UV light processing presents a facile means to tailor the properties of materials and structures. Metal–organic framework (MOF) with strong optical response has been realized through the incorporation of luminescent ligand within the van der Waals structure. The resulting MOF exhibits a significant one-photon excited luminesces change in response to UV light, enabling spatial modulation of the luminescent map of the MOF in micrometer scale. It thus demonstrates the capacity of patterning and data storage inside the crystal in a high resolution.
REFERENCES
1.
H.
Furukawa
, K. E.
Cordova
, M.
O’Keeffe
, and O. M.
Yaghi
, Science
341
, 1230444
(2013
).2.
W.
Cai
, A.
Gladysiak
, M.
Aniola
, V. J.
Smith
, L. J.
Barbour
, and A.
Katrusiak
, J. Am. Chem. Soc.
137
, 9296
(2015
).3.
S. H.
Han
, S. C.
Warren
, S. M.
Yoon
, C. D.
Malliakas
, X.
Hou
, Y.
Wei
, M. G.
Kanatzidi
, and B. A.
Grzybowski
, J. Am. Chem. Soc.
137
, 8169
(2015
).4.
Z.
Hu
, B. J.
Deibert
, and J.
Li
, Chem. Soc. Rev.
43
, 5815
–5840
(2014
).5.
L. R.
Mingabudinova
, V. V.
Vinogradov
, V. A.
Milichko
, E.
Hey-Hawkins
, and A. V.
Vinogradov
, Chem. Soc. Rev.
45
, 5408
(2016
).6.
A. V.
Vinogradov
, V. A.
Milichko
, H.
Zaake-Hertling
, A.
Aleksovska
, S.
Gruschinski
, S.
Schmorl
, B.
Kersting
, E. M.
Zolnhofer
, J.
Sutter
, K.
Meyer
, P.
Lönnecke
, and E.
Hey-Hawkins
, Dalton Trans.
45
, 7244
(2016
).7.
Y.
Sakata
, S.
Furukawa
, M.
Kondo
, K.
Hirai
, N.
Horike
, Y.
Takashima
, H.
Uehara
, N.
Louvain
, M.
Meilikhov
, T.
Tsuruoka
, S.
Isoda
, W.
Kosaka
, O.
Sakata
, and S.
Kitagawa
, Science
339
, 193
–196
(2013
).8.
J.
Yu
, Y.
Cui
, C.-De
Wu
, Y.
Yang
, B.
Chen
, and G.
Qian
, J. Am. Chem. Soc.
137
, 4026
–4029
(2015
).9.
B. L.
Huang
, Z.
Ni
, A.
Millward
, A. J. H.
McGaughey
, C.
Uher
, M.
Kaviany
, and O.
Yahi
, Int. J. Heat Mass Tran.
50
, 405
(2007
).10.
V. A.
Milichko
, S. V.
Makarov
, A. V.
Yulin
, A. V.
Vinogradov
, A. A.
Krasilin
, E.
Ushakova
, V. P.
Dzyuba
, E.
Hey-Hawkins
, E. A.
Pidko
, and P. A.
Belov
, Adv. Mater.
29
, 1606034
(2017
).
This content is only available via PDF.
© 2017 Author(s).
2017
Author(s)
You do not currently have access to this content.
