Polylactic acid (PLA) as a bioplastic material has been extensively applied in various industries, including packaging, textiles, and the biomedical industry due to their desired physical, chemical, and biological characteristics. This polymer is also used in 3D printing filaments and nanocomposites. Despite the various applications of PLA being explored in the industry, there is a demand for a higher yield, better efficiency, and a sustainable and economical process in PLA production. Thus, this preliminary study is investigating the potential of PLA production via microwave treatment. The work involves an experimental study of the conversion of glucose to lactic acid (LA), followed by a systemic review of the production of PLA from LA. The highest yield of LA was observed after 40 minutes of microwave treatment at 180 °C, as indicated by Benedict test and pH measurements, with time as the independent variable. Based on the review, it is suggested that the bicatalyst has the potential to increase the yield of PLA production from LA. Activated charcoal (AC) and tungsten phosphoric acid (TGA) were proposed as the recyclable bicatalysts due to their roles as effective adsorption and catalyst esterification, respectively. Overall, the present study demonstrated that the simultaneous conversion of glucose to PLA via microwave treatment offers great potential towards the sustainable and economically viable production of PLA polymers. A thorough study is required to optimize this process, and future studies should focus on scaling up the system. Sustainable production of PLA would be able to drive the demand for this polymer in the industry while supporting Sustainable Development Goal 12 towards responsible consumption and production.

1.
Kim
Y
,
Kim
J.S.
,
Lee
S.Y.
,
Mahajan
R.L.
,
Kim
Y.T.
Exploration of hybrid nanocarbon composite with polylactic acid for packaging applications
.
International Journal of Biological Macromolecules.
(
2020
)
144
:
135
42
.
2.
Perin
D
,
Rigotti
D
,
Fredi
G
,
Papageorgiou
G.Z.
,
Bikiaris
D.N.
,
Dorigato
A.
innovative bio-based poly (lactic acid)/poly (alkylene furanoate) fiber blends for sustainable textile applications
.
Journal of Polymers and the Environment.
(
2021
):
1
6
.
3.
Morozov
A.G.
,
Razborov
D.A.
,
Egiazaryan
T.A.
,
Baten'kin
M.A.
,
Aleynik
D.Y.
,
Egorikhina
M.N.
,
Rubtsova
Y.P.
,
Charikova
I.N.
,
Chesnokov
S.A.
,
Fedushkin
I.L.
In vitro study of degradation behavior, cytotoxicity, and cell adhesion of the atactic polylactic acid for biomedical purposes
.
Journal of Polymers and the Environment.
(
2020
),
28
:
2652
4.
Spinelli
G
,
Lamberti
P
,
Tucci
V
,
Ivanova
R
,
Tabakova
S
,
Ivanov
E
,
Kotsilkova
R
,
Cimmino
S
,
Di Maio
R
,
Silvestre
C.
Rheological and electrical behaviour of nanocarbon/poly (lactic) acid for 3D printing applications
.
Composites Part B: Engineering.
(
2019
),
167
:
467
476
.
5.
Peng
Q
,
Mahmood
K
,
Wu
Y
,
Liu
Z
,
Wei
L
,
Yuan
H
,
Yang
R.
Effective binary catalysts of BrØnsted acidic ionic liquids and stannous chloride dihydrate for melt polycondensation of L-lactic acid
.
Molecular Catalysis.
(
2017
)
434
:
140
145
.
6.
Balla
E
,
Daniilidis
V
,
Karlioti
G
,
Kalamas
T
,
Stefanidou
M
,
Bikiaris
N.D.
,
Vlachopoulos
A
,
Koumentakou
I
,
Bikiaris
D.N.
Poly (lactic Acid): A versatile biobased polymer for the future with multifunctional properties—from monomer synthesis, polymerization techniques and molecular weight increase to PLA applications
.
Polymers.
(
2021
),
11
:
1822
.
7.
Kabir
,
E.
,
Kaur
,
R.
,
Lee
,
J.
,
Kim
,
K.H.
and
Kwon
,
E.E.
, 2020.
Prospects of biopolymer technology as an alternative option for non-degradable plastics and sustainable management of plastic wastes
.
Journal of Cleaner Production
,
258
, p.
120536
.
8.
Ajala
E.O.
,
Olonade
Y.O.
,
Ajala
M.A.
,
Akinpelu
G.S.
Lactic acid production from lignocellulose–A review of major challenges and selected solutions
.
ChemBioEng Reviews.
(
2020
),
2
:
38
49
.
9.
Boey
J.Y.
,
Mohamad
L
,
Khok
Y.S.
,
Tay
G.S.
,
Baidurah
S.
A review of the applications and biodegradation of polyhydroxyalkanoates and poly (lactic acid) and its composites
.
Polymers.
(
2021
),
10
:
1544
.
10.
Komorowska-Durka
M
,
Dimitrakis
G
,
Bogdał
D
,
Stankiewicz
A.I.
,
Stefanidis
G.D.
A concise review on microwave assisted polycondensation reactions and curing of polycondensation polymers with focus on the effect of process conditions
.
Chemical Engineering Journal
. (
2015
),
264
:
633
644
.
11.
Dubey
S.P.
,
Thakur
V.K.
,
Krishnaswamy
S
,
Abhyankar
H.A.
,
Marchante
V
,
Brighton
J.L.
Progress in environmentalfriendly polymer nanocomposite material from PLA: Synthesis, processing and applications
.
Vacuum.
(
2017
),
146
:
655
663
.
12.
Zahari
S.S.
,
Mansor
M.H.
,
Azman
H.H.
,
Rosli
D.
Uncatalysed polycondensation of lactic acid to polylactic acid under microwave irradiation: Effect of microwave power.
In Journal of Physics: Conference Series
2020
May 1 (Vol.
1551
, No.
1
, p.
012001
).
IOP Publishing
.
13.
Van den Bosch
S
,
Koelewijn
S.F.
,
Renders
T
,
Van den Bossche
G
,
Vangeel
T
,
Schutyser
W
,
Sels
B.F.
Catalytic strategies towards lignin-derived chemicals
.
Topics in Current Chemistry.
(
2018
),
5
:
1
40
.
14.
Epane
G
,
Laguerre
J.C.
,
Wadouachi
A
,
Marek
D.
Microwave-assisted conversion of D-glucose into lactic acid under solvent-free conditions
.
Green Chemistry.
2010
,
12
:
502
506
.
15.
Kumar
V
,
Gill
K.D.
Basic concepts in clinical biochemistry: a practical guide.
Springer
;
2018
Mar 30.
16.
You
S.Y.
,
Yang
J.S.
,
Kim
S.H.
,
Hwang
I.M.
Changes in the physicochemical quality characteristics of cabbage kimchi with respect to storage conditions
.
Journal of Food Quality.
(
2017
)
15
;
2017
.
17.
Zahari
S.S.
,
Zulastry
N.A.
,
Azman
H.H.
A preliminary study of catalytic hydrothermal conversion of cellulose to lactic acid: Effects of reaction temperature and metal ion catalyst.
In Journal of Physics: Conference Series
2020
May 1 (Vol.
1551
, No.
1
, p.
012014
).
IOP Publishing
.
18.
Tolipova
N.K.
,
Azimova
S.B.
,
Ataeva
D.R.
optimization of diagnosis and treatment of lactose intolerance in infants
.
International Journal.
(
2018
)
3
:
64
67
.
19.
Hu
Y
,
Daoud
W.A.
,
Cheuk
K.K.
,
Lin
C.S.
Newly developed techniques on polycondensation, ring-opening polymerization and polymer modification: Focus on poly (lactic acid
).
Materials.
(
2016
)
3
:
133
.
20.
Singla
R
,
Mehta
R.
Preparation and characterization of polylactic acid-based biodegradable blends processed under microwave radiation
.
Polymer-Plastics Technology and Engineering.
(
2012
),
10
:
1014
1017
.
21.
Kaavessina
M
,
Chafidz
A
,
Mu'awanah
M
,
Nisa
S.S.
The effects of molecular weight of polylactic acid matrix on release time of smart urea fertilizer (SUF).
In AIP Conference Proceedings
2019
Apr 23 (Vol.
2097
, No.
1
, p.
030092
).
AIP Publishing LLC
.
22.
Chafran
L.S.
,
Paiva
M.F.
,
França
J.O.
,
Sales
M.J.
,
Dias
S.C.
,
Dias
J.A.
Preparation of PLA blends by polycondensation of D, L-lactic acid using supported 12-tungstophosphoric acid as a heterogeneous catalyst
.
Heliyon.
(
2019
),
5
:
e01810
.
23.
Nagahata
R
,
Sano
D
,
Suzuki
H
,
Takeuchi
K.
Microwave-assisted single-step synthesis of poly (lactic acid) by direct polycondensation of lactic acid
.
Macromolecular Rapid Communications.
2007
Feb 19;
28
(
4
):
437
42
.
24.
Leone
A.K.
,
McNeil
A.J.
Matchmaking in catalyst-transfer polycondensation: optimizing catalysts based on mechanistic insight
.
Accounts of Chemical Research.
(
2016
),
12
:
2822
2831
.
25.
Terzopoulou
Z
,
Karakatsianopoulou
E
,
Kasmi
N
,
Tsanaktsis
V
,
Nikolaidis
N
,
Kostoglou
M
,
Papageorgiou
G.Z.
,
Lambropoulou
D.A.
,
Bikiaris
D.N.
Effect of catalyst type on molecular weight increase and coloration of poly (ethylene furanoate) biobased polyester during melt polycondensation
.
Polymer Chemistry.
(
2017
),
14
:
6895
6908
.
26.
Zhang
M
,
Chen
L
,
Jiang
Z
,
Ma
J.
Effects of dehydration rate on the yield of ethyl lactate in a pervaporationassisted esterification process
.
Industrial & Engineering Chemistry Research.
(
2015
),
26
:
6669
6676
.
27.
Liu
N
,
Yao
C
,
Lin
F
,
Liu
B
,
Cui
D.
An intensification and integration process of preparing thermal stable polylactide end-capped by phosphate ester
.
Polymer.
(
2015
),
80
:
104
108
.
28.
Dove
A.P.
,
Xie
X
,
Waymouth
R.M.
Cyclopentadienyl titanium hydroxylaminato complexes as highly active catalysts for the polymerization of propylene
.
Chemical Communications.
(
2005
),
16
:
2152
2154
.
29.
Kinnersley
H.W.
,
Peters
R.A.
The relation of hydrogen ion concentration to the precipitation of purified torulin (yeast vitamin B1) by phosphotungstic acid
.
Biochemical Journal.
(
1930
),
24
:
1856
.
30.
Fazal-ur-Rehman
M.
Methodological trends in preparation of activated carbon from local sources and their impacts on production: a review
.
Chem. Int.
(
2018
),
4
:
109
119
.
31.
Zhong
L
,
Zhang
Y
,
Ji
Y
,
Norris
P
,
Pan
W.P.
Synthesis of activated carbon from coal pitch for mercury removal in coal-fired power plants
.
Journal of Thermal Analysis and Calorimetry.
(
2016
),
1
:
851
860
.
32.
Wang
H.H.
,
Liu
L.J.
,
Gong
S.W.
Esterification of oleic acid to biodiesel over a 12-phosphotungstic acid-based solid catalyst
.
Journal of Fuel Chemistry and Technology.
(
2017
),
3
:
303
310
.
33.
Zahari
S.S.
,
Azman
H
,
Karim
L.
Triethylammonium hydrogen sulfate ionic liquid as a low-cost solvent: A short review of synthesis, analysis and applications
.
In MATEC Web of Conferences
2018
(Vol.
204
, p.
00006
). EDP Sciences.
34.
Zahari
S.S.
,
Amin
A.T.
,
Halim
N.M.
,
Rosli
F.A.
,
Halim
W.I.
,
Samsukamal
N.A.
,
Sasithran
B
,
Ariffin
N.A.
,
Azman
H.H.
,
Hassan
N.H.
,
Othman
Z.S.
Deconstruction of Malaysian agro-wastes with inexpensive and bifunctional triethylammonium hydrogen sulfate ionic liquid.
In AIP Conference Proceedings
2018
Jun 5 (Vol.
1972
, No.
1
, p.
030024
).
AIP Publishing LLC
.
35.
Jamnongkan
T
,
Jaroensuk
O
,
Khankhuean
A
,
Laobuthee
A
,
Srisawat
N
,
Pangon
A
, …
Huang
,
C.F.
A Comprehensive Evaluation of Mechanical, Thermal, and Antibacterial Properties of PLA/ZnO Nanoflower Biocomposite Filaments for 3D Printing Application
.
Polymers.
(
2022
)
14(3)
:
600
.
36.
Ahmad Ruzaidi
D.A.
,
Mahat
M.M.
,
Mohamed Sofian
Z
,
Nor Hashim
N.A.
,
Osman
H
,
Nawawi
M.A.
,
Ramli
R
,
Jantan
K.A.
,
Aizamddin
M.F.
,
Azman
H.H.
,
Robin Chang
Y.H.
,
Hamzah
H.H.
Synthesis and Characterization of Porous, Electro-Conductive Chitosan–Gelatin–Agar-Based PEDOT: PSS Scaffolds for Potential Use in Tissue Engineering
.
Polymers.
(
2021
)
13
:
2901
.
37.
Omar
S.N.
,
Ariffin
Z.Z.
,
Akhir
R.A.
,
Shri
D.N.
,
Halim
M.I.
,
Safian
M.F.
,
Azman
H.H.
,
Ramli
R
,
Mahat
M.M.
Polyaniline (PANI) fabric doped p-toluene sulfonic acid (pTSA) with anti-infection properties. Materials Today
:
Proceedings.
(
2019
)
16
(
4
):
1994
2002
.
38.
Zahari
S.S.
,
Nordin
N.F.
,
Kamarudin
M.S.
,
Sahrim
M.A.
,
Mahat
M.M.
,
Azman
H.H.
,
Junid
R
,
Endot
N.A.
Poly (vinylpyrrolidinone)-iron magnetic nanocomposites as sorbents for effective oil removal from water.
In AIP Conference Proceedings
2018
Jun 5 (Vol.
1972
, No.
1
, p.
030026
).
AIP Publishing LLC
.
This content is only available via PDF.
You do not currently have access to this content.