Nd2O3 doped glass samples with compositions xNd2O3-(100-x) [0.1BaO-0.4ZnO-0.5B2O3]; x = 0.5, 1.0, 1.5 and 2.0 have been prepared using melt quench technique. Optical absorption spectra have been recorded for prepared glass samples at room temperature. The spectral intensities of Nd3+ transition observed in absorption spectra have been calculated by using Judd-Ofelt theory. The intensity parameters (Ω2, Ω4 and Ω6) have been estimated by applying least square fit method on the experimental (fexp) and calculated (fcal) oscillator strengths. The values of Ω2 increase with the increase in concentration of Nd3+ ions in the host glass matrix which suggests that the Nd3+ ions are covalent nature with the surrounding ligand.
REFERENCES
1.
B.D.
Bartolo
, O.
Forte
, Advances in Spectroscopy for Lasers and Sensing
, Springer
, Netherland
(2006
).2.
J.B.
Hedrick
, REE Handbook-The ultimate Guide to Rare Earth Elememts
, Toronto, Canada
(2012
).3.
4.
E.M.
Yoshimura
, C.N.
Santos
, A.
Ibanez
, A.C.
Hernandes
, Opt. Mater.
31
(2009
) 795
–799
.5.
S.
Arunkumar
, K.
Marimuthu
, J. Alloys Compd.
565
(2013
) 104
.6.
B. C.
Jamalaiah
, J. S.
Kumar
, A. M.
Babu
, T.
Suhasini
, L. R.
Moorthy
, J. Lumin.
29
(2009
) 363
.7.
B. R.
Judd
, Phys. Rev.
127
(1962
) 750
.8.
G. S.
Ofelt
, J. Chem. Phys.
37
(1962
) 511
.9.
H.
Doweidar
, G. M.
ElDamrawi
, Y. M.
Moustafa
, R. M.
Ramadan
, Phys. B
362
(2005
) 123
.10.
G. H.
Dieke
, Spectra and Energy Levels of Rare Earth Ions in Crystals
, Interscience
, New York
(1968
).11.
B. C.
Jamalaiah
, T.
Suhasini
, L. R.
Moorthy
, G.
Kim
, D.
Yoo
and K.
Jang
, J. Lumin.
132
(2012
) 1144
.12.
B. R.
Judd
, Phys. Rev.
127
(1962
) 750
.13.
G. S.
Ofelt
, J. Chem. Phys.
37
(1962
) 511
.14.
S. P.
Sinha
, in: Complexes of the Rare Earth
, Pergamon Press
, Oxford
, 1966
.15.
W. T.
Carnall
, P. R.
Fields
, B. G.
Wybourne
, J. Chem. Phy.
42
(1965
) 3797
.16.
C. K.
Jorgensen
, R.
Reisfeld
, J. Less-Commom Met.
93
(1983
) 107
.17.
B.
Shanmugavelu
, V.
Venkatramu
, V. V. R. K.
Kumar
, Spectro. Acta A: Mol. Biomol. Spec.
122
(2014
) 422
.18.
Kirti
Nanda
, R. S.
Kundu
, Inder
Pal
, R.
Punia
and N.
Kishore
, J. Alloys Compd.
676
(2016
) 521
.19.
P.
Babu
, C. K.
Jayashankar
, Opt. Mater.
15
(2000
) 65
.
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