Solar energy is the green source which can replace unsafe and unclean methods for the generation of electricity. Solar cell is a device that directly converts solar energy into electrical energy through the photovoltaic effect. Solar light absorption and film forming properties are very important requirement for light absorbing material in polymer solar cell. Polymer solar cell has lot of advantages over silicon based solar cell. But the synthesis of solar light absorbing polymers with higher molecular weight requires many synthetic steps and most of the synthesized polymers with higher molecular weights are not solution processable. Therefore, it is very difficult to synthesize solution processable solar light absorbing polymers with high molecular weight. This article reports the development of a novel one-pot synthetic method for the preparation of a light absorbing polymeric material with solution processability. Beetroot dye showed good absorption from the UV-Visible region of the electromagnetic spectrum. Hence it can be used as a light absorbing material in organic solar cell. But it will not form uniform film because of its low molecular weight. In this work, a new material is prepared by mixing beetroot dye with polyvinyl alcohol (PVA). PVA is selected because of its low cost, water solubility, high mechanical strength and good film forming properties. This new material combined the photo physical properties of beetroot dye along with high mechanical strength of polymers. This approach can be extended for the synthesis of large number of semiconducting polymeric materials with solution processability in large scale.

1.
P. K.
Nayak
,
S.
Mahesh
,
H. J.
Snaith
and
D.
Cahen
, "
Photovoltaic Solar Cell Technologies: Analysing the State of the Art
",
Nat. Rev. Mater
,
4
,
269
285
(
2019
).
2.
J.
Gong
,
C.
Li
,
M. R.
Wasielewski
, "
Advances in Solar Energy Conversion
",
Chem. Soc. Rev.
,
48
,
1862
1864
(
2019
)
3.
N. S.
Lewis
, "
Introduction: Solar Energy Conversion
",
Chem. Rev.
,
115
(
23
),
12631
12632
(
2015
).
4.
T. D.
Lee
and
A. U.
Ebong
. "
A Review of Thin Film Solar Cell Technologies and Challenges
",
Renew. Sust. Energ. Rev.
,
70
,
1286
1297
(
2017
).
5.
E. W.
Diau
, "
Next Generation Solar Cells and Conversion of Solar Energy
",
ACS Energy Lett.
,
2
(
2
),
334
335
, (
2017
).
6.
G. J.
Hedley
,
A.
Ruseckas
and
D. W
,
Samuel
, "
Light Harvesting for Organic Photovoltaics
",
Chem. Rev.
,
117
(
2
),
796
837
(
2017
).
7.
C.
Lee
,
S.
Lee
,
G.
kim
,
W.
Lee
and
B. J.
Kim
, "
Recent Advances, Design Guidlines and Prospects of All- Polymer Solar Cells
",
Chem. Rev.
,
119
(
13
),
8028
8086
(
2019
).
8.
G. S.
Gautam
,
T. P.
Senftle
,
N.
Alidoust
and
E. A.
Carter
, "
Novel Solar Cell Materials: Insights from First- Principles
",
J. Phys. Chem. C
,
122
(
48
),
27107
27126
(
2018
).
9.
H.
Yao
,
F.
Bai
,
H.
Hu
,
L.
Arunagiri
,
J.
Zhang
,
Y.
Chen
,
H.
Yu
,
S.
Chen
,
T.
Liu
,
J. Y. Lin
Lai
,
Y.
Zou
,
H.
Ade
and
He
Yan
, "
Efficient All-Polymer Solar Cell based on a New Polymer Acceptor Achieving 10.3% Power conversion Efficiency
",
ACS Energy Lett.
,
4
(
2
),
417
422
(
2019
).
10.
F. C.
Krebs
, "
Fabrication and Processing of Polymer Solar Cell: A Review of Printing and Coating Techniques
",
Sol. Energy mater. Sol. Cells
,
93
(
4
),
394
412
(
2009
).
11.
C. A.
Finch
, "Polyvinyl Alcohol-Developments",
Wiley-Blackwell
, 2nd edition,
1992
.
12.
V.
Goodship
and
D.
Jacobs
, "Polyvinyl Alcohol: Materials, Processing and Applications",
Smithers Rapra Press
,
2009
.
13.
C. A.
Finch
, "Polyvinyl Alcohol: Properties and Applications",
London: New York
:
Wiley
,
1973
.
14.
N. B.
Halima
, "
Poly(vinylalcohol): Review of its Promising Applications and insights into biodegradation
",
RSC Adv.
,
6
,
39823
39832
(
2016
).
15.
Y. Nishio. R. St. J.
Manley
,
"Cellulose/Poly(vinyl alcohol) Blends Prepared from Solutions in N,N- Dimethylacetamide-Lithium Chloride
,
Macromolecules
,
21
,
1270
1277
(
1988
).
16.
H.
Li
,
S.
Chen
,
Y.
Wang
, "
Thermoplastic PVA/PLA Blends with Improved Processability and Hydrophobicity
",
Ind. Eng. Chem. Res.
53
(
44
),
17355
17361
(
2014
).
17.
D.
Starck
,
T.
Vogt
and
W.
Schliemann
, "
Recent Advances in Betalain Research
",
Phytochemistry
,
62
(
3
),
247
69
, (
2003
).
18.
R.
Robinson
, "
Nature of Betanine, the Pigment of Red Beet
",
Nature
,
182
(
46
) (
1958
).
19.
G.
Calogero
,
A.
Bartolotta
,
G. D.
Marco
,
A. D.
Carlo
,
F.
Bonaccorso
, "
Vegetable-based Dye-Sensitized Solar Cells
",
Chem. Soc. Rev.
,
44
,
3244
3294
(
2015
).
20.
A.
Dumbrava
,
I.
Enache
,
C. I.
Oprea
and
A.
Georgescu
, "
Towards a More Efficient Utilisation of Betalains as pigments for Dye-Sensitized Solar Cells
",
DIG J. Nanomater. Bio.
,
7
(
1
),
339
351
(
2012
).
21.
B. J.
Clark
,
T.
Frost
,
M. A.
Russell
, "UV Spectroscopy Techniques, Instrumentation, Data Handling",
Chapman & Hall
,
London
(
1993
).
This content is only available via PDF.
You do not currently have access to this content.