This study aims to analyze the quality and responses of students to the chemistry puzzles book that has been developed as a learning media. The development model used ADDIE method, incorporated the stages of Analysis, Design, Development, Implementation, and Evaluate. Learning media quality testing is carried out based on validation by media and material experts. A feasibility study was conducted by seven chemistry teachers from three different schools. Students’ responses on the book were also gathered via a test, in which 60 students from these schools have participated. The results showed that (1) the media expert validation resulted in the total score obtained 79 with a percentage of 75.7%, and the mean score was 3.03 with very feasible category, (2) the material expert validation with the total score of 115 and a percentage of 92.7%, the average score was 3.7 with very feasible category (3) the results of the feasibility test showed that the percentage of the average score was 87.12 with very feasible category, (4) the results of the student responses showed that the total average score was 4.4 in.the very good category. It can be concluded that the quality of chemistry puzzles book is considered good, as a learning media for class X High School students.

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