Water electrolysis with a fast change of the polarity pumps in the liquid a huge amount of hydrogen and oxygen gases. In contrast with the DC electrolysis the gases do not form visible bubbles but change significantly the refractive index of the liquid nearby the electrodes from n = 1.35 to the values smaller than 1.19. The decrease of n is registered as distortion of the images of the electrodes. We argue that all the gas is collected in H2 and O2 nanobubbles with a size smaller than 200 nm. The concentration of nanobubbles with a size of 100 nm is estimated as 1021 m−3. Due to a significant contribution from the Laplace pressure the effective supersaturation reaches 500 for hydrogen and 150 for oxygen.

2.
Zeng
K
and
Zhang
D
2010
Prog. Energ. Combus.
36
307
326
3.
Svetovoy
V B
,
Sanders
R G P
,
Lammerink
T S J
and
Elwenspoek
M C
2011
Phys. Rev. E
84
035302(R)
.
4.
Svetovoy
V
,
Postnikov
A
,
Uvarov
I
,
Sanders
R
and
Krijnen
G
2016
Energies
9
94
5.
Svetovoy
V B
,
Sanders
R G P
,
Ma
K
and
Elwenspoek
M C
2014
Sci. Rep.
4
4296
6.
Weijs
J H
,
Seddon
J R T
and
Lohse
D
2012
Chem. Phys. Chem.
13
2197
204
7.
Svetovoy
V B
,
Sanders
R G P
and
Elwenspoek
M C
2013
J. Phys. Condens. Mat.
25
184002
8.
Aspnes
D E
1982
Thin Solid Films
89
249
262
.
9.
Urréjola
S
,
Sánchez
A
and
Hervello
M F
2010
J. Chem. Eng. Data
55
,
2924
10.
Prokaznikov
A
,
Tas
N
and
Svetovoy
V
2017
Energies
10
178
11.
Ohgaki
K
,
Khanh
N Q
,
Joden
Y
,
Tsuji
A
and
Nakagawa
T
2010
Chem. Eng. Sci.
65
1296
1300
12.
Ushikubo
F Y
,
Furukawa
T
,
Nakagawa
R
,
Enari
M
,
Makino
Y
Kawagoe
Y
 et al. 
2010
Colloids Surf. A: Physicochem. Eng. Asp.
361
31
37
13.
Kikuchi
K
,
Tanaka
Y
,
Saihara
Y
and
Ogumi
Z
2006
Electrochim. Acta
52
904
913
14.
Kikuchi
K
,
Ioka
A
,
Oku
T
,
Tanaka
Y
,
Saihara
Y
and
Ogumi
Z J
2009
Colloid. Interface Sci.
329
306
309
15.
Alheshibri
M
,
Qian
J
,
Jehannin
M
,
Craig
VSJ
2016
Langmuir
32
11086
100
This content is only available via PDF.
You do not currently have access to this content.