In the present study, oxide layer was formed on zirconium substrate by plasma electrolytic oxidation (PEO). The zirconia nanoparticles were incorporated in to the PEO coating structure by the electrophoretic deposition process (EPD). The coating was produced in an alkaline phosphate electrolyte with a time period of 6 min. The microstructural features, phase composition, wettability properties and corrosion behavior were analyzed. The nanoparticle incorporation substantially modifies the surface morphology. The thickness of the coating found to be increased with the particle addition. Wettability also enhanced. The electrochemical corrosion studies indicate that the nanoparticle addition very well enhanced the corrosion resistance properties of the coating.

1.
Raj
B
and
Mudali
U K
, “
Materials development and corrosion problems in nuclear fuel reprocessing plants
” (
Progress in Nuclear Energy
,
2006
) pp.
283
313
.
2.
A.R.
Shankar
,
V.R.
Raju
,
M.N.
Rao
,
U.K.
Mudali
,
H.S.
Khatak
and
B.
Raj
, “
Corrosion of Zircaloy-4 and its welds in nitric acid medium
”, (
Corros. Sci.
49
2007
), pp.
3527
3538
.
3.
Yardley
S. S.
,
Moore
K. L.
,
Nani
,
Wei
J. F.
,
Lyon
S.
,
Preuss
M.
and
Grovenor
C. R. M.
, “
An investigation of the oxidation behaviour of zirconium alloys using isotopic tracers and high-resolution SIMS
”, (
Journal of Nuclear Materials
,
2003
), pp.
436
443
.
4.
N.J.
Fisher
,
M.K.
Weckwerth
,
D.A.E.
Grandison
and
B.M.
Cotnam
, “
Fretting-wear of zirconium alloys
”, (
Nucl. Eng. Des.
213
,
2002
), pp.
79
90
.
5.
Shanmugavelayutham
G
,
Yano
S
and
Kobayashi
A
, “
Microstructural Characterization and Properties of ZrO2/Al2O3 Thermal Barrier Coatings by Gas Tunnel-Type Plasma Spraying
”, (
Vacuum
,
80
,
2006
), pp.
1336
1340
.
6.
A.L.
Yerokhin
,
X.
Nie
,
A.
Leyland
,
A.
Matthews
and
S. J.
Dowey
, “
Plasma electrolysis for surface engineering
”, (
Surf. Coat. Technol.
,
122
,
1999
), pp.
73
93
.
7.
R.
Hussein
,
X.
Nie
and
D.O.
Northwood
, “
Coating growth behavior during the plasma electrolytic oxidation process
”, (
Journal of Vacuum Science & Technology A
28
,
766
,
2010
).
8.
Y.
Chen
,
X.
Nie
and
D.O.
Northwood
, “
Investigation of Plasma Electrolytic Oxidation (PEO) coatings on a Zr-2.5Nb alloy using high temperature/pressure autoclave and tribological tests
”, (
Surf. Coat. Technol.
205
2010
), pp.
1774
1782
.
9.
Y.L.
Cheng
and
F.
Wu
, “
Plasma electrolytic oxidation of zircaloy-4 alloy with DC regime and properties of coatings
”, (
Trans. Nonferrous Met. Soc. China
22
,
2012
), pp.
1638
1646
.
10.
Z.
Zou
,
W.
Xue
,
X.
Jia
,
J.
Du
,
R.
Wang
and
L.
Weng
, “
Effect of voltage on properties of microarc oxidation films prepared in phosphate electrolyte on Zr-1Nb alloy
”, (
Surf. Coat. Technol.
222
,
2013
), pp.
62
67
.
11.
Cheng
Y
,
Wu
F
,
Matykina
E
,
Skeldon
P
and
Thompson
G E
, “
Formation of grooved and porous coatings on titanium by plasma electrolytic oxidation in H2SO4/H3PO4 electrolytes and effects of coating morphology on adhesive bonding
”, (
Corros Sci
59
,
2012
)
307
.
12.
K. K.,
Yadlapati
,
S.
,
Chidepudi
,
S. N. S.
,
Manikandan
,
M.
,
Arivarasu
,
M.
,
K.
Ramkumar
, D. and
Arivazhagan
,
N.
, “
Performance of Zirconium Dioxide Coatings by plasma spray coatings on Inconel 625 in Air oxidation and molten salt environment at 800 °c
”, (
International Journal of Chem Tech Research
,
2014
) pp.
2744
2749
.
13.
N.
Poongothai
,
Athira
,
R.
and
Neena
,
P. K.
, “
A green approach to preparing bio-inhibitor for mild steel corrosion in different acid mediums
”, (
International Journal of Engineering and Technology (UAE)
, vol.
7
,
2018
), pp.
322
329
.
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