Water electrolysis with a fast change of the polarity pumps in the liquid a huge amount of hydrogen and oxygen gases. In contrast with the DC electrolysis the gases do not form visible bubbles but change significantly the refractive index of the liquid nearby the electrodes from n = 1.35 to the values smaller than 1.19. The decrease of n is registered as distortion of the images of the electrodes. We argue that all the gas is collected in H2 and O2 nanobubbles with a size smaller than 200 nm. The concentration of nanobubbles with a size of 100 nm is estimated as 1021 m−3. Due to a significant contribution from the Laplace pressure the effective supersaturation reaches 500 for hydrogen and 150 for oxygen.
REFERENCES
1.
Khaselev
O
1998
Science
280
425
–427
2.
Zeng
K
and Zhang
D
2010
Prog. Energ. Combus.
36
307
–326
3.
Svetovoy
V B
, Sanders
R G P
, Lammerink
T S J
and Elwenspoek
M C
2011
Phys. Rev. E
84
035302(R)
.4.
Svetovoy
V
, Postnikov
A
, Uvarov
I
, Sanders
R
and Krijnen
G
2016
Energies
9
94
5.
Svetovoy
V B
, Sanders
R G P
, Ma
K
and Elwenspoek
M C
2014
Sci. Rep.
4
4296
6.
Weijs
J H
, Seddon
J R T
and Lohse
D
2012
Chem. Phys. Chem.
13
2197
–204
7.
Svetovoy
V B
, Sanders
R G P
and Elwenspoek
M C
2013
J. Phys. Condens. Mat.
25
184002
8.
Aspnes
D E
1982
Thin Solid Films
89
249
–262
.9.
Urréjola
S
, Sánchez
A
and Hervello
M F
2010
J. Chem. Eng. Data
55
, 2924
10.
Prokaznikov
A
, Tas
N
and Svetovoy
V
2017
Energies
10
178
11.
Ohgaki
K
, Khanh
N Q
, Joden
Y
, Tsuji
A
and Nakagawa
T
2010
Chem. Eng. Sci.
65
1296
–1300
12.
Ushikubo
F Y
, Furukawa
T
, Nakagawa
R
, Enari
M
, Makino
Y
Kawagoe
Y
et al. 2010
Colloids Surf. A: Physicochem. Eng. Asp.
361
31
–37
13.
Kikuchi
K
, Tanaka
Y
, Saihara
Y
and Ogumi
Z
2006
Electrochim. Acta
52
904
–913
14.
Kikuchi
K
, Ioka
A
, Oku
T
, Tanaka
Y
, Saihara
Y
and Ogumi
Z J
2009
Colloid. Interface Sci.
329
306
–309
15.
Alheshibri
M
, Qian
J
, Jehannin
M
, Craig
VSJ
2016
Langmuir
32
11086
–100
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