In this paper, the printing temperature ranges of PLA and PEEK, two semi-crystalline thermoplastics, have been investigated for the Fused Filament Fabrication (FFF) process. The printing range, comprised between the melting temperature and the degradation of each polymer, is 160°C to 190°C for PLA and 350°C to 390°C for PEEK. The complex viscosity has been measured for both polymers within the printing range. The kinetics of coalescence has been registered by measuring the bonding length between two filaments of the same polymer according to the temperature. At 167°C, the filaments of PLA reached the maximum value of bonding length. For PEEK, the filaments reached the maximum value of bonding length at 380°C. For the both materials, the final height of the filament is 80% of the initial diameter. The comparison of the obtained results with experimental study and predictive model shows a good agreement when the polymer is totally in fusion state.

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