Ammonium dihydrogen phosphate(ADP) is good Second Harmonic Generators(SHG) having versatile NLO properties, cultivated using the low-temperature solution growth method. Single crystals of pure and bimetal (Co+2-Ni+2) At room temperature, doped Ammonium dihydrogen phosphate (ADP) was developed utilising the slow evaporation solution growth approach. Solubility curves shows visible change when metallic impurities added in ADP. The powder XRD,EDAX and FTIR spectroscopic studies confirms the single phase nature, presence of dopant and all constitute functional groups of ADP in grown crystals. The second harmonic generation (SHG) efficiency was carryout using the Kurtz and Parry method which results in small decrement in the SHG efficiency due to bimetal dopant compare to pure ADP. Vickers micro hardness result indicates doping make the ADP crystal harder and mechanically stable in the applied load region. Variation in dielectric parameters due to dopant was carried out using Agilent Precision LCR meter [E4980A], 100Hz to 2MHz frequency range at ambient temperature.

1.
R.A.
Laudise
,
The Growth of Single Crystals
(
Prentice-Hall
,
Englewood Cliffs, N.J
.,
1970
).
2.
J.C.
Brice
,
Crystal Growth Processes
(
John Wiley and sons
.,
New York
,
1986
).
3.
H.S.
Nalwa
and
S.
Miyata
, editors,
Nonlinear Optics of Organic Molecules and Polymers
(
CRS Press
,
New York
,
1996
),pp.
896
.
4.
D.
Xu
and
D.
Xue
,
J. Cryst. Growth
310
,
1385
1390
(
2008
).
5.
R.J.
Davey
and
J.W.
Mullin
,
J. Cryst. Growth
26
,
45
51
(
1974
).
6.
7.
N.
Zaitseva
and
L.
Carman
,
Prog. Cryst. Growth Charact. Mater. Mater.
1
118
(
2001
).
8.
A.
Yokotani
,
T.
Sasaki
,
K.
Yoshida
,
T.
Yamanaka
, and
C.
Yamanaka
,
Appl. Phys. Lett.
48
,
1030
1032
(
1986
).
9.
X.
Feng
,
L.
Zhu
,
F.
Li
,
F.
Wang
,
W.
Han
,
Z.
Wang
,
Q.
Zhu
, and
X.
Sun
,
RSC Adv.
6
,
33983
33989
(
2016
).
10.
D.
Zion
,
S.
Devarajan
, and
T.
Arunachalam
,
J. Cryst. Process Technol.
03
,
5
11
(
2013
).
11.
D.
Jananakumar
and
P.
Mani
,
J. Nonlinear Opt. Phys. Mater.
22
,
1350016
(
2013
).
12.
P.V.
Dhanaraj
,
G.
Bhagavannarayana
, and
N.P.
Rajesh
,
Mater. Chem. Phys.
112
,
490
495
(
2008
).
13.
N.P.
Rajesh
,
C.K. Lakshmana
Perumal
,
P. Santhana
Raghavan
, and
P.
Ramasamy
,
Cryst. Res. Technol.
36
,
55
65
(
2001
).
14.
V.
Ganesh
,
M.
Shkir
,
S.
AlFaify
, and
I.S.
Yahia
,
J. Cryst. Growth
449
,
47
56
(
2016
).
15.
M. Mohan
Krishna
,
Growth and Characterization of Some Organic and Inorganic Nonlinear Optical (Nlo) Crystals
,
SRM University
,
2012
.
16.
V.I.
Bespalov
,
V.I.
Bredikhin
,
V.P.
Ershov
,
V.I.
Katsman
,
N. V
Kiseleva
, and
S.P.
Kuznetsov
,
Sov. J. Quantum Electron.
12
,
1527
1528
(
1982
).
17.
K.
Yamada
,
A.
Sato
,
T.
Shimizu
,
T.
Yamazaki
, and
S.
Yokoyama
,
Acta Crystallogr. Sect. E Struct. Reports Online
64
,
806
(
2008
).
18.
H.
Lipson
and
H.
Steeple
,
Interpretation of X-Ray Powder Diffraction Patterns
(
Macmillan; St Martin’s Press
,
London; New York
,
1970
).
19.
A.
Claude
,
V.
Vaithianathan
,
R.B.
Ganesh
,
R.
Sathyalakshmi
, and
P.
Ramasamy
,
J. Appl. Sci.
6
,
85
89
(
2005
).
20.
J.
Jerphagnon
and
S.K.
Kurtz
,
Phys. Rev. B
1
,
1739
1744
(
1970
).
21.
F.
Ben Brahim
and
A.
Bulou
,
Mater. Chem. Phys.
130
,
24
32
(
2011
).
22.
M.
Hasmuddin
,
P.
Singh
,
M.
Shkir
,
M.M.
Abdullah
,
N.
Vijayan
,
V.
Ganesh
, and
M.A.
Wahab
,
Mater. Chem. Phys.
144
,
293
300
(
2014
).
23.
P.
Rajesh
and
P.
Ramasamy
,
J. Cryst. Growth
311
,
3491
3497
(
2009
).
24.
M.
Hasmuddin
,
P.
Singh
,
M.
Shkir
,
M.M.
Abdullah
,
N.
Vijayan
,
G.
Bhagavannarayana
, and
M.A.
Wahab
,
Spectrochim. Acta Part A Mol. Biomol. Spectrosc.
123
,
376
384
(
2014
).
25.
A.P.
Kochuparampil
,
J.H.
Joshi
, and
M.J.
Joshi
,
Mod. Phys. Lett. B
31
,
1750246
(
2017
).
26.
S.K.
Kurtz
and
T.T.
Perry
,
J. Appl. Phys.
39
,
3798
3813
(
1968
).
27.
R.
Rai
,
P.
Ramasamy
, and
C.
Lan
,
J. Cryst. Growth
235
,
499
504
(
2002
).
28.
N.
Vijayan
,
G.
Bhagavannarayana
, and
A.M.Z.
Slawin
,
Mater. Lett.
62
,
2480
2482
(
2008
).
29.
D. Prem
Anand
,
M. Gulam
Mohamed
,
S.A.
Rajasekar
,
S.
Selvakumar
,
A. Joseph Arul
Pragasam
, and
P.
Sagayaraj
,
Mater. Chem. Phys.
97
,
501
505
(
2006
).
30.
A.H.
Reshak
,
I. V.
Kityk
, and
S.
Auluck
,
J. Phys. Chem. B
114
,
16705
16712
(
2010
).
31.
G.D.
Stucky
,
M.L.F.
Phillips
, and
T.E.
Gier
,
Chem. Mater.
1
,
492
509
(
1989
).
32.
X.S.
Shajan
and
C.
Mahadevan
,
Bull. Mater. Sci.
27
,
327
331
(
2004
).
33.
P.M.
Onitsch
,
Mikroskopie2
(
1974
).
34.
J.H.
Joshi
,
S.
Kalainathan
,
D.K.
Kanchan
,
M.J.
Joshi
, and
K.D.
Parikh
,
Arab. J. Chem.
13
,
1532
1550
(
2020
).
35.
D.J.
Dave
,
K.D.
Parikh
, and
M.J.
Joshi
,
Adv. Mater. Res.
665
,
172
178
(
2013
).
36.
A.
Hemalatha
,
S.
Arulmani
,
E.
Chinnasamy
, and
S.
Senthil
,
Mater. Today Proc.
34
,
412
415
(
2021
).
37.
J.H.
Joshi
,
K.V.
Vadhel
,
G.M.
Joshi
,
S.
Kalainathan
,
M.J.
Joshi
,
H.O.
Jethva
, and
K.D.
Parikh
,
Chinese J. Phys.
64
,
138
162
(
2020
).
38.
A.
Kumaresh
and
R. Arun
Kumar
,
Optik (Stuttg)
.
127
,
1922
1925
(
2016
).
39.
K.
Sangwal
and
E.
Mielniczek-Brzóska
,
Cryst. Res. Technol.
52
,
1600361
(
2017
).
40.
N.
Rani
,
N.
Vijayan
,
M.A.
Wahab
,
G.
Bhagavannarayana
,
B.
Riscob
, and
K.K.
Maurya
,
Optik (Stuttg)
.
124
,
1550
1554
(
2013
).
41.
N.P.
Zaitseva
,
F.S.
Ganikhanov
,
O. V.
Katchalov
,
V.F.
Efimkov
,
S.A.
Pastukhov
, and
V.B.
Sobolev
, "
Optical properties of KDP crystals grown at high growth rates
," in
USSR-CSFR Jt. Semin. Nonlinear Opt. Control. Diagnostics, Model. Biophys. Process.
, edited by
S.A.
Akhmanov
and
V.N.
Zadkov
(
1991
), pp.
223
230
.
This content is only available via PDF.
You do not currently have access to this content.