In this study the simple rapid method for the preparation of benzimidazole and benzothiazole by the condensationof an o-phenylene diamine with the aromatic aldehyde in presence of the ZnS nanoparticles derived from Trigonella foenum-graecum. Plant. ZnS as a catalyst was prepared by using the waste stem of the Trigonella foenum-graecum plant. The preparation of benzimidazole and benzothiazole derivative reaction carried under the mild condition with very high excellent yield. The method is used with aromatic, unsaturated and hetroaromatic aldehyde. the main advantage of this method as a very short reaction time, solvent-free reaction condition, reusable catalyst, milder reaction, easy workup, a waste stem of the plant was used.
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