A nanofiber-based of dye-sensitized solar cell (DSSC) attracts high interest for researchers due to its high efficiency, low cost, and mass production availability. This paper investigated the electrospinning machine to fabricate ZnO nanofiber and will be used as photoanode of DSSC. Direct deposition method was applied on electrospinning machine to directly capture the liquid jet electrospun of ZnO solution on transparent conductive oxide (TCO) glass. The stream velocity variation of 4, 6 and 8 µl/min were conducted to investigate its effects on ZnO nanofiber morphology. The results showed that at the stream velocity of 4 µl/min produced small average droplet size, and uniform morphology with a diameter of 138.20 nm. Furthermore, it also obtained the highest electrical efficiency of DSSC due to high of dye absorbance and electron excitation.

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