The work aims to create a formalized scheme of the hydrocarbons transformation in the catalytic cracking with the participation of high-molecular hydrocarbons of vacuum distillate in order to predict the gasoline group composition and the gases individual composition. Thermodynamic parameters of the most probable reactions of cracking gases formation under technological conditions of the process using the reference data and Density Functional Theory are determined; the features of the mechanism of hydrocarbon transformations on acid catalysts determining the high content of isoalkanes, alkenes, aromatic hydrocarbons in cracking products are taken into account.
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