Solvent effect on aggregation properties of the monosubstituted pillar[5]arenes containing N-alkyl amide fragments with the different length of the substituent has been investigated. It was shown by transmission and scanning electron microscopy that the monoamide derivatives based on the pillar[5]arene form various types of associates depending on the solvent. The ability of the investigated pillar[5]arenes to form supramolecular polymers in chloroform and nanometer-sized spherical particles in DMSO has been established. Moreover, it was found that the addition of water to the solutions of pillar[5]arene in DMSO led to formation of supramolecular polymers, while the addition of alcohol did not affect the type of formed associates.
REFERENCES
1.
J. W.
Steed
and J. L.
Atwood
, Supramolecular Chemistry, Second Edition
(John Wiley & Sons, Ltd
, United States
, 2009
).2.
R. V.
Shamagsumova
, D. N.
Shurpik
, P. L.
Padnya
, I. I.
Stoikov
and G. A.
Evtgyn
, Talanta
144
, 559
–568
(2015
).3.
X.-Y.
Hu
, X.
Liu
, W.
Zhang
, Sh.
Qin
, C.
Yao
, Y.
Li
, D.
Cao
, L.
Peng
and L.
Wang
, Chem. Mater.
28
, 3778
–3788
(2016
).4.
K. S.
Shibaeva
, A. A.
Nazarova
and I. I.
Stoikov
, Phosphorus Sulfur
191
, 1585
–1586
(2016
).5.
Z. V.
Singh
, L.-L.
Tan
, M. G.
Cowan
, Y.-W.
Yang
, W.
Zhang
, D. L.
Gin
and R. D.
Noble
, J. Membrane Sci.
539
, 224
–228
(2017
).6.
B.
Xia
, B.
Zheng
, C.
Han
, S.
Dong
, M.
Zhang
, B.
Hu
, Y.
Yub
and F.
Huang
, Polym. Chem.
4
, 2019
–2024
(2013
).7.
T.
Ogoshi
, S.
Kanai
, Sh.
Fujinami
, T.-A.
Yamagishi
and Y.
Nakamoto
, J. Am. Chem. Soc.
130
, 5022
–5023
(2008
).8.
Y.
Yao
, M.
Xue
, J.
Chen
, M.
Zhang
and F.
Huang
, J. Am. Chem. Soc.
134
, 15712
–15715
(2012
).9.
N. L.
Strutt
, H.
Zhang
, M. A.
Giesener
, J.
Lei
and J. F.
Stoddart
, Chem. Commun.
48
, 1647
–1649
(2012
).10.
A. A.
Nazarova
, L. I.
Makhmutova
and I. I.
Stoikov
, Russ. J. Gen. Chem.
87
, 1941
–1945
(2017
).11.
C.
Han
, D.
Zhao
, H.
Li
, H.
Wang
, X.
Huang
and D.
Sun
, ChemistrySelect.
3
, 11
–14
(2018
).12.
T.
Ogoshi
, K.
Demachi
, K.
Kitajima
and T.-A.
Yamagishi
, Chem. Commun.
47
, 7164
–7166
(2011
).13.
Sh.
Sun
, X.-Y.
Hu
, D.
Chen
, J.
Shi
, Y.
Dong
, Ch.
Lin
, Y.
Pan
and L.
Wang
, Polym. Chem.
4
, 2224
–2229
(2013
).14.
X.
Cheng
, H.
Li
, F.
Zheng
, Q.
Lin
, Y.
Zhang
, H.
Yao
and T.
Wei
, Dyes Pigments
127
, 59
–66
(2016
).15.
H.
Zhang
, X.
Ma
, J.
Guo
, K. T.
Nguyen
, Q.
Zhang
, X.-J.
Wang
, H.
Yan
, L.
Zhu
and Y.
Zhao
, RSC Adv.
3
, 368
–371
(2013
).16.
N. L.
Strutt
, R. S.
Forgan
, J. M.
Spruell
, Y. Y.
Botros
and J. F.
Stoddart
, J. Am. Chem. Soc.
133
, 5668
–5671
(2011
).17.
T.
Boinski
and A.
Szumna
// Tetrahedron
68
, 9419
–9422
(2012
).18.
K.
Wang
, L. L.
Tan
, D. X.
Chen
, N.
Song
, G.
Xi
, S. X. A.
Zhang
, Ch.
Lib
and Y. W.
Yang
, Org. Biomol. Chem.
10
, 9405
–9409
(2012
).19.
A. A.
Nazarova
, K. S.
Shibaeva
and I. I.
Stoikov
, Phosphorus Sulfur
191
, 1583
–1584
(2016
).20.
A. A.
Nazarova
, L. S.
Yakimova
, V. V.
Klochkov
and I. I.
Stoikov
, New J. Chem.
41
, 1820
–1826
(2017
).21.
L.
Yang
, X.
Tan
, Z.
Wang
, X.
Zhang
, Chem. Rev.
115
, 7196
–7239
(2015
).22.
C.
Schönbeck
, H.
Li
, B.-H.
Han
and B. W.
Laursen
, J. Phys. Chem. B
119
, 6711
–6720
(2015
).
This content is only available via PDF.
© 2019 Author(s).
2019
Author(s)
You do not currently have access to this content.
