisht
,
V.S.
;
Bhandari
,
P.
;
Kumar
,
K.
;
Singh
,
J.
;
Alam
,
T.
;
Dixit
,
S.
;
Singh
,
S.
;
Khusnutdinov
,
R.
Computational Parametric Investigation of Solar Air Heater with Dimple Roughness in S-Shaped Pattern
.
International Journal on Interactive Design and Manufacturing
2023
, doi:.
32.
Haq
,
Md.Z. ul
;
Sood
,
H.
;
Kumar
,
R.
Effect of Using Plastic Waste on Mechanical Properties of Fly Ash Based Geopolymer Concrete
.
Mater Today Proc
2022
.
33.
Kumar
,
A.
;
Mathur
,
N.
;
Rana
,
V.S.
;
Sood
,
H.
;
Nandal
,
M.
Sustainable Effect of Polycarboxylate Ether Based Admixture: A Meticulous Experiment to Hardened Concrete
.
Mater Today Proc
2022
.
34.
Nandal
,
M.
;
Sood
,
H.
;
Gupta
,
P.K.
;
Haq
,
M.Z.U.
Morphological and Physical Characterization of Construction and Demolition Waste
.
Mater Today Proc
2022
.
35.
Kumar
,
S.
;
Chopra
,
A.
;
Haq
,
M.Z.U.
Experimental Investigation on Marble Dust, Rice Husk Ash, And Fly Ash Based Geopolymer Brick
.
36.
Rana
,
V.S.
;
ul haq
,
M.Z.
;
Mathur
,
N.
;
Khera
,
G.S.
;
Dixit
,
S.
;
Singh
,
S.
;
Prakash
,
A.
;
Viktorovna
,
G.V.
;
Soloveva
,
O. V
;
Solovev
,
S.A.
Assortment of Latent Heat Storage Materials Using Multi Criterion Decision Making Techniques in Scheffler Solar Reflector
.
International Journal on Interactive Design and Manufacturing (IJIDeM)
2023
,
1
15
.
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