The method of selective chemical destruction reveals that the compounds linked to each other or to other structural fragments via ether and sulfide bridges are present in addition to the components in molecular form in the oil of the organic matter of oil shale from the Dmitrievskoye field. It is shown using chromatography-mass spectrometry that “sulfur-bound” and ‘ether-bound’ saturated and polycycloaromatic hydrocarbons are represented by n-alkanes, hopanes, naphthalenes, biphenyls, phenanthrenes, phenylnaphthalenes, fluorenes, fluorantenes, pyrenes and benzo[c]phenanthrene, perylenes and benzo[e]pyrenes. Unsubstituted structures, namely naphthalene, fluorene, triphenylene, and indeno[1,2,3-cd]fluorantene are only linked through a functional C-S group. The results of the study expand the understanding of the composition of the organic matter of oil shales. They are important for the choice of methods for their processing in order to obtain chemically useful components based on oil shale material, including motor fuels.

1.
B. T.
Gudzenko
and
A. A.
Varenichev
,
Geol. Geophys. Development Oil Gas Fields
9
,
45
55
(
2014
).
2.
S. A.
Semenova
and
Y. F.
Patrakov
,
Solid Fuel Chem.
43
,
267
272
(
2009
).
3.
Yu. F.
Patrakov
,
L. V.
Kuznetsova
, and
B. A.
Anferov
,
Bull. Kuzbass State Tech. Univ.
4
,
33
43
(
2016
).
4.
N. N.
Rokosova
,
V. Yu.
Rokosova
, and
Yu. V.
Rokosov
,
Chem. Technol. Fuels Oils
52
,
402
408
(
2016
).
5.
Yu. V.
Rokosov
,
P. V.
Lapsina
,
V. Yu.
Rokosova
, and
A. I.
Moiseev
,
Nat. Tech. Sci.
9
,
24
31
(
2016
).
6.
E. Yu.
Kovalenko
,
I. S.
Korol
,
T. A.
Sagachenko
, and
R. S.
Min
,
Bull. Tomsk Polytech. Univ. Geo Assets Eng.
328
,
94
104
(
2017
).
7.
P.
Peng
,
A.
Morales-Izguierdo
,
A.
Hogg
, and
O. P.
Strausz
,
Energy Fuels
11
,
1171
1187
(
1997
).
8.
A. V.
Petrov
,
E. Yu.
Kovalenko
, and
A. A.
Grin'ko
, in
Problems of Geology and Subsurface Development
:
Proceedings of the XXIII International Symposium of students and young researchers in honor of Acad. M. A. Usov devoted to the 120th anniversary of Acad. K. I. Satpayev and the 120th anniversary of Prof. K. V. Radugin
(
Publishing House of Tomsk Polytechnic University, Tomsk
,
2019
), vol.
2
, pp.
356
358
.
9.
V. R.
Antipenko
and
T. V.
Cheshkova
,
Bull. Tomsk Polytech. Univ.
324
,
16
21
(
2014
).
10.
L. I.
Bogorodskaya
,
A. E.
Kontorovich
, and
A. I.
Larichev
, in
Kerogen. Methods of Study and Geochemical Interpretation
(
Publishing House of the Siberian Branch of the Russian Academy of Sciences
,
“Geo” Branch, Novosibirsk
,
2005
), pp.
151
154
.
11.
B. P.
Tissot
and
D. H.
Welte
,
Petroleum Formation and Occurrence: A New Approach to Oil and Gas Exploration
(
Springer-Verlag
,
New York
,
1984
).
12.
S. Bou
Daher
,
F. H.
Nader
,
C.
Muller
, and
R.
Littke
,
Marine Petroleum Geol.
64
,
304
323
(
2015
).
13.
M. H.
Hakimi
,
W. H.
Abdullah
,
M.
Alqudah
,
Y. M.
Makeen
, and
K. A.
Mustapha
,
Fuel
181
,
34
45
(
2016
).
14.
D.
Saltymakova
,
N.
Krasnoyarova
, and
O.
Serebrennikova
,
J. Petroleum Sci. Eng.
154
,
91
99
(
2017
).
15.
J. Z.
Zhang
,
X. Q.
Li
,
X. Q.
Zhang
,
M.
Zhang
,
G. S.
Cong
,
G. W.
Zhang
, and
F. Y.
Wang
,
Marine Petroleum Geol.
96
,
1
15
(
2018
).
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