In this work, the zeolitic imidazolate framework (ZIF-67) has been synthesized as an efficient adsorber for dibenzothiophene (DBT) removal from liquid model fuel via the adsorptive desulfurization method. Different characterizations were applied to assess the properties of the synthesized ZIF-67 adsorber. The effects of experimental parameters, DBT concentration in model fuel, and contact time have been investigated on the absorption performance of ZIF-67. The synthesized ZIF-67 presented a high surface area (1159.9 m2.g-1). Also, the ZIF-67 exhibited good DBT absorption uptake (86.12 mg.g-1). Moreover, the kinetics and equilibrium isotherm of DBT removal was considered. The pseudo-second-order kinetic model and the Freundlich isotherm exhibited well agreement with the experimental data.
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12 July 2022
INTERNATIONAL CONFERENCE OF CHEMISTRY AND PETROCHEMICAL TECHNIQUES (ICCPT)
26–27 June 2021
Kut, Iraq
Research Article|
July 12 2022
Synthesis, characterization, and adsorptive desulfurization efficiency of ZIF-67 nanoadsorber Available to Purchase
S. M. Flihh;
S. M. Flihh
a)
Chemical Engineering Department, Al-Nahrain University
, Baghdad, Iraq
a)Corresponding author: [email protected]
Search for other works by this author on:
S. H. Ammar
S. H. Ammar
b)
Chemical Engineering Department, Al-Nahrain University
, Baghdad, Iraq
Search for other works by this author on:
S. M. Flihh
a)
Chemical Engineering Department, Al-Nahrain University
, Baghdad, Iraq
S. H. Ammar
b)
Chemical Engineering Department, Al-Nahrain University
, Baghdad, Iraq
a)Corresponding author: [email protected]
AIP Conf. Proc. 2450, 020032 (2022)
Citation
S. M. Flihh, S. H. Ammar; Synthesis, characterization, and adsorptive desulfurization efficiency of ZIF-67 nanoadsorber. AIP Conf. Proc. 12 July 2022; 2450 (1): 020032. https://doi.org/10.1063/5.0094052
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