The ratios of emission probabilities were determined by using the measured K shell X-ray intensity ratio values for elements from Sc to Zn. For the experimental measurements, the samples were excited by 59.5 keV γ rays from a 241Am annular radioactive source. The emitted K X-rays from the samples were counted by an Ultra-LEGe detector with a resolution of 150 eV at 5.9 keV. The ratios of emission probabilities were denoted as uand v which means p(KLX)/p(KLL) and p(KXY)/p(KLL) respectively. The extracted values from the measured intensity ratios and calculated intensity ratios were compared with the earlier studies. It was found that the ratios of emission probabilities that evaluated from the calculated intensity ratios were agree well with the earlier studies except for Zn.

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