The method of selective chemical destruction reveals that the compounds linked to each other or to other structural fragments via ether and sulfide bridges are present in addition to the components in molecular form in the oil of the organic matter of oil shale from the Dmitrievskoye field. It is shown using chromatography-mass spectrometry that “sulfur-bound” and ‘ether-bound’ saturated and polycycloaromatic hydrocarbons are represented by n-alkanes, hopanes, naphthalenes, biphenyls, phenanthrenes, phenylnaphthalenes, fluorenes, fluorantenes, pyrenes and benzo[c]phenanthrene, perylenes and benzo[e]pyrenes. Unsubstituted structures, namely naphthalene, fluorene, triphenylene, and indeno[1,2,3-cd]fluorantene are only linked through a functional C-S group. The results of the study expand the understanding of the composition of the organic matter of oil shales. They are important for the choice of methods for their processing in order to obtain chemically useful components based on oil shale material, including motor fuels.
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14 December 2020
PROCEEDINGS OF THE INTERNATIONAL CONFERENCE ON PHYSICAL MESOMECHANICS. MATERIALS WITH MULTILEVEL HIERARCHICAL STRUCTURE AND INTELLIGENT MANUFACTURING TECHNOLOGY
5–9 October 2020
Tomsk, Russia
Research Article|
December 14 2020
Composition of compounds bounded via sulfide and ether bridges in oils of the organic matter of oil shale of the Dmitrievskoye field
Elena Yu. Kovalenko;
Elena Yu. Kovalenko
a)
1
Institute of Petroleum Chemistry SB RAS
, Tomsk, 634055 Russia
a)Corresponding author: [email protected]
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Tatiana A. Sagachenko;
Tatiana A. Sagachenko
1
Institute of Petroleum Chemistry SB RAS
, Tomsk, 634055 Russia
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Raisa S. Min;
Raisa S. Min
b)
1
Institute of Petroleum Chemistry SB RAS
, Tomsk, 634055 Russia
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Andrei A. Grin'ko
Andrei A. Grin'ko
2
National Research Tomsk Polytechnic University
, Tomsk, 634050 Russia
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Elena Yu. Kovalenko
1,a)
Tatiana A. Sagachenko
1
Raisa S. Min
1,b)
Andrei A. Grin'ko
2
1
Institute of Petroleum Chemistry SB RAS
, Tomsk, 634055 Russia
2
National Research Tomsk Polytechnic University
, Tomsk, 634050 Russia
a)Corresponding author: [email protected]
AIP Conf. Proc. 2310, 020161 (2020)
Citation
Elena Yu. Kovalenko, Tatiana A. Sagachenko, Raisa S. Min, Andrei A. Grin'ko; Composition of compounds bounded via sulfide and ether bridges in oils of the organic matter of oil shale of the Dmitrievskoye field. AIP Conf. Proc. 14 December 2020; 2310 (1): 020161. https://doi.org/10.1063/5.0034672
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