Using Electrochemical Impedance Spectroscopy (EIS), this study analyzes the corrosion resistance of novel coating materials such as Polyurethane-Based Epoxy, Ceramic Nano-Coating, Graphene-Enhanced Polymer, and Zinc-Aluminum Alloy. The characteristics research indicates notable differences, with Ceramic Nano-Coating demonstrating a significant 40% increase in hardness (500 HV) and Graphene-Enhanced Polymer exhibiting a remarkable 20% rise in adhesion strength (18 MPa) when compared to Polyurethane-Based Epoxy. Ceramic Nano-Coating demonstrated a remarkable 900% increase in testing time, according to the EIS criteria. The EIS findings show that Ceramic Nano-Coating has a 40% decrease in corrosion rate (0.03 mpy), confirming its higher resistance. Cross-sectional study reveals improved structural integrity, especially in the Graphene-Enhanced Polymer, which has a stunning 100% decrease in porosity (2%). This multifaceted investigation not only advances scientific knowledge of corrosion resistance, but also gives useful insights for practical applications, paving the way for the selection and design optimization of coatings in various and demanding situations.

1.
Ji
,
X.
,
Ji
,
W.
,
Pourhashem
,
S.
,
Duan
,
J.
,
Wang
,
W.
,
Hou
,
B.
Novel Superhydrophobic Core-Shell Fibers/Epoxy Coatings with Self-Healing Anti-Corrosion Properties in Both Acidic and Alkaline Environments
.
React Funct Polym
2023
,
187
, doi:.
2.
Sánchez Batalla
,
B.
,
Bachmann
,
J.
,
Weidlich
,
C.
Investigation of the Degradation of Proton Exchange Membrane Water Electrolysis Cells Using Electrochemical Impedance Spectroscopy with Distribution of Relaxation Times Analysis
.
Electrochim Acta
2024
,
473
,
143492
, doi:.
3.
Thoume
,
A.
,
Benmessaoud Left
,
D.
,
Elmakssoudi
,
A.
,
Safi
,
Z.S.
,
Benzbiria
,
N.
,
Berisha
,
A.
,
Kellal
,
R.
,
Zertoubi
,
M.
An In-Depth on the High Corrosion Resistance of Carbon Steel in an Acidic Solution by a Novel Functionalized Graphene Oxide with Oxime Derivative via Cutting-Edge Experimental Characterization and Computational Modeling
.
Mater Chem Phys
2023
,
310
, doi:.
4.
Haghi
,
M.
,
Kazemian
,
H.
,
Ranjbar
,
Z.
Improvement of the Corrosion Resistance of Acrylic Electrocoating in the Presence of Acid-Modified Montmorillonite Nano Clay
.
Prog Org Coat
2023
,
182
, doi:.
5.
Xu
,
R.
,
Li
,
Y.
,
Fan
,
B.
,
Weng
,
Y.
,
Zhou
,
Y.
,
Yan
,
F.
One-Step Preparation of Molybdate-Stannate-Tungstate Composite Conversion Coating on Magnesium Alloy AZ91D and Its Microstructure and Corrosion Resistance
.
Int J Electrochem Sci
2023
,
18
,
100398
, doi:.
6.
Xiang
,
Z.
,
Tong
,
L.
,
Li
,
M.
,
Li
,
X.
,
Ju
,
M.
,
Sun
,
W.
,
Zhang
,
B.
,
Wang
,
K.
A Smart Acid-Responsive GO/MS/BTA Hybrid Epoxy-Based Anti-Corrosion Coating for Mg Alloy
.
Colloids Surf A Physicochem Eng Asp
2023
,
678
, doi:.
7.
Purwasena
,
I.A.
,
Karima
,
A.
,
Asri
,
L.A.T.W.
,
Setiawan
,
A.R.
The Potency of Spores and Biosurfactant of Bacillus Clausii as a New Biobased Sol-Gel Coatings for Corrosion Protection of Carbon Steel ST 37 in Water Cooling Systems
.
Applied Surface Science Advances
2023
,
18
, doi:.
8.
Borzooei
,
F.
,
Aghili
,
H.
,
Javadpour
,
S.
Synthesis of Electrodeposited Co–P–ZrO2–CeO2 Nanocomposite Coating: Effect of Heat Treatment on Corrosion and Mechanical Properties
.
Ceram Int
2023
, doi:.
9.
Lu
,
R.
,
Xu
,
F.
,
Cui
,
Y.
,
Bao
,
D.
,
Yuan
,
S.
,
Sun
,
Y.
,
Pei
,
L.
,
Jiang
,
Y.
,
Zhu
,
J.
,
Wang
,
H.
Novel Thermal Conductivity and Anti-Corrosion Coating with Hydrophobic Properties for Heat Exchanger Applications
.
Prog Org Coat
2024
,
186
, doi:.
10.
Wu
,
L.
,
Zhang
,
K.
,
Zhou
,
Z.
,
Wang
,
G.
,
Zhang
,
X.
Two-Step Post Treatment to Improve Corrosion Resistance and Friction Performance of Fe-Based Metallic Glasses/Crystalline Dual-Phase Coatings
.
J Non Cryst Solids
2023
,
609
, doi:.
11.
Mutlu
,
I.H.
,
Emre
,
M.C.
,
Kaya
,
A.O.
A Comparison of the Corrosion Resistance of Galvanized Low Steel with Solgel Method Coated ZrO2, ZrO2+Polymer Coating
.
Kuwait Journal of Science
2023
, doi:.
12.
Pan
,
X.
,
Luo
,
X.
,
Li
,
J.
,
Peng
,
J.
,
Zhang
,
X.
,
Liu
,
Y.
Enhanced Corrosion Resistance of Ammonium Heptamolybdate (AHM) Sealed Li–Al LDHs Conversion Coating on Aluminum Alloy
.
Surf Coat Technol
2023
,
474
, doi:.
13.
Corrosion Resistance of Novel Coating Materials: Electrochemical Impedance Spectroscopy (EIS) Approach – Search
|
ScienceDirect.Com
Available online: https://www.sciencedirect.com/search?qs=Corrosion%20Resistance%20of%20Novel%20Coating%20Materials%3A%20Electrochemical%20Impedance%20Spectroscopy%20%28EIS%29%20Approach (accessed on 16 November 2023).
14.
Kumar Aruchamy
,
U.
,
Merino
,
E.
,
Durán
,
A.
,
Eckert
,
M.
,
Galusek
,
D.
,
Castro
,
Y.
Polyorganosilazane/GPTMS Functionalized Silica Coatings as an Integrated Corrosion–Resistance System for AA2024-T3 Aluminum Alloy
.
Results in Surfaces and Interfaces
2023
,
13
, doi:.
15.
Mofidabadi
,
A.H.J.
,
Bahlakeh
,
G.
,
Ramezanzadeh
,
B.
Anti-Corrosion Performance of the Mild Steel Substrate Treated by a Novel Nanostructure Europium Oxide-Based Conversion Coating: Electrochemical and Surface Studies
.
Colloids Surf A Physicochem Eng Asp
2021
,
609
, doi:.
16.
Haji Naghi Tehrani
,
M.E.
,
Malekan
,
M.
,
Ramezanzadeh
,
B.
Corrosion Interpretation of the Novel Rare-Element Bearing Bulk Metallic Glass: Electrochemical, Thermodynamic, and Surface Analysis of the (Cu50Zr43Al7)100-XErx
.
Intermetallics (Barking)
2023
,
154
, doi:.
17.
Majidi
,
R.
,
Farhadi
,
A.
,
Danaee
,
I.
,
Panah
,
N.B.
,
Zarei
,
D.
,
Nikmanesh
,
S.
Investigation of Synthesized Planar Cu-MOF and Spherical Ni-MOF Nanofillers for Improving the Anti-Corrosion Performance of Epoxy Coatings
.
Prog Org Coat
2023
,
183
, doi:.
18.
Li
,
J.
,
Li
,
T.
,
Zeng
,
Y.
,
Chen
,
C.
,
Guo
,
H.
,
Lei
,
B.
,
Zhang
,
P.
,
Feng
,
Z.
,
Meng
,
G.
A Novel Sol-Gel Coating via Catechol/Lysine Polymerization for Long-Lasting Corrosion Protection of Mg Alloy AZ31
.
Colloids Surf A Physicochem Eng Asp
2023
,
656
, doi:.
19.
Jia
,
W.
,
Cao
,
H.
,
Wang
,
T.
,
Min
,
Y.
,
Xu
,
Q.
Electrochemical Behavior and Anti-Corrosion Property of Ti3C2Tx MXene/LDH Heterostructured Coating on Aluminum Alloy
.
Surf Coat Technol
2023
,
463
, doi:.
20.
Guo
,
C.
,
Li
,
Y.
,
Qi
,
C.
,
Sun
,
H.
,
Xue
,
Y.
,
Wan
,
Y.
,
Zhang
,
D.
Preparation and Corrosion Resistance Characterization of MAO Coating on AZ31B Magnesium Alloy Formed in the Mixed Silicate and Phosphate Electrolytes with Pectin as an Additive
.
Surf Coat Technol
2023
,
130209
, doi:.
21.
Wang
,
X.
,
Lin
,
Z.
A Novel High-Performance Coating with Hybrid Nanofiller Reinforcement for Superior Self-Cleaning, Anti-Icing, and Corrosion Resistance Properties
.
Journal of Building Engineering
2023
,
80
, doi:.
22.
Ahmad
,
S.
,
Nawaz
,
M.
,
Mohammad
,
S.
,
Shakoor
,
R.A.
,
Kahraman
,
R.
,
Al Tahtamouni
,
T.M.
Modified Ni-Al Layer Double Hydroxides as Nanoparticles for Self-Healing Anti-Corrosion Composite Coating
.
Surf Coat Technol
2023
,
130172
, doi:.
23.
Verma
,
A.
,
Singh
,
H.
,
Mahton
,
Y.
,
Saha
,
P.
,
Tiwary
,
C.S.
,
Bhattacharya
,
J.
Use of Waste to Wealth Process Derived Sustainable Silica-Rich Graphene Analogues to Provide Enhanced Corrosion Resistance Properties for Coatings on Carbon Steel, Exposed to Marine Environments
.
Surf Coat Technol
2023
,
464
, doi:.
24.
Zhang
,
Q.
,
Shen
,
M.
,
Liu
,
X.
,
Fu
,
H.
,
Yang
,
W.
,
Zhao
,
J.
,
Wang
,
J.
,
Du
,
Y.
,
Ma
,
C.
Construction and Utilization of Rare Earth Complexes as Efficient Corrosion Inhibitor in Epoxy Coating
.
Prog Org Coat
2024
,
186
, doi:.
25.
Istanbullu
,
O.B.
,
Akdogan
,
G.
Increased Body Fluid Repellency and Electrochemical Corrosion Resistance of Intravascular Stent Materials by ICP-CVD-Based DLC Thin-Film Deposition
.
Diam Relat Mater
2023
,
138
, doi:.
26.
Mahdy
,
A.
,
Aly
,
K.I.
,
Mohamed
,
M.G.
Construction Novel Polybenzoxazine Coatings Exhibiting Corrosion Protection of Mild Steel at Different Concentrations in a Seawater Solution
.
Heliyon
2023
,
9
, doi:.
27.
Haq
,
Md.Z. ul
,
Sood
,
H.
,
Kumar
,
R.
Effect of Using Plastic Waste on Mechanical Properties of Fly Ash Based Geopolymer Concrete
.
Mater Today Proc
2022
.
28.
Rana
,
V.S.
,
Ul Haq
,
M.Z.
,
Mathur
,
N.
,
Khera
,
G.S.
,
Dixit
,
S.
,
Singh
,
S.
,
Prakash
,
A.
,
Viktorovna
,
G.V.
,
Soloveva
,
O. V
,
Solovev
,
S.A.
Correction: Assortment of Latent Heat Storage Materials Using Multi Criterion Decision Making Techniques in Scheffler Solar Reflector
.
International Journal on Interactive Design and Manufacturing (IJIDeM)
2023
,
1
.
29.
Kumar
,
K.
,
Dixit
,
S.
,
Ul Haq
,
M.Z.
,
Stefanska
,
A.
,
Tummala
,
S.K.
,
Bobba
,
P.B.
,
Kaur
,
N.
,
Mohiuddin
,
M.A.
From Homogeneity to Heterogeneity: Designing Functionally Graded Materials for Advanced Engineering Applications
.
In Proceedings of the E3S Web of Conferences; EDP Sciences
,
2023
; Vol.
430
, p.
01198
.
30.
Ul Haq
,
M.Z.
,
Sood
,
H.
,
Kumar
,
R.
,
Chaudhary
,
P.
,
Lavanya
,
C.
,
Dhaliwal
,
N.
,
Singarapu
,
S.
,
Kumar
,
K.
Waste Upcycling in Construction: Geopolymer Bricks at the Vanguard of Polymer Waste Renaissance
.
In Proceedings of the E3S Web of Conferences; EDP Sciences
,
2023
; Vol.
430
, p.
01205
.
31.
Ul Haq
,
M.Z.
,
Sood
,
H.
,
Kumar
,
R.
,
Dixit
,
S.
,
Srinivas
,
T.
,
Ahuja
,
S.
,
Lingam
,
B.
,
Kumar
,
K.
Circular Economy Enabler: Enhancing High-Performance Bricks through Geopolymerization of Plastic Waste
.
In Proceedings of the E3S Web of Conferences; EDP Sciences
,
2023
; Vol.
430
, p.
01202
.
32.
Ul Haq
,
M.Z.
,
Sood
,
H.
,
Kumar
,
R.
,
Sharma
,
V.
,
Kumar
,
A.
,
Srinivas
,
T.
,
Gulati
,
M.
,
Bindu
,
K.H.
,
Kumar
,
K.
Eco-Friendly Building Material Innovation: Geopolymer Bricks from Repurposed Plastic Waste
.
In Proceedings of the E3S Web of Conferences; EDP Sciences
,
2023
; Vol.
430
, p.
01201
.
33.
Ul Haq
,
M.Z.
,
Sharma
,
V.
,
Sood
,
H.
,
Kumar
,
R.
,
Joshi
,
K.
,
Manisha
,
K.
,
Lakhanpal
,
S.
,
Chary
,
M.R.
,
Kumar
,
K.
Geopolymerization of Plastic Waste for Sustainable Construction: Unveiling Novel Opportunities in Building Materials
.
In Proceedings of the E3S Web of Conferences; EDP Sciences
,
2023
; Vol.
430
, p.
01204
.
34.
Das
,
L.
,
Nayak
,
R.
,
Saxena
,
K.K.
,
Nanda
,
J.
,
Jena
,
S.P.
,
Behera
,
A.
,
Sehgal
,
S.
,
Prakash
,
C.
,
Dixit
,
S.
,
Abdul-Zahra
,
D.S.
Determination of Optimum Machining Parameters for Face Milling Process of Ti6A14V Metal Matrix Composite
.
Materials
2022
,
15
, doi:.
35.
Kuppusamy
,
Y.
,
Jayaseelan
,
R.
,
Pandulu
,
G.
,
Kumar
,
V.S.
,
Murali
,
G.
,
Dixit
,
S.
,
Vatin
,
N.I.
Artificial Neural Network with a Cross-Validation Technique to Predict the Material Design of Eco-Friendly Engineered Geopolymer Composites
.
Materials
2022
,
15
, doi:.
36.
Zheng Yang
,
K.
,
Pramanik
,
A.
,
Basak
,
A.K.
,
Dong
,
Y.
,
Prakash
,
C.
,
Shankar
,
S.
,
Dixit
,
S.
,
Kumar
,
K.
,
Ivanovich Vatin
,
N.
Application of Coolants during Tool-Based Machining – A Review
.
Ain Shams Engineering Journal
2022
, doi:.
37.
Kumar
,
K.
,
Dixit
,
S.
,
Arora
,
R.
,
Vatin
,
N.I.
,
Singh
,
J.
,
Soloveva
,
O. V.
,
Ilyashenko
,
S.B.
,
John
,
V.
,
Buddhi
,
D.
Comparative Analysis of Waste Materials for Their Potential Utilization in Green Concrete Applications
.
Materials
2022
,
15
, doi:.
38.
Samal
,
S.K.
,
Vishwanatha
,
H.M.
,
Saxena
,
K.K.
,
Behera
,
A.
,
Nguyen
,
T.A.
,
Behera
,
A.
,
Prakash
,
C.
,
Dixit
,
S.
,
Mohammed
,
K.A.
3D-Printed Satellite Brackets: Materials, Manufacturing and Applications
.
Crystals (Basel)
2022
,
12
, doi:.
39.
Bindu Katikala
,
H.
,
Pavan Kumar
,
T.
,
Manideep Reddy
,
B.
,
V.V.Pavan
Kumar
, B.,
Ramana Murthy
,
G.
,
Dixit
,
S.
Design of Half Adder Using Integrated Leakage Power Reduction Techniques
.
Mater Today Proc
2022
,
69
,
576
581
, doi:.
This content is only available via PDF.
You do not currently have access to this content.