Due to their characteristics of high power, high energy density, high thermal stability and long-life time, NMC metal-based cathode material for lithium ion become one of the most popular material and widely used in the automotive industry. In this study, material of LiNi0.33Mn0.33Co0.33O2 (NMC 111) was synthesized via urea-assisted solid state method. The effect of urea addition of 0, 20, 40, 60 %wt/wt was investigated. Sintering process was carried out at 800°C for 12 hours. The structure of NMC 111 material was analyzed using X-ray Diffraction (XRD). The XRD pattern showed that material of NMC 111 has been successfully synthesized which is indexed well to JCPDS card #20-0781. Cylindrical battery was used to test the electrochemical performance of NMC 111 material. The best of electrochemical performance was obtained by NMC 111 material with 40 %wt addition of urea.

1.
S. U.
Muzayanha
 et al, “
Lithium Nickel Cobalt Aluminum Oxide Material from Cathode Waste
,”
Metals (Basel).
, vol.
9
, p.
615
,
2019
.
2.
F.
Wu
,
X.
Li
,
Z.
Wang
, and
H.
Guo
, “
Synthesis of chromium-doped lithium titanate microspheres as high- performance anode material for lithium ion batteries
,”
Ceram. Int.
, vol.
40
, no.
8 PART B
., pp.
13195
13204
,
2014
.
3.
L.
Gou
 et al, “
One-pot synthesis of a metal-organic framework as an anode for Li-ion batteries with improved capacity and cycling stability
,”
J. Solid State Chem.
, vol.
210
, no.
1
, pp.
121
124
,
2014
.
4.
A.
Purwanto
,
C. S.
Yudha
,
U.
Ubaidillah
,
H.
Widiyandari
,
T.
Ogi
, and
H.
Haerudin
, “
NCA cathode material: Synthesis methods and performance enhancement efforts
,”
Mater. Res. Express
, vol.
5
, no.
12
,
2018
.
5.
E. J.
Cheng
,
K.
Hong
,
N. J.
Taylor
,
H.
Choe
,
J.
Wolfenstine
, and
J.
Sakamoto
, “
Mechanical and physical properties of LiNi0.33Mn0.33Co0.33O2 (NMC
),”
J. Eur. Ceram. Soc.
, vol.
37
, no.
9
, pp.
3213
3217
,
2017
.
6.
S.
Phadke
and
M.
Anouti
, “
Effect of lithium salt concentration on the capacity retention of Lithium rich NMC cathodes
,”
Electrochim. Acta
, vol.
223
, no.
December
, pp.
31
38
,
2017
.
7.
D.
Doughty
and
E. P.
Roth
, “
A general discussion of Li Ion battery safety
,”
Electrochem. Soc. Interface
, vol.
21
, no.
2
, pp.
37
44
,
2012
.
8.
S.
Liu
,
Z.
Dang
,
D.
Liu
,
C.
Zhang
,
T.
Huang
, and
A.
Yu
, “
Comparative studies of zirconium doping and coating on LiNi 0.6 Co 0.2 Mn 0.2 O 2 cathode material at elevated temperatures
,”
J. Power Sources
, vol.
396
, no.
May
, pp.
288
296
,
2018
.
9.
H.
Widiyandari
,
A. N.
Sukmawati
,
H.
Sutanto
,
C.
Yudha
, and
A.
Purwanto
, “
Synthesis of LiNi0.8Mn0.1Co0.1O2 cathode material by hydrothermal method for high energy density lithium ion battery
,”
J. Phys. Conf. Ser.
, vol.
1153
, no.
1
, pp.
0
7
,
2019
.
10.
L.
Kang
,
L.
Zhang
,
H.
Zou
,
Z.
Deng
,
Y.
Zhang
, and
L.
Chen
, “
Urea-assisted hydrothermal synthesis of manganese dioxides with various morphologies for hybrid supercapacitors
,”
J. Alloys Compd.
, vol.
648
, pp.
190
194
,
2015
.
11.
C. S.
Yudha
,
S. U.
Muzayanha
,
H.
Widiyandari
,
F.
Iskandar
,
W.
Sutopo
, and
A.
Purwanto
, “
and its Performance in an NCA / Graphite Full-Battery
,”
energies
, vol.
12
, p.
1886
,
2019
.
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