Corrosion become major problem in most industries. In the oil and gas company, corrosion occurs because of reaction between steel and chemical species inside crude oil. Crude oil or nature gas provide corrosive species, such as CO2, O2, H2S and so on. Fluid containing CO2 gas causes CO2 corrosion which attack steel as well as other corrosion phenomena. This CO2 corrosion commonly called as sweet environment and produce FeCO3 as corrosion products. Fluid flow factor in pipelines during the oil and gas transportation might increase the rate of corrosion itself. Inhibitor commonly use used as corrosion protection because its simplicity in usage. Nowadays, organic inhibitor become main issue in corrosion protection because of biodegradable, low cost, and environmental friendly. This research tried to use tobacco leaf extract as organic inhibitor to control corrosion in CO2 environment. The electrolyte solution used was 3.5% NaCl at pH 4 and pH 7. Weight loss test results showed that the lowest corrosion rate was reach at 132.5 ppm inhibitor, pH 7 and rotational speed of 150 rpm with corrosion rate of 0.091 mm/y. While at pH 4, the lowest corrosion rate was found at rotational speed of 150 rpm with inhibitor concentration of 265 ppm and corrosion rate of 0.327 mm/y. FTIR results indicate the presence of nicotine functional groups on the steel surface. However, based on corrosion rate, it is believed that corrosion occurs, and FeCO3 was soluble in electrolyte. Tobacco leaf extract inhibitors worked by a physisorption mechanism, where tobacco inhibitors formed thin layer on the steel surface.
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3 April 2018
PROCEEDINGS OF THE 3RD INTERNATIONAL CONFERENCE ON MATERIALS AND METALLURGICAL ENGINEERING AND TECHNOLOGY (ICOMMET 2017) : Advancing Innovation in Materials Science, Technology and Applications for Sustainable Future
30–31 October 2017
Surabaya, Indonesia
Research Article|
April 03 2018
Effect of fluid flow, pH and tobacco extracts concentration as organic inhibitors to corrosion characteristics of AISI 1045 steel in 3.5% NaCl environment containing CO2 gas Available to Purchase
Budi Agung Kurniawan;
Budi Agung Kurniawan
a)
1
Materials Engineering Department, Institut Teknologi Sepuluh Nopember Kampus ITS Keputih Sukolilo Surabaya
Indonesia
a)Corresponding author: [email protected]
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Vania Mitha Pratiwi;
Vania Mitha Pratiwi
1
Materials Engineering Department, Institut Teknologi Sepuluh Nopember Kampus ITS Keputih Sukolilo Surabaya
Indonesia
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Nafi’ul Fikri Ahmadi
Nafi’ul Fikri Ahmadi
1
Materials Engineering Department, Institut Teknologi Sepuluh Nopember Kampus ITS Keputih Sukolilo Surabaya
Indonesia
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Budi Agung Kurniawan
1,a)
Vania Mitha Pratiwi
1
Nafi’ul Fikri Ahmadi
1
1
Materials Engineering Department, Institut Teknologi Sepuluh Nopember Kampus ITS Keputih Sukolilo Surabaya
Indonesia
a)Corresponding author: [email protected]
AIP Conf. Proc. 1945, 020050 (2018)
Citation
Budi Agung Kurniawan, Vania Mitha Pratiwi, Nafi’ul Fikri Ahmadi; Effect of fluid flow, pH and tobacco extracts concentration as organic inhibitors to corrosion characteristics of AISI 1045 steel in 3.5% NaCl environment containing CO2 gas. AIP Conf. Proc. 3 April 2018; 1945 (1): 020050. https://doi.org/10.1063/1.5030272
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