Nanoparticles of multiferroic BiFeO3-xPbTiO3 (BF-0.2PT) was synthesized using sol-gel process in the size range of 50-160 nm. The optimization procedure for the preparation pure single phase was carefully investigated and structural effects are addressed. The Rietveld refinement shows ∼14.6% tetragonal phase is present in bismuth rich compostion, whose tetragonality is around 20.4%. The results indicate that the size and morphology of sample changes with sintering temperature.

1.
Yu
.
E.
Roginskaya
,
Yu
.
Ya.
Tomashpolskii
,
Yu. N.
Venevtsev
,
V. M.
Petrov
and
G.S.
Zhdanov
,
Sov Phys JETP
23
,
47
51
(
1966
).
2.
W.
Kaczmarek
,
Z.
Pajak
and
M.
Polomska
,
Solid State Commun
17
,
807
810
(
1975
).
3.
J. L.
Dormann
,
D.
Fiorani
and
E.
Tronc
,
Adv. Chem. Phys.
98
,
283
(
1997
).
4.
A.
Pankhurst
,
J.
Conolly
,
S.K.
Jones
and
J.
Dobson
,
J. Phys. D Appl. Phys.
36
,
R167
(
2003
).
5.
J.
Chaigneau
,
R.
Haumont
and
J.M.
Kiat
,
Phys Rev B.
80
,
184107
(
2009
).
6.
R.
Mazumder
and
A.
Sen
,
J Alloys Compd
475
,
577
580
(
2009
)
7.
S.M.
Selbach
,
T.
Tybell
,
M. A.
Einarsrud
and
T.
Grande
,
Chem. Matter
21
,
5176
5186
(
2009
).
8.
T.J.
Park
,
G.C.
Papaefthymiou
,
A.J.
Viescas
,
A.R.
Moodenbaugh
and
S.
Wong
,
Nano Letters
7
,
766
(
2007
).
9.
R.T.
Smith
,
G.D.
Achenbach
,
R.
Gerson
and
W.J.
James
,
J Appl Phys
39
,
70
74
(
1968
).
10.
T.J.
Park
,
G.C.
Papaefthymiou
,
A.J.
Viescas
,
Y.
Lee
,
H.
Zhou
and
S.S.
Wong
,
Phys Rev B
82
,
024431
(
2010
)
11.
W.–M.
Zhu
,
H. –Y
Guo
, and
Z.-G
Ye
,
Phys. Rev. B
78
,
014401
(
2008
).
12.
T.P.
Comyn
,
D.F.
Kanguwe
,
J.Y.
He
and
A.P.
Brown
,
J Eur Ceram Soc
28
,
2233
2238
(
2008
)
13.
J.
Prado-Gonjal
,
M. E.
Villafuerte-Castrejón
,
L.
Fuentes
and
E.
Morán
Mater Res Bull
44
,
1734
1737
(
2009
).
14.
T.T.
Carvalho
and
P.B.
Tavares
,
Mater Lett
62
,
3984
3986
(
2008
)
15.
T.P.
Comyn
,
T.
Stevenson
,
M. A.
Jawad
,
S.L.
Turner
,
R.I.
Smith
,
A.J.
Bell
and
R.
Cywinski
,
J Appl Phys.
105
,
094108
(
2009
).
16.
I.
Sosnowska
,
R.
PrzeniosŁo
,
A.
Palewicz
,
D.
Wardecki
and
A.
Fitch
,
J. Phys. Soc. Japan
81
,
044604
(
2012
).
17.
Rodriguez-Carvajal Lab
.
FULLPROF, A Rietvield pattern matching Anal. program
,
Lab. Leon Brillouin CEA-CNRS, Fr.
18.
V. V. S. S.
,
Sai Sunder
,
A.
Halliyal
and
A.M.
Umarji
,
J. Mater. Res.
10
,
1301
1306
, (
1995
).
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