The thermoforming process involves a previously extruded sheet of material being reheated to a softened state below the melting temperature and then forced into a mould either by a plug, air pressure or a combination of both. Thermoplastics such as polystyrene (PS) and polypropylene (PP) are commonly processed via thermoforming for products in the packaging industry. However, high density polyethylene (HDPE) is generally not processed via thermoforming and yet HDPE is extensively processed throughout the packaging industry. The aim of this study was to investigate the potential of thermoforming HDPE. The objectives were to firstly investigate the mechanical response under comparable loading conditions and secondly, to investigate the final mechanical properties post-forming. Obtaining in-process stress-strain behavior during thermoforming is extremely challenging if not impossible. To overcome this limitation the processing conditions were replicated offline using the QUB biaxial stretcher. Typical processing conditions that the material will experience during the process are high strain levels, high strain rates between 0.1-10s−1 and high temperatures in the solid phase (1). Dynamic Mechanical Analysis (DMA) was used to investigate the processing range of the HDPE grade used in this study, a peak in the tan delta curve was observed just below the peak melting temperature and hence, a forming temperature was selected in this range. HPDE was biaxially stretched at 128°C at a strain rate of 4s−1, under equal biaxial deformation (EB). The results showed a level of biaxial orientation was induced which was accompanied by an increase in the modulus from 606 MPa in the non-stretched sample to 1212MPa in the stretched sample.

1.
Plastics Europe [Internet]
. [cited 2016 Jul 18]. Available from: http://www.plasticseurope.org
2.
Li
Y
,
Chen
J
,
Yuan
Y
,
Shen
K
,
Guo
J.
Study on Properties and Structure of Near Melt Point Extruded High-Density Polyethylene
.
J Macromol Sci Part B.
2008
;
47
(
3
):
426
33
.
3.
Zheng
H
,
Wang
B
,
Zheng
G
,
Wang
Z
,
Dai
K
,
Liu
C
, et al. Study on Crystallization Kinetics of Partially Melting Polyethylene Aiming To Improve Mechanical Properties.
2014
;
4.
Bourgin
P
,
Cormeau
I
,
Saint-Matin
T.
A first step towards the modelling of the thermoforming of plastic sheets
.
J Mater Process Tech.
1995
;
54
(
1-4
):
1
11
.
5.
Menary
GH
,
Tan
CW
,
Harkin-Jones
EMA
,
Armstrong
CG
,
Martin
PJ
.
Biaxial Deformation and Experimental Study of PET at Conditions Applicable to Stretch Blow Molding
.
Polym Eng Sci.
2012
;
52
:
671
88
.
6.
Martin
PJ
,
Tan
CW
,
Tshai
KY
,
McCool
R
,
Menary
G
,
Armstrong
CG
, et al. 
Biaxial characterisation of materials for thermoforming and blow moulding
.
Plast Rubber Compos.
2005
;
34
(
5-6
):
276
82
.
7.
Wunderlich
B.
Crystal structure morphology, defects
.
Macromol Phys.
1973
;
1
(Academic Press).
8.
Hiss
R
,
Hobeika
S
,
Lynn
C
,
Strobl
G.
Network stretching, slip processes, and fragmentation of crystallites during uniaxial drawing of polyethylene and related copolymers
.
A comparative study. Macromolecules.
1999
;
32
(
13
):
4390
403
.
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