In this study, strong acid doped polyaniline (PANi) has been successfully fabricated through the chemical oxidative polymerization process with various polymerization times. Nonconducting PANi resulting from the polymerization process at various polymerization times were then doped by a strong acid HClO4 to generate dielectric properties. Ammonium Persulfate (APS) as an initiator was used during Polymerization process to develop dark green precipitates which then called Emeraldine Base Polyaniline (PANi-EB). The PANi-EB was successively doped by strong acid HClO4 with dopant and PANi ratio 10:1 to enhance the electrical conductivity. The conductivity of doped PANi was evaluated by Four Point Probe. Results of evaluation showed that the conductivity values of HClO4 doped PANi were in the range 337-363 mS/cm. The dielectric properties of doped PANi were evaluated by Vector Network Analyzer (VNA) which suggested that an increase in the permittivity value in the conducting PANi. It is concluded that PANi could be a potential candidate for electromagnetic waves absorbing materials.

1.
S.
Bhadra
,
D.
Khastgir
,
N. K.
Singha
, and
J.
Hee
, “
Progress in Polymer Science Progress in preparation, processing and applications of polyaniline
,” vol.
34
, pp.
783
810
,
2009
.
2.
N. Y.
Abu-thabit
, “
Chemical Oxidative Polymerization of Polyaniline: A Practical Approach for Preparation of Smart Conductive Textiles
,”
2016
.
3.
J.
Huang
, “
Syntheses and applications of conducting polymer polyaniline nanofibers
*,” vol.
78
, no.
1
, pp.
15
27
,
2006
.
4.
S.
Wai
,
M.
Tadokoro
,
J.
Watanabe
, and
N.
Kuramoto
, “
Synthesis, characterization and microwave absorption property of doped polyaniline nanocomposites containing TiO2 nanoparticles and carbon nanotubes
,” vol.
158
, pp.
251
258
,
2008
.
5.
I. Y.
Sapurina
and
M. A.
Shishov
, “
Oxidative Polymerization of Aniline : Molecular Synthesis of Polyaniline and the Formation of Supramolecular Structures
,”
2012
.
6.
Y.
Kim
,
J.
Yun
,
Y.
Lee
, and
H.
Kim
, “
Preparation and Characteristics of Conducting Polymer-Coated MWCNTs as Electromagnetic Interference Shielding Materials
,” vol.
12
, no.
1
, pp.
48
52
,
2011
.
7.
M.
Milojevic
,
B.
Marjanovic
, and
J.
Stejskal
, “
Synthesis and Characterization of Self-Assembled Polyaniline Nanotubes / Silica
,” pp.
7116
7127
,
2009
.
8.
P. C.
Maity
and
M.
Khandelwal
, “
Synthesis Time and Temperature Effect on Polyaniline Morphology and Conductivity
,” vol.
1
, no.
4
, pp.
37
42
,
2016
.
9.
E.
Agustiani
,
B. P.
Lapanporo
,
P. S.
Fisika
, and
U. T.
Pontianak
, “
Analisis Spektrum Serapan Optis Polianilin Hasil Sintesis Polimerisasi Kimia Interfasial
,” pp.
1
5
,
2008
.
10.
X.
Chen
,
C. A.
Yuan
,
C. K. Y.
Wong
,
H.
Ye
,
S. Y. Y.
Leung
, and
G.
Zhang
, “
Sensors and Actuators B : Chemical Molecular modeling of protonic acid doping of emeraldine base polyaniline for chemical sensors
,”
Sensors Actuators B. Chem.
, vol.
174
, pp.
210
216
,
2012
.
11.
M. A. E.
Hafizah
,
A.
Bimantoro
, and
A.
Manaf
, “
Synthesized of conductive polyaniline by solution polymerization technique
,”
Procedia Chem.
, vol.
19
, pp.
162
165
,
2016
.
12.
J.
Stejskal
and
R. G.
Gilbert
, “POLYANILINE. PREPARATION OF A CONDUCTING POLYMER (IUPAC Technical Report) Polyaniline Preparation of a conducting polymer (IUPAC Technical Report),” vol.
74
, no.
5
, pp.
857
867
,
2006
.
13.
“‘ Re - discovering ’ an old material, Polyaniline, for modern applications,” 2013.
14.
M.
Trchová
and
J.
Stejskal
, “
Polyaniline : The infrared spectroscopy of conducting polymer nanotubes (IUPAC Technical Report)
*,” vol.
83
, no.
10
, pp.
1803
1817
,
2011
.
15.
W.
Liu
,
X.
Yan
,
J.
Chen
,
Y.
Feng
, and
Q.
Xue
, “
Supplementary material
,”
2013
.
This content is only available via PDF.
You do not currently have access to this content.