A series of new D-π-A chromophores containing a triphenylamine fragment as a terminal electron-donating group, as well as (5,5-dimethylcyclohex-2-en-1-ylidene) propanedinitrile or (6-methyl-4H-pyran-4-ylidene) propanedinitrile fragments as an acceptor. A comparative analysis of the optical and electrochemical properties of the obtained compounds is carried out. It was found that the replacement of the (5,5-dimethylcyclohex-2-en-1-ylidene) propanedinitrile fragment with a (6- methyl-4H-pyran-4-ylidene) propanedinitrile fragment leads to a slight increase in the bandgap of the compound, while the coefficient increases significantly molar absorption, as well as the quantum yield of luminescence.
REFERENCES
1.
L. R.
Dalton
, P.
Günter
, M.
Jazbinsek
, Ph. A.
Sullivan
and O-P.
Kwon
, Organic Electro-Optics and Photonics: Molecules, Polymers and Crystals
(Cambridge University Press
, Cambridge
, 2015
), pp. 1
–10
.2.
J.
Liu
, G.
Xu
, F.
Liu
, I.
Kityk
, X.
Liu
and Zh.
Zhen
, RSC Adv.
5
, 15784
–15794
(2015
).3.
V.
Shelkovnikov
, G.
Selivanova
, G.
Lyubas
, S.
Korotaev
, I.
Shundrina
, E.
Tretyakov
, E.
Zueva
, A.
Plekanov
, S.
Mikerin
and A.
Simanchuk
, Opt. Mater.
69
, 67
–72
(2017
).4.
G.
Melikian
, F. P.
Rouessac
and Ch.
Alexandre
, Synth. Commun.
25
, 3045
–3051
(1995
).5.
Q.
Cheng
, X.
Shi
, Ch.
Li
, Y.
Jiang
, Z.
Shi
, J.
Zou
, X.
Wang
, X.
Wang
and Zh.
Cui
, Dyes Pigments
162
, 721
–727
(2019
).6.
J.
Holtmann
, E.
Walczuk
, M.
Dede
, Ch.
Wittenburg
, J.
Heck
, G.
Archetti
, R.
Wortmann
, H.-G.
Kuball
, Y.-H.
Wang
, K.
Liu
, and Y.
Luo
, J. Phys. Chem. B
112
, 14751
–14761
(2008
).7.
M.
Li
, X.
Zhang
, Z.
Shi
, Y.
Wan
, L.
Zhao
, R.
Jin
, Y.
Yu
, M.
Yi
and Zh.
Cui
, Opt. Mater.
34
, 705
–710
(2012
).8.
M.
Li
, H.
Zhang
, Y.
Zhang
, B.
Hou
, Ch.
Li
, X.
Wang
, J.
Zhang
, L. H.
Xiao
, Zh.
Cui
and Y.
Ao
, J. Mater. Chem. C
4
, 9094
–9102
(2016
).9.
X.
Zhang
, M.
Li
, Z.
Shi
, L.
Zhao
, R.
Jin
, M.
Yi
, D.
Zhang
and Zh.
Cui
, Dyes Pigments
92
, 982
–987
(2012
).10.
R.
Andreu
, L.
Carrasquer
, S.
Franco
, J.
Garín
, J.
Orduna
, N. M.
Baroja
, R.
Alicante
, B.
Villacampa
, and M.
Allain
, J. Org. Chem.
74
, 6647
–6657
(2009
).11.
A. R.
Morales
, A.
Frazer
, A. W.
Woodward
, H.-Y.
Ahn-White
, A.
Fonari
, P.
Tongwa
, T.
Timofeeva
and K. D.
Belfield
, J. Org. Chem.
78
, 1014
–1025
(2013
).12.
Z.
Shi
, X.
Zhang
, G.
Yang
, Zh.
Su
and Zh.
Cui
, Tetrahedron
67
, 4110
–4117
(2011
).13.
S.
Koyuncu
, C.
Zafer
, E.
Sefer
, F. B.
Koyuncu
, S.
Demic
, I.
Kaya
, E.
Ozdemir
and S.
Icli
, Synth. Met.
159
, 2013
‒2021
(2009
).14.
E. T.
Seo
, R. F.
Nelson
, J. M.
Fritsch
, L. S.
Marcoux
, D. W.
Leedy
, R. N.
Adams
, J. Am. Chem. Soc.
88
, 3498
−3503
(1966
).
This content is only available via PDF.
© 2020 Author(s).
2020
Author(s)
You do not currently have access to this content.